Literature DB >> 31408332

Asymmetric Synthesis and Stereochemical Assignment of 12C/13C Isotopomers.

Tomoya Miura1, Takayuki Nakamuro1, Yuuya Nagata1, Daisuke Moriyama1, Scott G Stewart1, Masahiro Murakami1.   

Abstract

A synthesis of chiral hydrocarbons having C1 axis and C3 symmetry, which owe their chirality due to asymmetrical distribution of 12C/13C isotopes, is reported. Their absolute configurations assigned using the vibrational circular dichroism technique conform with those deduced from the absolute configurations of the parent α-formyl cyclopropanes.

Entities:  

Year:  2019        PMID： 31408332     DOI： 10.1021/jacs.9b07181

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  3 in total

1.  Computational Comparison of Chemical and Isotopic Approaches to Control the Photoisomerization Dynamics of Light-Driven Molecular Motors.

Authors:  Jun Wang; Baswanth Oruganti; Bo Durbeej
Journal:  J Org Chem       Date:  2021-03-30       Impact factor: 4.354

2.  Unidirectional Rotary Motion in Isotopically Chiral Molecular Motors: A Computational Analysis.

Authors:  Jun Wang; Baswanth Oruganti; Bo Durbeej
Journal:  Org Lett       Date:  2020-08-21       Impact factor: 6.005

3.  Enantioselective Synthesis of Enantioisotopomers with Quantitative Chiral Analysis by Chiral Tag Rotational Spectroscopy.

Authors:  Mitchell D Mills; Reilly E Sonstrom; Zoua Pa Vang; Justin L Neill; Haley N Scolati; Channing T West; Brooks H Pate; Joseph R Clark
Journal:  Angew Chem Int Ed Engl       Date:  2022-07-08       Impact factor: 16.823
  3 in total

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