| Literature DB >> 32741022 |
Marvin Nathusius1,2,3, Barbara Ejlli1,2,3, Frank Rominger2, Jan Freudenberg2,3, Uwe H F Bunz2, Klaus Müllen1.
Abstract
Chrysene and its bisbenzannulated homologue, naphtho[2,3-c]tetraphene, were synthesized through a PtCl2 -catalyzed cyclization of alkynes, which also furnished corresponding biaryls subsequent to a Glaser coupling reaction of the starting alkynes. The optoelectronic properties of 5,5'-bichrysenyl and 6,6'-binaphtho[2,3-c]tetraphene were compared to their chrysene-based "monomers". Oxidative cyclodehydrogenations of bichrysenyl and its higher homologue towards large nanographenes were also investigated.Entities:
Keywords: 2D acenes; blue emission; polyaromatic hydrocarbons; solubility increase; twisted biaryls
Year: 2020 PMID: 32741022 PMCID: PMC7756344 DOI: 10.1002/chem.202001808
Source DB: PubMed Journal: Chemistry ISSN: 0947-6539 Impact factor: 5.236