Literature DB >> 30393421

Carbon Dioxide Cleavage by a Ni2 Complex Supported by a Binucleating Bis(N-Heterocyclic Carbene) Framework.

Emily Y Tsui1, Theodor Agapie1.   

Abstract

A binucleating bis(N-heterocyclic carbene) ligand was designed as a means to coordinate and proximally constrain two transition metal centers. Using an imidazopyridine-based NHC afforded a framework structurally related to previously reported para-terphenyl diphosphines. Bimetallic copper, cobalt, and nickel complexes supported by this framework were synthesized and structurally characterized. Strong interactions between the metal centers and the central arene were observed in all nickel complexes. Dinickel(0) complexes of this ligand framework were found to react with CO2 to form a dicarbonyl-bridged dinickel(0) product, demonstrating facile CO2 reduction.

Entities:  

Year:  2014        PMID： 30393421      PMCID： PMC6214461          DOI： 10.1016/j.poly.2014.06.041

Source DB:  PubMed          Journal:  Polyhedron        ISSN： 0277-5387            Impact factor:   3.052


  24 in total

1.  Nickel hydrides supported by a non-innocent diphosphine arene pincer: mechanistic studies of nickel-arene H-migration and partial arene hydrogenation.

Authors:  Sibo Lin; Michael W Day; Theodor Agapie
Journal:  J Am Chem Soc       Date:  2011-02-23       Impact factor: 15.419

2.  Synthesis and C-C coupling reactivity of a dinuclear Ni(i)-Ni(i) complex supported by a terphenyl diphosphine.

Authors:  Alexandra Velian; Sibo Lin; Alexander J M Miller; Michael W Day; Theodor Agapie
Journal:  J Am Chem Soc       Date:  2010-05-12       Impact factor: 15.419

3.  Synthesis and chemistry of bis(triisopropylphosphine) nickel(I) and nickel(0) precursors.

Authors:  Robert Beck; Manar Shoshani; Jonathan Krasinkiewicz; Jillian A Hatnean; Samuel A Johnson
Journal:  Dalton Trans       Date:  2012-11-20       Impact factor: 4.390

4.  Oxygen-induced ligand dehydrogenation of a planar bis-mu-chloronickel(I) dimer featuring an NHC ligand.

Authors:  Benjamin R Dible; Matthew S Sigman; Atta M Arif
Journal:  Inorg Chem       Date:  2005-05-30       Impact factor: 5.165

5.  Reactions of CO(2) and CS(2) with 1,2-bis(di-tert-butylphosphino)ethane complexes of nickel(0) and nickel(I).

Authors:  John S Anderson; Vlad M Iluc; Gregory L Hillhouse
Journal:  Inorg Chem       Date:  2010-11-01       Impact factor: 5.165

6.  CO oxidation at nickel centres by N2O or O2 to yield a novel hexanuclear carbonate.

Authors:  Bettina Horn; Christian Limberg; Christian Herwig; Michael Feist; Stefan Mebs
Journal:  Chem Commun (Camb)       Date:  2012-07-12       Impact factor: 6.222

7.  Generation of a doubly bridging CO2 ligand and deoxygenation of CO2 by an (NHC)Ni(0) complex.

Authors:  Chang Hoon Lee; David S Laitar; Peter Mueller; Joseph P Sadighi
Journal:  J Am Chem Soc       Date:  2007-10-18       Impact factor: 15.419

8.  Carbon dioxide activation at the Ni,Fe-cluster of anaerobic carbon monoxide dehydrogenase.

Authors:  Jae-Hun Jeoung; Holger Dobbek
Journal:  Science       Date:  2007-11-30       Impact factor: 47.728

9.  Trinuclear Nickel Complexes with Metal-Arene Interactions Supported by Tris- and Bis(phosphinoaryl)benzene Frameworks.

Authors:  Sandy Suseno; Kyle T Horak; Michael W Day; Theodor Agapie
Journal:  Organometallics       Date:  2013-12-09       Impact factor: 3.876

10.  Arene non-innocence in dinuclear complexes of Fe, Co, and Ni supported by a para-terphenyl diphosphine.

Authors:  Kyle T Horak; Alexandra Velian; Michael W Day; Theodor Agapie
Journal:  Chem Commun (Camb)       Date:  2014-03-19       Impact factor: 6.222
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  1 in total

1.  Mg3N2-assisted one-pot synthesis of 1,3-disubstituted imidazo[1,5-a]pyridine.

Authors:  Suhas G Patil; Jagannath S Jadhav; Sagar T Sankpal
Journal:  RSC Adv       Date:  2020-03-23       Impact factor: 4.036
  1 in total

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