Literature DB >> 27573816

Near-optimal protocols in complex nonequilibrium transformations.

Todd R Gingrich1, Grant M Rotskoff2, Gavin E Crooks3, Phillip L Geissler4.   

Abstract

The development of sophisticated experimental means to control nanoscale systems has motivated efforts to design driving protocols that minimize the energy dissipated to the environment. Computational models are a crucial tool in this practical challenge. We describe a general method for sampling an ensemble of finite-time, nonequilibrium protocols biased toward a low average dissipation. We show that this scheme can be carried out very efficiently in several limiting cases. As an application, we sample the ensemble of low-dissipation protocols that invert the magnetization of a 2D Ising model and explore how the diversity of the protocols varies in response to constraints on the average dissipation. In this example, we find that there is a large set of protocols with average dissipation close to the optimal value, which we argue is a general phenomenon.

Entities:  

Keywords:  Ising model; Metropolis algorithm; entropic sampling methods; irreversible thermodynamics; nonequilibrium

Year:  2016        PMID: 27573816      PMCID: PMC5027427          DOI: 10.1073/pnas.1606273113

Source DB:  PubMed          Journal:  Proc Natl Acad Sci U S A        ISSN: 0027-8424            Impact factor:   11.205


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