Literature DB >> 30244574

Site-Selective Ni-Catalyzed Reductive Coupling of α-Haloboranes with Unactivated Olefins.

Shang-Zheng Sun1, Marino Börjesson1, Raul Martin-Montero1, Ruben Martin1,2.   

Abstract

A mild, chemo- and site-selective catalytic protocol that allows for incorporating an alkylboron fragment into unactivated olefins is described. The use of internal olefins enables C-C bond-formation at remote sp3 C-H sites, constituting a complementary and conceptually different approach to existing borylation techniques that are currently available at sp3 centers.

Entities:  

Year:  2018        PMID: 30244574     DOI: 10.1021/jacs.8b09425

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN: 0002-7863            Impact factor:   15.419


  19 in total

1.  Recent Advances in Radical Addition to Alkenylboron Compounds.

Authors:  Gabriel J Lovinger; James P Morken
Journal:  European J Org Chem       Date:  2019-11-21

2.  Low-Valent Tungsten Catalysis Enables Site-Selective Isomerization-Hydroboration of Unactivated Alkenes.

Authors:  Tanner C Jankins; Raul Martin-Montero; Phillippa Cooper; Ruben Martin; Keary M Engle
Journal:  J Am Chem Soc       Date:  2021-09-09       Impact factor: 16.383

3.  Regio- and enantioselective remote hydroarylation using a ligand-relay strategy.

Authors:  Yuli He; Jiawei Ma; Huayue Song; Yao Zhang; Yong Liang; You Wang; Shaolin Zhu
Journal:  Nat Commun       Date:  2022-05-05       Impact factor: 17.694

4.  Electrochemically driven cross-electrophile coupling of alkyl halides.

Authors:  Wen Zhang; Lingxiang Lu; Wendy Zhang; Yi Wang; Skyler D Ware; Jose Mondragon; Jonas Rein; Neil Strotman; Dan Lehnherr; Kimberly A See; Song Lin
Journal:  Nature       Date:  2022-02-21       Impact factor: 69.504

5.  Mechanism of Ni-Catalyzed Reductive 1,2-Dicarbofunctionalization of Alkenes.

Authors:  Qiao Lin; Tianning Diao
Journal:  J Am Chem Soc       Date:  2019-10-28       Impact factor: 15.419

6.  Development and Mechanistic Interrogation of Interrupted Chain-Walking in the Enantioselective Relay Heck Reaction.

Authors:  Sean P Ross; Ajara A Rahman; Matthew S Sigman
Journal:  J Am Chem Soc       Date:  2020-05-29       Impact factor: 15.419

7.  Hydroalkylation of Olefins To Form Quaternary Carbons.

Authors:  Samantha A Green; Tucker R Huffman; Ruairí O McCourt; Vincent van der Puyl; Ryan A Shenvi
Journal:  J Am Chem Soc       Date:  2019-05-03       Impact factor: 15.419

8.  Enantioselective access to chiral aliphatic amines and alcohols via Ni-catalyzed hydroalkylations.

Authors:  Shan Wang; Jian-Xin Zhang; Tian-Yi Zhang; Huan Meng; Bi-Hong Chen; Wei Shu
Journal:  Nat Commun       Date:  2021-05-13       Impact factor: 14.919

9.  Nickel-catalysed selective migratory hydrothiolation of alkenes and alkynes with thiols.

Authors:  Yulong Zhang; Xianfeng Xu; Shaolin Zhu
Journal:  Nat Commun       Date:  2019-04-15       Impact factor: 14.919

10.  Ru-catalyzed isomerization of ω-alkenylboronates towards stereoselective synthesis of vinylboronates with subsequent in situ functionalization.

Authors:  Guo-Ming Ho; Lucas Segura; Ilan Marek
Journal:  Chem Sci       Date:  2020-05-26       Impact factor: 9.825

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