Recent Advances in Radical Addition to Alkenylboron Compounds.

The addition of carbon-centered radicals to alkenylboron compounds provides a useful method for the construction of organoboron reagents which are versatile reagents in chemical synthesis. While the first examples of this type or process appeared 70 years ago, until recently, attention to this type of reaction has been limited. A number of examples of this reactivity have been demonstrated recently, and strategies are emerging that allow for tuning the reagent structure in order to modulate reactivity. This review surveys recent advances in this class of reaction.