Literature DB >> 31625758

Four-Fold Alkyne Benzannulation: Synthesis, Properties, and Structure of Pyreno[a]pyrene-Based Helicene Hybrids.

Radha Bam1, Wenlong Yang1, Giovanna Longhi2, Sergio Abbate2, Andrea Lucotti3, Matteo Tommasini3, Roberta Franzini4, Claudio Villani4, Vincent J Catalano1, Marilyn M Olmstead5, Wesley A Chalifoux1.   

Abstract

The synthesis of pyreno[a]pyrene-based helicene hybrids was achieved in good yield via a four-fold alkyne benzannulation reaction that was promoted by Brønsted acid. The molecules are configurationally locked, allowing the enantiomers to be separated using chiral HPLC so that their photophysical and chiroptical properties, including circular dichroism and circularly polarized luminescence, could be studied.

Entities:  

Year:  2019        PMID: 31625758     DOI: 10.1021/acs.orglett.9b03273

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  1 in total

1.  Chrysene-Based Blue Emitters.

Authors:  Marvin Nathusius; Barbara Ejlli; Frank Rominger; Jan Freudenberg; Uwe H F Bunz; Klaus Müllen
Journal:  Chemistry       Date:  2020-10-19       Impact factor: 5.236

  1 in total

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