| Literature DB >> 33889052 |
Matthew S Landis1, Russell W Long1, Jonathan Krug1, Maribel Colón1, Robert Vanderpool1, Andrew Habel2, Shawn P Urbanski3.
Abstract
Wildland fires can emit substantial amounts of air pollution that may pose a risk to those in proximity (e.g., first responders, nearby residents) as well as downwind populations. Quickly deploying air pollution measurement capabilities in response to incidents has been limited to date by the cost, complexity of implementation, and measurement accuracy. Emerging technologies including miniaturized direct-reading sensors, compact microprocessors, and wireless data communications provide new opportunities to detect air pollution in real time. The U.S. Environmental Protection Agency (EPA) partnered with other U.S. federal agencies (CDC, NASA, NPS, NOAA, USFS) to sponsor the Wildland Fire Sensor Challenge. EPA and partnering organizations share the desire to advance wildland fire air measurement technology to be easier to deploy, suitable to use for high concentration events, and durable to withstand difficult field conditions, with the ability to report high time resolution data continuously and wirelessly. The Wildland Fire Sensor Challenge encouraged innovation worldwide to develop sensor prototypes capable of measuring fine particulate matter (PM2.5), carbon monoxide (CO), carbon dioxide (CO2), and ozone (O3) during wildfire episodes. The importance of using federal reference method (FRM) versus federal equivalent method (FEM) instruments to evaluate performance in biomass smoke is discussed. Ten solvers from three countries submitted sensor systems for evaluation as part of the challenge. The sensor evaluation results including sensor accuracy, precision, linearity, and operability are presented and discussed, and three challenge winners are announced. Raw solver submitted PM2.5 sensor accuracies of the winners ranged from ~22 to 32%, while smoke specific EPA regression calibrations improved the accuracies to ~75-83% demonstrating the potential of these systems in providing reasonable accuracies over conditions that are typical during wildland fire events.Entities:
Keywords: Carbon dioxide; Carbon monoxide; Ozone; Particulate matter; Sensor performance; Wildland fire smoke
Year: 2021 PMID: 33889052 PMCID: PMC8059620 DOI: 10.1016/j.atmosenv.2020.118165
Source DB: PubMed Journal: Atmos Environ (1994) ISSN: 1352-2310 Impact factor: 4.798
Fig. 1.Example phase I testing day (March 28, 2018) demonstrating stepping through test points with transition times highlighted.
Phase I testing accuracy (%) and collocated precision (%) results for PM2.5, CO, CO2, and O3.
| Solver | Sensor | n | Accuracy (Mean ± Standard Deviation) | Collocated Precision (Mean ± Standard Deviation) | ||||||
|---|---|---|---|---|---|---|---|---|---|---|
| PM2.5 | CO | CO2 | O3 | PM2.5 | CO | CO2 | O3 | |||
| A | # 1 | 283 | 22.5 ± 14.8 | 69.7 ± 21.6 | 87.6 ± 10.3 | 44.1 ± 5.4 | 4.9 ± 5.8 | 14.5 ± 6.0 | 3.0 ± 2.8 | 28.2 ± 12.2 |
| A | # 2 | 22.4 ± 14.4 | 57.5 ± 17.4 | 87.5 ± 10.2 | 66.1 ± 7.8 | |||||
| B | # 1 | 288 | 13.5 ± 5.2 | 60.9 ± 41.7 | 34.8 ± 9.7 | 18.7 ± 17.5 | 67.7 ± 9.1 | 7.7 ± 4.9 | 53.1 ± 15.6 | 66.2 ± 18.2 |
| B | # 2 | 37.2 ± 10.1 | 69.7 ± 36.9 | 74.7 ± 4.0 | 39.4 ± 24.0 | |||||
| C | # 1 | 287 | 69.8 ± 31.6 | 72.1 ± 6.6 | – | 66.3 ± 6.1 | 4.8 ± 2.3 | 15.4 ± 0.9 | – | 13.0 ± 7.0 |
| C | # 2 | 65.6 ± 25.1 | 90.6 ± 4.9 | – | 58.7 ± 9.4 | |||||
| D | # 1 | 53 | 52.6 ± 9.3 | −429 ± 552 | 14.1 ± 2.4 | −8.4 ± 3.7 | 12.0 ± 7.3 | −72.1 ± 210.8 | 6.6 ± 5.9 | −1.9 ± 1.6 |
| D | # 2 | 45.9 ± 7.8 | 116 ± 332 | 15.0 ± 3.0 | −8.3 ± 3.4 | |||||
Fig. 2.Phase I testing (March 28, 2018) demonstrating the solver A and solver B CO results with transition times highlighted.
Phase I MANOVA Testing Type III Sum of Squares Results Evaluating the Impact of Chamber Temperature and Relative Humidity on Sensor Measurements (Bold Values are Significant).
| Solver | Sensor | Temperature Effect Pr > F | Relative Humidity Effect Pr > F | ||||||
|---|---|---|---|---|---|---|---|---|---|
| PM2.5 | CO | CO2 | O3 | PM2.5 | CO | CO2 | O3 | ||
| A | # 1 | 0.8461 | 0.4220 | 0.0955 | 0.9700 | 0.3004 | |||
| A | # 2 | 0.1677 | 0.1029 | 0.7017 | 0.6679 | ||||
| B | # 1 | 0.2464 | 0.0835 | 0.3712 | 0.7343 | ||||
| B | # 2 | 0.5218 | 0.8273 | 0.3774 | |||||
| C | # 1 | 0.9685 | 0.7305 | – | 0.1331 | 0.4336 | – | ||
| C | # 2 | 0.8129 | – | – | |||||
| D | # 1 | 0.9233 | 0.1444 | 0.1101 | |||||
| D | # 2 | 0.5229 | 0.9245 | 0.0539 | 0.4009 | 0.0845 | 0.2439 | 0.2274 | |
Fig. 3.Example phase II testing day (April 18, 2018) demonstrating PM2.5 concentrations during sequential test burns with fuel ignition (red) and chamber ventilation start times indicated (blue). (For interpretation of the references to colour in this figure legend, the reader is referred to the Web version of this article.)
Phase II smoke testing accuracy (%) and collocated precision (%) results for PM2.5, CO, CO2, and O3.
| Solver | Sensor | Accuracy (Mean ± Standard Deviation) | Collocated Precision (Mean ± Standard Deviation) | ||||||||
|---|---|---|---|---|---|---|---|---|---|---|---|
| n | PM2.5 | CO | CO2 | O3 | n | PM2.5 | CO | CO2 | O3 | ||
| A | # 1 | 353[ | 33.0 ± 12.7 | 73.4 ± 78.8 | 89.9 ± 5.0 | – | 339 | 4.8 ± 10.0 | 18.3 ± 10.6 | 6.5 ± 5.1 | 46.6 ± 196.8 |
| A | # 2 | 398 | 31.9 ± 11.8 | 65.0 ± 12.0 | 92.6 ± 5.6 | – | |||||
| B | # 1 | 398 | 25.7 ± 15.5 | −294 ± 1545 | 14.0 ± 6.2 | – | 398 | 49.7 ± 11.4 | 10.8 ± 6.7 | 90.8 ± 17.1 | 47.3 ± 12.5 |
| B | # 2 | 398 | 48.4 ± 24.4 | −205 ± 1237 | 61.9 ± 2.2 | – | |||||
| C | # 1 | 0 | – | – | – | – | 0 | – | – | – | – |
| C | # 2 | 0 | – | – | – | – | |||||
| D | # 1 | 110 | 32.5 ± 196.4 | −374 ± 668 | 17.5 ± 2.5 | – | 97 | 9.0 ± 9.2 | 3.2 ± 43.4 | 10.5 ± 7.5 | −102 ± 79.8 |
| D | # 2 | 125 | 43.8 ± 141.8 | −643 ±1415 | 18.8 ± 3.4 | – | |||||
| E | # 1 | 129 | 51.7 ± 10.9 | 53.6 ± 40.7 | 87.6 ± 2.5 | – | 0 | – | – | – | – |
EPA testing team inadvertently turned off sensor pod for one day of Phase II testing impacting the number of observations.
Fig. 4.Phase II Chamber Testing PM2.5 Concentration (·g m-3) Scatter Plots for Solver A (a–b) and Solver B (c–d) Raw Challenge Data.
Phase II MANOVA Testing Type III Sum of Squares Results Evaluating the Impact of Black Carbon (BC), Nitrogen Dioxide (NO2), Chamber Temperature, and Relative Humidity on Sensor Measurements (Bold Values are Significant).
| Solver | Sensor | BC Pr > F | NO2 Pr > F | Temperature Effect Pr > F | Relative Humidity Effect Pr > F | ||||||
|---|---|---|---|---|---|---|---|---|---|---|---|
| PM2.5 | O3 | PM2.5 | CO | CO2 | O3 | PM2.5 | CO | CO2 | O3 | ||
| A | # 1 | 0.4538 | 0.1709 | 0.1802 | |||||||
| A | # 2 | 0.0974 | 0.6401 | ||||||||
| B | # 1 | 0.0538 | 0.0562 | 0.0839 | 0.2836 | 0.7278 | 0.2068 | ||||
| B | # 2 | 0.2975 | 0.2769 | 0.0880 | 0.1662 | 0.1381 | |||||
| C | # 2 | – | – | – | – | – | – | – | – | – | – |
| D | # 1 | 0.1990 | 0.2007 | 0.1343 | 0.8908 | 0.9914 | |||||
| D | # 2 | 0.0548 | 0.1495 | 0.6114 | 0.9058 | ||||||
| E | # 1 | 0.1948 | |||||||||
Summary of sensor calibration equations and reference PM2.5 concentration versus calibrated instrument linear regression equations.
| Instrument | Parameter | Phase I Clean Chamber | Phase II Smoke Chamber |
|---|---|---|---|
| Solver A #1 | PM2.5 | Ref = (3.3855 × Sensor #11.1549) − 19.46; r2 = 0.957 | Ref = (1.3451 × Sensor #1) + (0.0187 × Sensor #12) + 8.52; r2 = 0.936 |
| Solver A #1 | CO | Ref = (1.3749 × Sensor #1) − 1.01; r2 = 0.985 | Ref = (1.2897 × Sensor #1) − 0.19; r2 = 0.991 |
| Solver A #1 | CO2 | Ref = (1.2228 × Sensor #1) − 99.19; r2 = 0.986 | Ref = (0.2868 / Sensor #1) + (0.0010 / Sensor #12) + 165.39; r2 = 0.946 |
| Solver A #1 | O3 | Ref = (2.1683 × Sensor #1) + 6.05; r2 = 0.924 | – |
| Solver A #2 | PM2.5 | Ref = (5.8076 × Sensor #21.0337) − 32.896; r2 = 0.937 | Ref = (2.4324 × Sensor #2) + (0.0132 × Sensor #22) − 13.78; r2 = 0.940 |
| Solver A #2 | CO | Ref = (1.7711 × Sensor #2) − 1.01; r2 = 0.972 | Ref = (1.4075 × Sensor #2) + 0.17; r2 = 0.973 |
| Solver A #2 | CO2 | Ref = (1.2611 × Sensor #2) − 131.80; r2 = 0.987 | Ref = (−3.6716 × Sensor #2) + (0.0040 × Sensor #22) + 1333.91; r2 = 0.875 |
| Solver A #2 | O3 | Ref = (1.3419 × Sensor #2) + 13.81; r2 = 0.905 | |
| Solver B #1 | PM2.5 | Ref = (4.9463 × Sensor #1) + 87.89; r2 = 0.904 | Ref = (2.3247 × Sensor #1) + 135.55; r2 = 0.797 |
| Solver B #1 | CO | Ref = (1.5467 × Sensor #1) − 3.75; r2 = 0.963 | Ref = (1.2993 − Sensor #1) − 4.93; r2 = 0.649 |
| Solver B #1 | CO2 | Ref = (1.8094 × Sensor #1) + 359.69; r2 = 0.964 | Ref = (1.9515 × Sensor #1) + 409.12; r2 = 0.861 |
| Solver B #1 | O3 | Ref = (0.2162 × Sensor #1) + 121.75; r2 = 0.008 | |
| Solver B #2 | PM2.5 | Ref = (2.1353 × Sensor #2) + 43.40; r2 = 0.945 | Ref = (1.6158 × Sensor #2) + 66.05; r2 = 0.811 |
| Solver B #2 | CO | Ref = (1.3269 × Sensor #2) − 2.85; r2 = 0.980 | Ref = (1.2401 × Sensor #2) − 3.88; r2 = 0.858 |
| Solver B #2 | CO2 | Ref = (1.2538 × Sensor #2) + 43.85; r2 = 0.987 | Ref = (1.5560 × Sensor #2) + 21.01; r2 = 0.960 |
| Solver B #2 | O3 | Ref = (0.2981 × Sensor #2) + 111.08; r2 = 0.054 | |
| Solver C #1 | PM2.5 | Ref = (1.2559 × Sensor #1) + 12.57; r2 = 0.951 | |
| Solver C #1 | CO | Ref = (1.6970 × Sensor #1) − 2.17; r2 = 0.979 | – |
| Solver C #1 | O3 | Ref = (1.2837 × Sensor #1) + 16.50; r2 = 0.984 | |
| Solver C #2 | PM2.5 | Ref = (1.3090 × Sensor #2) + 18.79; r2 = 0.944 | |
| Solver C #2 | CO | Ref = (1.3634 × Sensor #2) − 2.18; r2 = 0.978 | – |
| Solver C #2 | O3 | Ref = (1.5432 × Sensor #2) + 12.86; r2 = 0.816 | |
| Solver D #1 | PM2.5 | Ref = (1.7335 × Sensor #1) + 28.63; r2 = 0.956 | Ref = (0.8367 × Sensor #1) + 128.83; r2 = 0.447 |
| Solver D #1 | CO | Ref = (1.3342 × Sensor #1) + 77.40; r2 = 0.731 | Ref = (0.9252 × Sensor #1) − 3.78; r2 = 0.569 |
| Solver D #1 | CO2 | Ref = (9.8540 × Sensor #1) − 364.08; r2 = 0.976 | Ref = (7.5688 × Sensor #1) − 173.40; r2 = 0.565 |
| Solver D #1 | O3 | Ref = (542.6847 × Sensor #1) + 5233.21; r2 = 0.331 | |
| Instrument | Parameter | Phase I Clean Chamber Testing Calibration Equation | Phase II Smoke Chamber Testing Calibration Equation |
| Solver D #2 | PM2.5 | Ref = (2.0810 × Sensor #2) + 12.06; r2 = 0.976 | Ref = (1.0336 × Sensor #2) + 99.56; r2 = 0.533 |
| Solver D #2 | CO | Ref = (0.9059 × Sensor #2) + 18.37; r2 = 0.965 | Ref = (0.2568 × Sensor #2) − 0.52; r2 = 0.710 |
| Solver D #2 | CO2 | Ref = (9.1478 × Sensor #2) − 323.77; r2 = 0.965 | Ref = (3.7927 × Sensor #2) + 179.29; r2 = 0.290 |
| Solver D #2 | O3 | Ref = (−140.9741 × Sensor #2) − 1169.42; r2 = 0.640 | – |
| Solver E #1 | PM2.5 | – | Ref = (1.5545 × Sensor #1) + 74.41; r2 = 0.794 |
| Solver E #1 | CO | – | Ref = (0.3546 × Sensor #1) + 2.21; r2 = 0.280 |
| Solver E #1 | CO2 | – | Ref = (1.1427 × Sensor #1) − 0.26; r2 = 0.985 |
| Solver E #1 | O3 | – | – |
Post challenge regression calibrated chamber testing accuracy (%) results (mean ± standard deviation) for PM2.5, CO, CO2, and O3.
| Solver | Sensor | Phase I Accuracy (Mean ± Standard Deviation) | Phase II Accuracy (Mean ± Standard Deviation) | ||||||
|---|---|---|---|---|---|---|---|---|---|
| PM2.5 | CO | CO2 | O3 | PM2.5 | CO | CO2 | O3 | ||
| A | # 1 | 79.4 ± 46.6 | 92.9 ± 9.8 | 95.0 ± 3.2 | 91.2 ± 8.5 | 83.1 ± 18.7 | 82.1 ± 83.5 | 96.3 ± 3.1 | – |
| A | # 2 | 73.8 ± 61.1 | 91.7 ± 5.3 | 95.3 ± 3.7 | 91.0 ± 6.3 | 83.6 ± 18.4 | 88.0 ± 46.1 | 94.3 ± 4.2 | – |
| B | # 1 | 1.1 ±314.3 | 59.8 ± 59.9 | 92.7 ± 5.3 | 63.0 ± 35.4 | 18.8 ± 122.0 | −51.7 ± 643.5 | 95.4 ± 4.8 | – |
| B | # 2 | 50.8 ± 150.3 | 69.3 ± 44.0 | 95.7 ± 3.1 | 64.1 ± 34.0 | 48.0 ± 63.7 | 3.7 ± 458.8 | 97.5 ± 2.3 | – |
| C | # 1 | 79.0 ± 44.4 | 87.1 ± 9.8 | – | 96.2 ± 3.3 | – | – | – | – |
| C | # 2 | 74.3 ± 47.3 | 86.8 ± 9.9 | – | 87.9 ± 10.3 | – | – | – | – |
| D | # 1 | 89.9 ± 14.0 | −32.8 ± 150.9 | 92.0 ± 8.0 | 72.4 ± 28.9 | 12.2 ± 227.2 | 4.0 ± 181.1 | 88.1 ± 9.4 | – |
| D | # 2 | 91.0 ± 12.0 | 52.0 ± 190.9 | 86.1 ± 11.3 | 83.5 ± 20.3 | 28.1 ± 190.1 | 38.2 ± 111.4 | 85.6 ± 9.6 | – |
| E | # 1 | – | – | – | – | 84.0 ± 20.2 | 66.2 ± 42.0 | 97.7 ± 1.6 | – |