Literature DB >> 22785444

CO oxidation at nickel centres by N2O or O2 to yield a novel hexanuclear carbonate.

Bettina Horn1, Christian Limberg, Christian Herwig, Michael Feist, Stefan Mebs.   

Abstract

Reaction of a nickel(0) carbonyl complex, K(2)[L(tBu)NiCO](2), with N(2)O generates a cyclic carbonate compound composed of six [Ni(II)(CO(3))K](+) units. The same product can also be obtained using O(2) as the oxidant in a solid-state/gas reaction. These conversions represent unique examples of a nickel-bound CO oxidation by N(2)O and O(2), respectively.

Entities:  

Year:  2012        PMID： 22785444     DOI： 10.1039/c2cc33846g

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  3 in total

1.  Carbon Dioxide Cleavage by a Ni2 Complex Supported by a Binucleating Bis(N-Heterocyclic Carbene) Framework.

Authors:  Emily Y Tsui; Theodor Agapie
Journal:  Polyhedron       Date:  2014-07-02       Impact factor: 3.052

2.  Multimetallic Cooperativity in Activation of Dinitrogen at Iron-Potassium Sites.

Authors:  Karen P Chiang; Sarina M Bellows; William W Brennessel; Patrick L Holland
Journal:  Chem Sci       Date:  2014-01-01       Impact factor: 9.825

3.  Synthesis and reactivity of a nickel(ii) thioperoxide complex: demonstration of sulfide-mediated N2O reduction.

Authors:  Nathaniel J Hartmann; Guang Wu; Trevor W Hayton
Journal:  Chem Sci       Date:  2018-06-27       Impact factor: 9.825
  3 in total

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