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Literature DB >> 30047974

Rhodium(iii)-catalyzed C-H allylation of indoles with allyl alcohols via β-hydroxide elimination.

Abstract

An efficient Rh(iii)-catalyzed dehydrative C-H allylation of indoles with allyl alcohols via β-hydroxide elimination under oxidant-free conditions has been developed. This method features very mild reaction conditions, excellent regioselectivity and stereoselectivity, and compatibility with various functional groups. In addition, the directing group can be removed under mild reaction conditions, which further underscores the synthetic utility of this method.

Entities: Chemical Disease Species

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Year: 2018 PMID： 30047974 PMCID： PMC6135611 DOI： 10.1039/c8ob01394b

Source DB: PubMed Journal: Org Biomol Chem ISSN： 1477-0520 Impact factor: 3.876

35 in total

1. On the interpretation of deuterium kinetic isotope effects in C-H bond functionalizations by transition-metal complexes.

Authors: Eric M Simmons; John F Hartwig
Journal: Angew Chem Int Ed Engl Date: 2012-03-05 Impact factor: 15.336

2. Mild Rh(III)-catalyzed C7-allylation of indolines with allylic carbonates.

Authors: Jihye Park; Neeraj Kumar Mishra; Satyasheel Sharma; Sangil Han; Youngmi Shin; Taejoo Jeong; Joa Sub Oh; Jong Hwan Kwak; Young Hoon Jung; In Su Kim
Journal: J Org Chem Date: 2015-01-20 Impact factor: 4.354

3. Manganese(I)-Catalyzed Dispersion-Enabled C-H/C-C Activation.

Authors: Tjark H Meyer; Weiping Liu; Milica Feldt; Axel Wuttke; Ricardo A Mata; Lutz Ackermann
Journal: Chemistry Date: 2017-04-03 Impact factor: 5.236

4. Weakly Coordinating, Ketone-Directed Cp*Co(III)-Catalyzed C-H Allylation on Arenes and Indoles.

Authors: Md Raja Sk; Sourav Sekhar Bera; Modhu Sudan Maji
Journal: Org Lett Date: 2017-12-19 Impact factor: 6.005

5. Rhodium(III)-Catalyzed Regio- and Stereoselective C-H Allylation of Arenes with Vinyl Benzoxazinanones.

Authors: Zisong Qi; Lingheng Kong; Xingwei Li
Journal: Org Lett Date: 2016-08-24 Impact factor: 6.005

6. Temperature-controlled redox-neutral ruthenium(ii)-catalyzed regioselective allylation of benzamides with allylic acetates.

Authors: Rajendran Manikandan; Masilamani Jeganmohan
Journal: Org Biomol Chem Date: 2016-08-10 Impact factor: 3.876

Rhodium(iii)-catalyzed C-H allylation of indoles with allyl alcohols via β-hydroxide elimination.

1. On the interpretation of deuterium kinetic isotope effects in C-H bond functionalizations by transition-metal complexes.

2. Mild Rh(III)-catalyzed C7-allylation of indolines with allylic carbonates.

3. Manganese(I)-Catalyzed Dispersion-Enabled C-H/C-C Activation.

4. Weakly Coordinating, Ketone-Directed Cp*Co(III)-Catalyzed C-H Allylation on Arenes and Indoles.

5. Rhodium(III)-Catalyzed Regio- and Stereoselective C-H Allylation of Arenes with Vinyl Benzoxazinanones.

6. Temperature-controlled redox-neutral ruthenium(ii)-catalyzed regioselective allylation of benzamides with allylic acetates.

7. Oxidant-free Rh(III)-catalyzed direct C-H olefination of arenes with allyl acetates.

8. Direct allylation of aromatic and α,β-unsaturated carboxamides under ruthenium catalysis.

9. Rhodium-Catalyzed C-H Alkylation of Indolines with Allylic Alcohols: Direct Access to β-Aryl Carbonyl Compounds.

10. Manganese-catalyzed allylation via sequential C-H and C-C/C-Het bond activation.

1. Iridium-Catalyzed Enantioselective Intermolecular Indole C2-Allylation.