Literature DB >> 15070362

A sulfido-bridged diiron(II) compound and its reactions with nitrogenase-relevant substrates.

Javier Vela1, Sebastian Stoian, Christine J Flaschenriem, Eckard Münck, Patrick L Holland.   

Abstract

The active site iron-molybdenum cofactor of nitrogenase has sulfide-bridged pairs of redox-active, trigonal pyramidal iron atoms that are postulated to be the site of N2 transformation. A synthetic compound is described in which two three-coordinate iron(II) ions are bridged similarly by sulfide. The compound binds nitrogen donors to become trigonal pyramidal and cleaves the N-N bond of phenylhydrazine with oxidation of iron(II) to iron(III).

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Year:  2004        PMID： 15070362     DOI： 10.1021/ja049417l

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  34 in total

Review 1.  Catalytic N2-to-NH3 (or -N2H4) Conversion by Well-Defined Molecular Coordination Complexes.

Authors:  Matthew J Chalkley; Marcus W Drover; Jonas C Peters
Journal:  Chem Rev       Date:  2020-04-30       Impact factor: 60.622

2.  Sterically directed nitronate complexes of 2,6-di-tert-butyl-4-nitrophenoxide with Cu(ii) and Zn(ii) and their H-atom transfer reactivity.

Authors:  Thomas R Porter; Ellen C Hayes; Werner Kaminsky; James M Mayer
Journal:  Dalton Trans       Date:  2017-02-21       Impact factor: 4.390

3.  Synthesis, structure and reactivity of Fe(II/III)-NH3 complexes bearing a tripodal sulfonamido ligand.

Authors:  Nathaniel S Sickerman; Sonja M Peterson; Joseph W Ziller; A S Borovik
Journal:  Chem Commun (Camb)       Date:  2014-01-24       Impact factor: 6.222

4.  Low-spin pseudotetrahedral iron(I) sites in Fe₂(μ-S) complexes.

Authors:  John S Anderson; Jonas C Peters
Journal:  Angew Chem Int Ed Engl       Date:  2014-04-17       Impact factor: 15.336

5.  Oxidized and reduced [2Fe-2S] clusters from an iron(I) synthon.

Authors:  Megan E Reesbeck; Meghan M Rodriguez; William W Brennessel; Brandon Q Mercado; David Vinyard; Patrick L Holland
Journal:  J Biol Inorg Chem       Date:  2015-06-05       Impact factor: 3.358

6.  Three-coordinate terminal imidoiron(III) complexes: structure, spectroscopy, and mechanism of formation.

Authors:  Ryan E Cowley; Nathan J DeYonker; Nathan A Eckert; Thomas R Cundari; Serena DeBeer; Eckhard Bill; Xavier Ottenwaelder; Christine Flaschenriem; Patrick L Holland
Journal:  Inorg Chem       Date:  2010-07-05       Impact factor: 5.165

7.  Dinitrogen complexes of sulfur-ligated iron.

Authors:  Ayumi Takaoka; Neal P Mankad; Jonas C Peters
Journal:  J Am Chem Soc       Date:  2011-05-16       Impact factor: 15.419

8.  A mixed valence zinc dithiolene system with spectator metal and reactor ligands.

Authors:  Stephen C Ratvasky; Benjamin Mogesa; Michael J van Stipdonk; Partha Basu
Journal:  Polyhedron       Date:  2016-02-01       Impact factor: 3.052

9.  Dinitrogen binding and activation at a molybdenum-iron-sulfur cluster.

Authors:  Alex McSkimming; Daniel L M Suess
Journal:  Nat Chem       Date:  2021-05-27       Impact factor: 24.427

10.  Conversion of Fe-NH2 to Fe-N2 with release of NH3.

Authors:  John S Anderson; Marc-Etienne Moret; Jonas C Peters
Journal:  J Am Chem Soc       Date:  2013-01-08       Impact factor: 15.419
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