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Literature DB >> 29584438

Ruthenium(II)-Catalyzed Regio- and Stereoselective C-H Allylation of Indoles with Allyl Alcohols.

Abstract

A ruthenium-catalyzed C-H allylation of indoles with allyl alcohols via β-hydroxide elimination is reported. Without external oxidants and expensive additives, this reaction features mild reaction conditions, compatibility with various functional groups, and good to excellent regioselectivity and stereoselectivity.

Entities: Chemical Disease Gene

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Year: 2018 PMID： 29584438 PMCID： PMC7771326 DOI： 10.1021/acs.orglett.8b00567

Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005

40 in total

1. On the interpretation of deuterium kinetic isotope effects in C-H bond functionalizations by transition-metal complexes.

Authors: Eric M Simmons; John F Hartwig
Journal: Angew Chem Int Ed Engl Date: 2012-03-05 Impact factor: 15.336

2. Highly selective mild stepwise allylation of N-methoxybenzamides with allenes.

Authors: Rong Zeng; Chunling Fu; Shengming Ma
Journal: J Am Chem Soc Date: 2012-06-04 Impact factor: 15.419

3. Copper-catalyzed C-H functionalization reactions: efficient synthesis of heterocycles.

Authors: Xun-Xiang Guo; Da-Wei Gu; Zhengxing Wu; Wanbin Zhang
Journal: Chem Rev Date: 2014-12-22 Impact factor: 60.622

4. Rhodium(III)-catalyzed C-C coupling of arenes with 2-vinyloxiranes: synthesis of allylic alcohols.

Authors: Songjie Yu; Xingwei Li
Journal: Org Lett Date: 2014-02-07 Impact factor: 6.005

5. Ruthenium-Catalyzed, Site-Selective C-H Allylation of Indoles with Allyl Alcohols as Coupling Partners.

Authors: Gangam Srikanth Kumar; Manmohan Kapur
Journal: Org Lett Date: 2016-02-19 Impact factor: 6.005

6. Rhodium-catalysed direct C-H allylation of N-sulfonyl ketimines with allyl carbonates.

Authors: Shu-Tao Mei; Nan-Jin Wang; Qin Ouyang; Ye Wei
Journal: Chem Commun (Camb) Date: 2015-02-18 Impact factor: 6.222

7. Analysis of the concerted metalation-deprotonation mechanism in palladium-catalyzed direct arylation across a broad range of aromatic substrates.

Authors: Serge I Gorelsky; David Lapointe; Keith Fagnou
Journal: J Am Chem Soc Date: 2008-07-29 Impact factor: 15.419

8. Temperature-controlled redox-neutral ruthenium(ii)-catalyzed regioselective allylation of benzamides with allylic acetates.

Authors: Rajendran Manikandan; Masilamani Jeganmohan
Journal: Org Biomol Chem Date: 2016-08-10 Impact factor: 3.876

9. Cp*Rh(III)-Catalyzed Low Temperature C-H Allylation of N-Aryl-trichloro Acetimidamide.

Authors: Suvankar Debbarma; Sourav Sekhar Bera; Modhu Sudan Maji
Journal: J Org Chem Date: 2016-11-17 Impact factor: 4.354

10. Ruthenium(II)-catalyzed oxidative C-H alkenylations of sulfonic acids, sulfonyl chlorides and sulfonamides.

Authors: Wenbo Ma; Ruhuai Mei; Giammarco Tenti; Lutz Ackermann
Journal: Chemistry Date: 2014-10-03 Impact factor: 5.236

5 in total

1. Ruthenium-Catalyzed C-H Allylation of Alkenes with Allyl Alcohols via C-H Bond Activation in Aqueous Solution.

Authors: Xiaowei Wu; Haitao Ji
Journal: J Org Chem Date: 2018-09-21 Impact factor: 4.354

Review 2. Recent advances in theoretical studies on transition-metal-catalyzed regioselective C-H functionalization of indoles.

Authors: Hongsheng Ma; Tongyan Yu; Longxiao Chi; Cong Huang; Xuwen Li; Rui Zhang; Chao Deng
Journal: J Mol Model Date: 2022-08-22 Impact factor: 2.172