Literature DB >> 33295370

Transition metal-catalyzed alkene isomerization as an enabling technology in tandem, sequential and domino processes.

Daniele Fiorito1, Simone Scaringi, Clément Mazet.   

Abstract

One-pot reactions elaborated around transition metal-catalyzed isomerization of alkenes not only offer the inherent advantages of atom-, step- and redox-economy but also enable the preparation of value-added products that would be difficult to access by conventional methods. In this Review, we cover seminal and recent examples of tandem, sequential and domino processes, which incorporate the most attractive features of olefin isomerization.

Entities:  

Year:  2020        PMID： 33295370     DOI： 10.1039/d0cs00449a

Source DB:  PubMed          Journal:  Chem Soc Rev        ISSN： 0306-0012            Impact factor:   54.564


  13 in total

1.  Contra-thermodynamic Olefin Isomerization by Chain-Walking Hydroboration and Dehydroboration.

Authors:  Steven Hanna; Brandon Bloomer; Nicodemo R Ciccia; Trevor W Butcher; Richard J Conk; John F Hartwig
Journal:  Org Lett       Date:  2022-01-26       Impact factor: 6.005

2.  Aza-Heterocycles via Copper-Catalyzed, Remote C-H Desaturation of Amines.

Authors:  Leah M Stateman; Ross M Dare; Alyson N Paneque; David A Nagib
Journal:  Chem       Date:  2021-11-16       Impact factor: 22.804

3.  Low-Valent Tungsten Catalysis Enables Site-Selective Isomerization-Hydroboration of Unactivated Alkenes.

Authors:  Tanner C Jankins; Raul Martin-Montero; Phillippa Cooper; Ruben Martin; Keary M Engle
Journal:  J Am Chem Soc       Date:  2021-09-09       Impact factor: 16.383

4.  Conversion of Primary Alcohols and Butadiene to Branched Ketones via Merged Transfer Hydrogenative Carbonyl Addition-Redox Isomerization Catalyzed by Rhodium.

Authors:  Brian J Spinello; Jessica Wu; Yoon Cho; Michael J Krische
Journal:  J Am Chem Soc       Date:  2021-08-20       Impact factor: 16.383

Review 5.  Synthesis of Natural Products by C-H Functionalization of Heterocycless.

Authors:  Yang Zhang; Michal Szostak
Journal:  Chemistry       Date:  2022-02-17       Impact factor: 5.020

6.  Parts-per-million of ruthenium catalyze the selective chain-walking reaction of terminal alkenes.

Authors:  Sergio Sanz-Navarro; Marta Mon; Antonio Doménech-Carbó; Rossella Greco; Jorge Sánchez-Quesada; Estela Espinós-Ferri; Antonio Leyva-Pérez
Journal:  Nat Commun       Date:  2022-05-20       Impact factor: 17.694

7.  (NHC)Pd(II) hydride-catalyzed dehydroaromatization by olefin chain-walking isomerization and transfer-dehydrogenation.

Authors:  Weihao Chen; Yang Chen; Xiao Gu; Zaizhu Chen; Chun-Yu Ho
Journal:  Nat Commun       Date:  2022-09-20       Impact factor: 17.694

8.  Preparation of Distant Quaternary Carbon Stereocenters by Double Selective Ring-Opening of 1,1-Biscyclopropyl Methanol Derivatives.

Authors:  Yogesh Siddaraju; Juliette Sabbatani; Anthony Cohen; Ilan Marek
Journal:  Angew Chem Int Ed Engl       Date:  2022-05-20       Impact factor: 16.823

9.  [1,5]-Hydride Shift Triggered N-Dealkylative Cyclization into 2-Oxo-1,2,3,4-tetrahydroquinoline-3-carboxylates via Boronate Complexes.

Authors:  Elvira R Zaitseva; Dmitrii S Ivanov; Alexander Yu Smirnov; Andrey A Mikhaylov; Nadezhda S Baleeva; Mikhail S Baranov
Journal:  Molecules       Date:  2022-08-18       Impact factor: 4.927

10.  Stereoselective tandem iridium-catalyzed alkene isomerization-cope rearrangement of ω-diene epoxides: efficient access to acyclic 1,6-dicarbonyl compounds.

Authors:  Rahul Suresh; Itai Massad; Ilan Marek
Journal:  Chem Sci       Date:  2021-06-09       Impact factor: 9.825
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