Warning: Undefined array key "mm" in /www/wwwroot/www.ai-bt.com/si.php on line 10 Deprecated: trim(): Passing null to parameter #1 ($string) of type string is deprecated in /www/wwwroot/www.ai-bt.com/si.php on line 10 Arene non-innocence in dinuclear complexes of Fe, Co, and Ni supported by a para-terphenyl diphosphine.

Literature DB >> 24643352

Arene non-innocence in dinuclear complexes of Fe, Co, and Ni supported by a para-terphenyl diphosphine.

Kyle T Horak¹, Alexandra Velian, Michael W Day, Theodor Agapie.

Abstract

Cofacial Fe2, Co2, and Ni2 complexes supported by a para-terphenyl diphosphine ligand were prepared. Central arene deplanarization and a μ2:(η(3),η(3)) coordination mode suggest partial bisallyl character in the Fe2 and Co2 complexes. An oxidation induced shift in Fe2-arene binding highlights the non-innocent nature of the arene ligand.

Entities: Chemical

Year: 2014 PMID： 24643352 DOI： 10.1039/c4cc00838c

Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222

Keyword Cloud
Cited

7 in total

1. Four-electron deoxygenative reductive coupling of carbon monoxide at a single metal site.

Authors: Joshua A Buss; Theodor Agapie
Journal: Nature Date: 2015-12-21 Impact factor: 49.962

2. Carbon Dioxide Cleavage by a Ni₂ Complex Supported by a Binucleating Bis(N-Heterocyclic Carbene) Framework.

Authors: Emily Y Tsui; Theodor Agapie
Journal: Polyhedron Date: 2014-07-02 Impact factor: 3.052

3. Nitrogenase-Relevant Reactivity of a Synthetic Iron-Sulfur-Carbon Site.

Authors: Amy L Speelman; Ilija Čorić; Casey Van Stappen; Serena DeBeer; Brandon Q Mercado; Patrick L Holland
Journal: J Am Chem Soc Date: 2019-08-12 Impact factor: 15.419

4. Oxidative Coupling with Zr(IV) Supported by a Noninnocent Anthracene-Based Ligand: Application to the Catalytic Cotrimerization of Alkynes and Nitriles to Pyrimidines.

Authors: Choon Heng Low; Jeffrey N Rosenberg; Marco A Lopez; Theodor Agapie
Journal: J Am Chem Soc Date: 2018-09-14 Impact factor: 15.419

Arene non-innocence in dinuclear complexes of Fe, Co, and Ni supported by a para-terphenyl diphosphine.

1. Four-electron deoxygenative reductive coupling of carbon monoxide at a single metal site.

2. Carbon Dioxide Cleavage by a Ni₂ Complex Supported by a Binucleating Bis(N-Heterocyclic Carbene) Framework.

3. Nitrogenase-Relevant Reactivity of a Synthetic Iron-Sulfur-Carbon Site.

4. Oxidative Coupling with Zr(IV) Supported by a Noninnocent Anthracene-Based Ligand: Application to the Catalytic Cotrimerization of Alkynes and Nitriles to Pyrimidines.

Review 5. Tuning metal-metal interactions for cooperative small molecule activation.

6. Molybdenum catalyzed ammonia borane dehydrogenation: oxidation state specific mechanisms.

7. Radical-Type Reactivity and Catalysis by Single-Electron Transfer to or from Redox-Active Ligands.

Arene non-innocence in dinuclear complexes of Fe, Co, and Ni supported by a para-terphenyl diphosphine.

1. Four-electron deoxygenative reductive coupling of carbon monoxide at a single metal site.

2. Carbon Dioxide Cleavage by a Ni2 Complex Supported by a Binucleating Bis(N-Heterocyclic Carbene) Framework.

3. Nitrogenase-Relevant Reactivity of a Synthetic Iron-Sulfur-Carbon Site.

4. Oxidative Coupling with Zr(IV) Supported by a Noninnocent Anthracene-Based Ligand: Application to the Catalytic Cotrimerization of Alkynes and Nitriles to Pyrimidines.

Review 5. Tuning metal-metal interactions for cooperative small molecule activation.

6. Molybdenum catalyzed ammonia borane dehydrogenation: oxidation state specific mechanisms.

7. Radical-Type Reactivity and Catalysis by Single-Electron Transfer to or from Redox-Active Ligands.

2. Carbon Dioxide Cleavage by a Ni₂ Complex Supported by a Binucleating Bis(N-Heterocyclic Carbene) Framework.