| Literature DB >> 32484683 |
Mervin Zhao1, Lei Liao1, Wang Xiao1, Xuanze Yu1, Haotian Wang1, Qiqi Wang1, Ying Ling Lin2, F Selcen Kilinc-Balci3, Amy Price4, Larry Chu4, May C Chu5, Steven Chu6,7, Yi Cui8,9.
Abstract
The COVID-19 pandemic is currently causing a severe disruption and shortage in the global supply chain of necessary personal protective equipment (e.g., N95 respirators). The U.S. CDC has recommended use of household cloth by the general public to make cloth face coverings as a method of source control. We evaluated the filtration properties of natural and synthetic materials using a modified procedure for N95 respirator approval. Common fabrics of cotton, polyester, nylon, and silk had filtration efficiency of 5-25%, polypropylene spunbond had filtration efficiency 6-10%, and paper-based products had filtration efficiency of 10-20%. An advantage of polypropylene spunbond is that it can be simply triboelectrically charged to enhance the filtration efficiency (from 6 to >10%) without any increase in pressure (stable overnight and in humid environments). Using the filtration quality factor, fabric microstructure, and charging ability, we are able to provide an assessment of suggested fabric materials for homemade facial coverings.Entities:
Keywords: COVID-19; aerosols; cloth filtration efficiency; face masks; facial coverings; triboelectricity
Mesh:
Substances:
Year: 2020 PMID: 32484683 PMCID: PMC7294826 DOI: 10.1021/acs.nanolett.0c02211
Source DB: PubMed Journal: Nano Lett ISSN: 1530-6984 Impact factor: 11.189
Evaluation of Reference and Common Materials’ Filtration Propertiesa
| material | source | structure | basis weight (g·m–2) | bulk density (basis weight/thickness) (g·m–2·μm–1) | initial filtration efficiency (%) | initial pressure drop (Pa) | filter quality factor,
|
|---|---|---|---|---|---|---|---|
| Personal Protection Materials | |||||||
| polypropylene 1 | particulate FFR | meltblown (nonwoven) | 25 | 0.17 | 95.94 ± 2.00 | 9.0 ± 2.0 | 162.7 ± 21.3 |
| polypropylene 2 | medical face mask | meltblown (nonwoven) | 26 | 0.21 | 33.06 ± 0.95 | 34.3 ± 0.5 | 5.0 ± 0.1 |
| polypropylene 3 | medical face mask | meltblown (nonwoven) | 20 | 0.20 | 18.81 ± 0.50 | 16.3 ± 0.5 | 5.5 ± 0.1 |
| Household Materials | |||||||
| cellulose 1 | paper towel | bonded | 42.9 | 0.33 | 10.41 ± 0.28 | 11.0 ± 0.0 | 4.3 ± 2.8 |
| cellulose 2 | tissue paper | bonded | 32.8 | 0.39 | 20.2 ± 0.32 | 19.0 ± 1.0 | 5.1 ± 3.2 |
| cellulose 3 | copy paper | bonded | 72.8 | 0.76 | 99.85 ± 0.02 | 1883.6 ± 39.3 | 1.5 ± 0.2 |
All materials were tested in samples of three unless denoted. Uncertainties denoted here represent the standard deviation between the samples. Materials in bold were further studied to investigate if the simple triboelectric charging can positively impact the filtration properties. For the particulate FFR sample, the meltblown is independently procured for usage in FFRs as it is difficult to obtain enough sample to test with the filter tester.
Indicates this sample did not have enough material and data is presented in samples of two.
Figure 1SEM images of the microscopic structure of various household materials. All images are given in pairs. The first of the pairs has a scale bar (left, black bar in white background) corresponding to 300 μm. The second of the pairs has a scale bar (right, white bar in black background) corresponding to 75 μm. (a–c) Polypropylene samples from PPE (a,b) and common spunbond (c). (d–f) Cotton samples, as given in Table . (g–i) Polyester, silk, and nylon samples, respectively. (j–l) Other cellulose-based products, paper towel, tissue paper, and printing paper, as per given in Table .
Figure 2Filtration properties of common materials before and after charging. Each uncertainty represents the standard deviation of three samples (excluding cotton which are from two samples). (a) Schematic of effect of charging fibers using triboelectricity. Particle filtration efficiency can be enhanced using charges generated from the triboelectric effect. (b) Filtration efficiency of materials before and after charging. Silk, nylon, polyester, and PP-4 all have increases in filtration efficiency after rubbing with latex. Cotton’s efficiency after charging was unchanged or decreased in efficiency, possibly due to abrasion and/or pore size expansion. (c) Quality factor, Q, of household materials before and after charging. Results are roughly in agreement with data presented in (b), except nylon which had lower performance due to pressure drop and PP-4 is much better performing due to low pressure drop. (d,e) Filtration efficiency (d) and Q (e) of various polypropylene spunbond fabrics with different basis weights.
Figure 3Time evolution of filtration properties of common materials. Each uncertainty represents the standard deviation of three samples. (a) Filtration efficiency decay in ambient conditions (listed in the main text), up to overnight. (b) Evolution of Q as a function of time, up to overnight. (c) Evolution of filtration efficiency in a humid and warmer environment, up to an hour. (d) Evolution of the PP-4 Q as a function of the time, up to an hour.
Figure 4Efficiency after charging PP-4 with different materials. Each uncertainty represents the standard deviation of three samples.
Summary and Ranking of Materials Tested Here Based on Filtration Quality Factor, Q, with Relevant Comments for Each Material
| ∼ | ∼filtration efficiency (%) | material | comments |
|---|---|---|---|
| >100 | >95 | polypropylene meltblown (charged) | material found in FFRs (used for reference) |
| 30 | 10–20 | charged polypropylene (PP-4) | charged value after overnight, polypropylene
spunbonds can vary (different basis weight has
different efficiency), charging increased the
|
| 15 | 5–10 | uncharged polypropylene (PP-4) | initial polypropylene spunbond fabrics can vary in efficiency, but most tested had low pressure drops |
| 5–10 | 5–20 | cotton | cotton fabrics can vary in initial pressure drop, select cotton fabrics without any visible pores under light illumination or use multilayer configurations |
| 5–10 | 20 | polyester | similar properties and comments as cotton |
| 5 | 30 | polypropylene meltblown (uncharged) | material found in medical face masks (used for reference) |
| 5 | 10–20 | tissue paper, paper towel | low mechanical strength, but may be possible to integrate into some masks with other cloths as a composite material |
| <5 | 5 | silk | silk can be considered for use if cotton and/or polyester are unavailable |
| <1 | 20 | nylon (woven) | the nylon tested in this study had very high pressure drop. If using nylon for masks the fabric needs to have a lower pressure drop to be effective |