Literature DB >> 33890601

CO substitution by PPh3 in Fe2S2(CO)6 proceeds via a novel Fe2S intermediate.

Fanjun Zhang1, Toby J Woods, Thomas B Rauchfuss, Federica Arrigoni, Giuseppe Zampella.   

Abstract

The reaction of Fe2S2(CO)6 and PPh3 affords Fe2S2(CO)4(PPh3)2 by an unprecedented mechanism involving the intermediacy of SPPh3 and Fe2S(CO)6(PPh3)2.

Entities:  

Year:  2021        PMID： 33890601      PMCID： PMC8141036          DOI： 10.1039/d1cc00956g

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  10 in total

1.  The way into the bridge: a new bonding mode of tertiary phosphanes, arsanes, and stibanes.

Authors:  Helmut Werner
Journal:  Angew Chem Int Ed Engl       Date:  2004-02-13       Impact factor: 15.336

2.  Thermodynamic scales for sulfur atom transfer and oxo-for-sulfido exchange reactions.

Authors:  James P Donahue
Journal:  Chem Rev       Date:  2006-11       Impact factor: 60.622

Review 3.  Catalytic Metallopolymers from [2Fe-2S] Clusters: Artificial Metalloenzymes for Hydrogen Production.

Authors:  Metin Karayilan; William P Brezinski; Kayla E Clary; Dennis L Lichtenberger; Richard S Glass; Jeffrey Pyun
Journal:  Angew Chem Int Ed Engl       Date:  2019-03-12       Impact factor: 15.336

Review 4.  Hydrogenase Enzymes and Their Synthetic Models: The Role of Metal Hydrides.

Authors:  David Schilter; James M Camara; Mioy T Huynh; Sharon Hammes-Schiffer; Thomas B Rauchfuss
Journal:  Chem Rev       Date:  2016-06-29       Impact factor: 60.622

5.  Electron-Rich, Diiron Bis(monothiolato) Carbonyls: C-S Bond Homolysis in a Mixed Valence Diiron Dithiolate.

Authors:  Qianli Li; Noémie Lalaoui; Toby J Woods; Thomas B Rauchfuss; Federica Arrigoni; Giuseppe Zampella
Journal:  Inorg Chem       Date:  2018-04-05       Impact factor: 5.165

Review 6.  [FeFe]-Hydrogenases: maturation and reactivity of enzymatic systems and overview of biomimetic models.

Authors:  Julian T Kleinhaus; Florian Wittkamp; Shanika Yadav; Daniel Siegmund; Ulf-Peter Apfel
Journal:  Chem Soc Rev       Date:  2021-02-15       Impact factor: 54.564

7.  Ligand Displacement Reaction Paths in a Diiron Hydrogenase Active Site Model Complex.

Authors:  Jan H Blank; Salvador Moncho; Allen M Lunsford; Edward N Brothers; Marcetta Y Darensbourg; Ashfaq A Bengali
Journal:  Chemistry       Date:  2016-08-02       Impact factor: 5.236

8.  Redox and "Antioxidant" Properties of Fe2(μ-SH)2(CO)4(PPh3)2.

Authors:  Husain N Kagalwala; Noémie Lalaoui; Qian-Li Li; Liang Liu; Toby Woods; Thomas B Rauchfuss
Journal:  Inorg Chem       Date:  2019-02-06       Impact factor: 5.165

9.  Regioselectivity in ligand substitution reactions on diiron complexes governed by nucleophilic and electrophilic ligand properties.

Authors:  Ryan D Bethel; Danielle J Crouthers; Chung-Hung Hsieh; Jason A Denny; Michael B Hall; Marcetta Y Darensbourg
Journal:  Inorg Chem       Date:  2015-03-13       Impact factor: 5.165

10.  A sulfido-bridged diiron(II) compound and its reactions with nitrogenase-relevant substrates.

Authors:  Javier Vela; Sebastian Stoian; Christine J Flaschenriem; Eckard Münck; Patrick L Holland
Journal:  J Am Chem Soc       Date:  2004-04-14       Impact factor: 15.419
  10 in total

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