Literature DB >> 28480467

A CaMn4O2 model of the biological oxygen evolving complex: synthesis via cluster expansion on a low symmetry ligand.

Heui Beom Lee1, Emily Y Tsui, Theodor Agapie.   

Abstract

Using a new multinucleating ligand featuring two dipyridyl alkoxide moieties and a carboxylate moiety, low symmetry tetranuclear complexes 1-M (M = Mn, Fe, and Co) have been synthesized. Complex 1-Mn was used as a precursor for the synthesis of a pentanuclear CaMn4O2 cluster (3) with the same metal stoichiometry as the biological OEC.

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Year:  2017        PMID: 28480467      PMCID: PMC5508601          DOI: 10.1039/c7cc02313h

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  28 in total

1.  A series of new structural models for the OEC in photosystem II.

Authors:  Ian J Hewitt; Jin-Kui Tang; N T Madhu; Rodolphe Clérac; Gernot Buth; Christopher E Anson; Annie K Powell
Journal:  Chem Commun (Camb)       Date:  2006-03-02       Impact factor: 6.222

2.  Trinucleating copper: synthesis and magnetostructural characterization of complexes supported by a hexapyridyl 1,3,5-triarylbenzene ligand.

Authors:  Emily Y Tsui; Michael W Day; Theodor Agapie
Journal:  Angew Chem Int Ed Engl       Date:  2011-01-11       Impact factor: 15.336

3.  Towards models of the oxygen-evolving complex (OEC) of photosystem II: a Mn4Ca cluster of relevance to low oxidation states of the OEC.

Authors:  Evangelia S Koumousi; Shreya Mukherjee; Christine M Beavers; Simon J Teat; George Christou; Theocharis C Stamatatos
Journal:  Chem Commun (Camb)       Date:  2011-09-09       Impact factor: 6.222

4.  Controllable formation of heterotrimetallic coordination compounds: systematically incorporating lanthanide and alkali metal ions into the manganese 12-metallacrown-4 framework.

Authors:  Michael R Azar; Thaddeus T Boron; Jacob C Lutter; Connor I Daly; Kelcie A Zegalia; Ruthairat Nimthong; Gregory M Ferrence; Matthias Zeller; Jeff W Kampf; Vincent L Pecoraro; Curtis M Zaleski
Journal:  Inorg Chem       Date:  2014-01-13       Impact factor: 5.165

5.  The effects of redox-inactive metal ions on the activation of dioxygen: isolation and characterization of a heterobimetallic complex containing a Mn(III)-(μ-OH)-Ca(II) core.

Authors:  Young Jun Park; Joseph W Ziller; A S Borovik
Journal:  J Am Chem Soc       Date:  2011-05-31       Impact factor: 15.419

6.  Trigonal propeller-shaped [Mn(III)3M(II)Na] complexes (M = Mn, Ca): structural and functional models for the dioxygen evolving centre of PSII.

Authors:  Sanjit Nayak; Hari Pada Nayek; Stefanie Dehnen; Annie K Powell; Jan Reedijk
Journal:  Dalton Trans       Date:  2011-02-15       Impact factor: 4.390

7.  Emissive {Mn4(III)Ca} clusters with square pyramidal topologies: syntheses and structural, spectroscopic, and physicochemical characterization.

Authors:  Alysha A Alaimo; Daisuke Takahashi; Luís Cunha-Silva; George Christou; Theocharis C Stamatatos
Journal:  Inorg Chem       Date:  2014-12-05       Impact factor: 5.165

8.  Synthetic cluster models of biological and heterogeneous manganese catalysts for O2 evolution.

Authors:  Emily Y Tsui; Jacob S Kanady; Theodor Agapie
Journal:  Inorg Chem       Date:  2013-12-16       Impact factor: 5.165

9.  Development of bioinspired Mn4O4-cubane water oxidation catalysts: lessons from photosynthesis.

Authors:  G Charles Dismukes; Robin Brimblecombe; Greg A N Felton; Ruslan S Pryadun; John E Sheats; Leone Spiccia; Gerhard F Swiegers
Journal:  Acc Chem Res       Date:  2009-12-21       Impact factor: 22.384

Review 10.  Mn4Ca cluster in photosynthesis: where and how water is oxidized to dioxygen.

Authors:  Junko Yano; Vittal Yachandra
Journal:  Chem Rev       Date:  2014-03-31       Impact factor: 60.622

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  4 in total

1.  Tetranuclear [MnIIIMn3IVO4] Complexes as Spectroscopic Models of the S2 State of the Oxygen Evolving Complex in Photosystem II.

Authors:  Heui Beom Lee; Angela A Shiau; Paul H Oyala; David A Marchiori; Sheraz Gul; Ruchira Chatterjee; Junko Yano; R David Britt; Theodor Agapie
Journal:  J Am Chem Soc       Date:  2018-11-30       Impact factor: 15.419

2.  S = 3 Ground State for a Tetranuclear MnIV4O4 Complex Mimicking the S3 State of the Oxygen-Evolving Complex.

Authors:  Heui Beom Lee; David A Marchiori; Ruchira Chatterjee; Paul H Oyala; Junko Yano; R David Britt; Theodor Agapie
Journal:  J Am Chem Soc       Date:  2020-02-18       Impact factor: 15.419

3.  Revealing redox isomerism in trichromium imides by anomalous diffraction.

Authors:  Amymarie K Bartholomew; Rebecca A Musgrave; Kevin J Anderton; Cristin E Juda; Yuyang Dong; Wei Bu; Su-Yin Wang; Yu-Sheng Chen; Theodore A Betley
Journal:  Chem Sci       Date:  2021-11-03       Impact factor: 9.825

4.  CaMn3 IV O4 Cubane Models of the Oxygen-Evolving Complex: Spin Ground States S<9/2 and the Effect of Oxo Protonation.

Authors:  Heui Beom Lee; Angela A Shiau; David A Marchiori; Paul H Oyala; Byung-Kuk Yoo; Jens T Kaiser; Douglas C Rees; R David Britt; Theodor Agapie
Journal:  Angew Chem Int Ed Engl       Date:  2021-07-01       Impact factor: 16.823

  4 in total

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