Literature DB >> 32019890

Energy dissipation bounds for autonomous thermodynamic cycles.

Samuel J Bryant1, Benjamin B Machta1,2.   

Abstract

How much free energy is irreversibly lost during a thermodynamic process? For deterministic protocols, lower bounds on energy dissipation arise from the thermodynamic friction associated with pushing a system out of equilibrium in finite time. Recent work has also bounded the cost of precisely moving a single degree of freedom. Using stochastic thermodynamics, we compute the total energy cost of an autonomously controlled system by considering both thermodynamic friction and the entropic cost of precisely directing a single control parameter. Our result suggests a challenge to the usual understanding of the adiabatic limit: Here, even infinitely slow protocols are energetically irreversible.

Keywords:  dissipation; energy bounds; entropy production; molecular machines; nonequilibrium

Year:  2020        PMID: 32019890      PMCID: PMC7035472          DOI: 10.1073/pnas.1915676117

Source DB:  PubMed          Journal:  Proc Natl Acad Sci U S A        ISSN: 0027-8424            Impact factor:   11.205


  29 in total

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