Literature DB >> 24506454

Rhodium(III)-catalyzed C-C coupling of arenes with 2-vinyloxiranes: synthesis of allylic alcohols.

Songjie Yu1, Xingwei Li.   

Abstract

A rhodium(III)-catalyzed C-C coupling between 2-vinyloxiranes and arenes directed by different chelating groups has been realized via a C-H activation pathway. This reaction proceeded under conditions with a low catalyst loading, and allylic alcohols were isolated as the coupling products. A series of benzoazepanes has been synthesized by following this coupling.

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Year:  2014        PMID： 24506454     DOI： 10.1021/ol5000764

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  8 in total

1.  Ruthenium-Catalyzed C-H Allylation of Alkenes with Allyl Alcohols via C-H Bond Activation in Aqueous Solution.

Authors:  Xiaowei Wu; Haitao Ji
Journal:  J Org Chem       Date:  2018-09-21       Impact factor: 4.354

2.  A combined experimental and DFT mechanistic study for the unexpected nitrosolysis of N-hydroxymethyldialkylamines in fuming nitric acid.

Authors:  Yu Zhang; Po Zou; Yingbin Han; Yongliang Geng; Jun Luo; Baojing Zhou
Journal:  RSC Adv       Date:  2018-05-24       Impact factor: 4.036

3.  Ruthenium(II)-Catalyzed Regio- and Stereoselective C-H Allylation of Indoles with Allyl Alcohols.

Authors:  Xiaowei Wu; Haitao Ji
Journal:  Org Lett       Date:  2018-03-27       Impact factor: 6.005

4.  Rhodium(iii)-catalyzed C-H allylation of indoles with allyl alcohols via β-hydroxide elimination.

Authors:  Xiaowei Wu; Haitao Ji
Journal:  Org Biomol Chem       Date:  2018-08-08       Impact factor: 3.876

5.  Ru-catalysed C-H arylation of indoles and pyrroles with boronic acids: scope and mechanistic studies.

Authors:  Carina Sollert; Karthik Devaraj; Andreas Orthaber; Paul J Gates; Lukasz T Pilarski
Journal:  Chemistry       Date:  2015-02-17       Impact factor: 5.236

6.  Manganese-catalyzed allylation via sequential C-H and C-C/C-Het bond activation.

Authors:  Qingquan Lu; Felix J R Klauck; Frank Glorius
Journal:  Chem Sci       Date:  2017-02-24       Impact factor: 9.825

7.  Rhodium(III)-Catalyzed Redox-Neutral [3+3] Annulation of N-nitrosoanilines with Cyclopropenones: A Traceless Approach to Quinolin-4(1H)-One Scaffolds.

Authors:  Lingjun Liu; Jiyuan Li; Wenhao Dai; Feng Gao; Kaixian Chen; Yu Zhou; Hong Liu
Journal:  Molecules       Date:  2020-01-09       Impact factor: 4.411

8.  Iridium-Catalyzed Enantioselective Intermolecular Indole C2-Allylation.

Authors:  James A Rossi-Ashton; Aimee K Clarke; James R Donald; Chao Zheng; Richard J K Taylor; William P Unsworth; Shu-Li You
Journal:  Angew Chem Int Ed Engl       Date:  2020-03-11       Impact factor: 15.336
  8 in total

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