Literature DB >> 27446724

Argon I Lines Produced in a Hollow Cathode Source, 332 nm to 5865 nm.

W Whaling1, W H C Anderson1, M T Carle1, J W Brault2, H A Zarem2.   

Abstract

We report precision measurements by Fourier transform spectroscopy of the vacuum wavenumber, line width, and relative signal strength of 928 lines in the Ar I spectrum. Wavelength in air and classification of the transition are supplied for each line. A comparison of our results with other precision measurements illustrates the sensitivity of Ar I wavelengths to conditions in the light source.

Entities:  

Keywords:  Fourier transform spectroscopy; argon; atomic spectra; pressure shifts; wavelengths

Year:  2002        PMID: 27446724      PMCID: PMC4859259          DOI: 10.6028/jres.10714

Source DB:  PubMed          Journal:  J Res Natl Inst Stand Technol        ISSN: 1044-677X


Foreword

Spectra of the noble gases are frequently observed in laboratory discharges, industrial plasmas, lighting discharges, sources for analytical spectrochemistry, and astrophysical sources. In response to the wide interest in these elements the NIST Atomic Spectroscopy Data Center is currently compiling the spectra and energy levels for all ionization stages of Ne, Ar, Kr, and Xe. A critical review of the literature revealed that no comprehensive description of the infrared spectrum of neutral argon has ever been published. In 1995 observations of the spectrum of singly ionized argon covering the range 222 nm to 5865 nm were published by Whaling, Anderson, Carle, Brault, and Zarem [J. Quant. Spectros. Radiat. Transfer 53, 1 (1995)]. Their measurements, made with the high-resolution Fourier Transform Spectrometer at the National Solar Observatory (Kitt Peak), have been widely used as a source of wavelength standards. Measurements of neutral argon from the same spectra have been circulated as an unpublished line list. This list has been used in a number of laboratories to identify lines of argon in spectral sources and as a source of calibration wavelengths. This article presents the comprehensive list of neutral argon observations from the Kitt Peak spectra over a wide wavelength region from the near ultraviolet to near infrared and describes the experimental conditions under which the measurements were made. It was prepared by Ward Whaling for publication in the NIST Journal of Research with the encouragement and assistance of the Atomic Spectroscopy Data Center in order to make these data available to the broad community of users and to adequately document the work so that its results can be integrated with other available data in our argon compilation. Craig J. Sansonetti NIST Atomic Spectroscopy Data Center

1. Introduction

Argon is frequently used to sustain the discharge in a hollow cathode spectral source, and the source typically excites the first, second, and third spectra of argon as well as the spectrum of the cathode material. Consequently, a complete picture of the argon spectrum is useful in avoiding, or correcting for, interference between argon lines and lines from the cathode material. In this paper we provide such a line list for Ar I; similar line lists for Ar II [1] and Ar III [2] have been published earlier.

2. Experimental Method

Argon lines were obtained by comparing many high-resolution spectra of a hollow cathode discharge in argon, with different cathode materials for the different spectra. By extracting lines common to several spectra, regardless of the cathode material, we have generated a list of lines arising from the argon that supports the discharge, or from a common contaminant as discussed below. All spectra were recorded on the 1 m vacuum Fourier transform spectrometer [3] at the National Solar Observatory (Kitt Peak). Hollow cathode spectra from the Kitt Peak archive with cathodes of Co, Cu, Fe, Mo, Ti, V, and Y were measured for this work; the Kitt Peak National Observatory archive designation of each spectrum is given in Ref. [1]. The cathode cavity was 25 mm long by 8 mm diameter; further details of the water-cooled source will be found in Ref. [1]. The source pressure varied from one spectrum to another between 270 Pa and 530 Pa (2 Torr and 4 Torr) of high purity argon, with discharge currents between 150 mA and 600 mA. All spectra were measured with the DECOMP [4] line-finding program developed by Brault. This program fits a Voigt profile to the spectral feature and records the line-center, peak amplitude, full width at half maximum intensity (FWHM), and other parameters of the Voigt profile.

3. Results

In the first column of Table 1 we list the line-center vacuum wavenumber (in cm−1), followed by the experimental uncertainty in column 2. The ratio of the peak amplitude S to the root mean square background noise N appears in column 3 as the log10(S/N) for each line. Note that the peak amplitude has not been corrected for the spectrometer response. Over the range of a given spectrum, the spectrometer response may vary by an order of magnitude, and the comparison of the signal-to-noise ratio of two lines is a reliable indication of the relative strength of the lines only if they are close in wavelength. The full width of the observed line (in 10−3 cm−1) at half maximum height appears in the 4th column. The absolute value of the line width depends on source and instrumental conditions, but the increased relative width of lines from levels of high excitation and high angular momentum is an aid in identification.
Table 1

Ar I lines observed in the hollow cathode spectrum. The vacuum wavenumber (cm−1) in the first column has been converted to wavelength in standard air in the last column. Upper and lower levels are identified by the integer part of the level energy in cm−1, J-value (or [K]-value if individual J levels are not resolved), and configuration. Descriptive notes at the far right are as follows: B = blended line; R = reversed; ? = uncertain classification

WavenumberUnc.log (S/N)FWHMUpper levelaLower levelaWavelength
(cm−1)(cm−1)(10−3 cm−1)(cm−1)(cm−1)(nm)
1704.5679.00081.102112127126p11956634d5864.9902
1710.0644.00051.231812147006p11976016s5846.1389
1723.0187.00032.231511890724d11718425p5802.1855
1746.9721.00041.361712119226p11944524d5722.6295
1755.2831.00031.711511890724d11715115p5695.5337
1778.6263.00031.451912279106p12101214d5620.7838
1786.1520.00160.842212203645d12025044f5597.1015
1798.3588.00031.771411666015p11486205s5559.1098
1806.8168.00051.301912165524f11984814d5533.0867
1812.3256.00032.261912125716p11944524d5516.2681
1816.7271.00051.181511718425p11536713d5502.9035
1825.7821.00081.152312127126p11944524d5475.6118
1828.9313.00032.152112203645d12020754f5466.1834
1850.9071.00500.483012350525d12165524f5401.2835
1852.2026.00033.531611851204d11666015p5397.5056
1853.5579.00461.009112413635f12228225d5393.5590
1854.8601.00032.151511666015p11480523d5389.7725
1856.8485.00081.112012208725d12023024f5384.0008
1857.1584.00032.502112208725d12023034f5383.1024
1881.5954.00032.981812263526p12075334d5313.1900
1898.2640.00031.712212208725d12018924f5266.5350
1898.6772.00110.952012208725d12018814f5265.3889
1903.1812.00540.503412355735d12165434f5252.9280
1904.1373.00031.942612355735d12165344f5250.2904
1907.2839.00032.361511890724d11699925p5241.6286
1910.2258.00031.451712216035d12025044f5233.5561
1910.2660.00051.614112216035d12025034f5233.4459
1930.0838.00950.475612216035d12023024f5179.7098
1930.3927.00200.842712216035d12023034f5178.8810
1942.2126.00141.437312269645f12075334d5147.3634
1952.4926.00032.511912116536p11921334d5120.2621
1952.9706.00032.482312216035d12020744f5119.0089
1963.8546.00031.771611890724d11694335p5090.6386
1964.3675.00301.30121  12271835f12075334d5089.3094
1971.1566.00200.521312165434f11968326s5071.7807
1975.5468.00430.957612413645f12216035d5060.5098
1978.9326.00033.251812119226p11921334d5051.8517
1990.6309.00032.492012261016p12061924d5022.1635
1991.3992.00033.611511865114d11666015p5020.2259
2000.3339.00031.572112260116p12060124d4997.8026
2007.1430.00110.701112471537d12270835f4980.8478
2010.6171.00350.673312317217p12116116s4972.2416
2024.3074.00031.751511699925p11497515s4938.6145
2029.2808.00032.471611921334d11718425p4926.5108
2032.2207.00032.202612228225d12025034f4919.3839
2034.1767.00032.201912263526p12060124d4914.6536
2050.2908.00121.527812413735f12208725d4876.0273
2052.0339.00041.502612228225d12023024f4871.8853
2057.7439.00031.492112127126p11921334d4858.3664
2067.0419.00540.664912268615f12061924d4836.5124
2067.3880.00231.095612268625f12061924d4835.7027
2075.0395.00041.1311125330210s12325517p4817.8716
2075.3327.00290.672712317217p12109706s4817.1909
2079.7502.00032.242812233035d12025044f4806.9589
2080.8897.00034.771611902444d11694335p4804.3266
2085.5130.00111.456112268625f12060124d4793.6761
2087.2321.00031.731812165344f11956634d4789.7279
2088.1848.00041.341812165434f11956634d4787.5427
2088.8664.00121.568612270835f12061924d4785.9805
2089.1113.00241.197312270825f12061924d4785.4194
2098.7920.00511.21164  12271835f12061924d4763.3466 B
2099.9107.00041.532812233035d12023034f4760.8090
2102.3065.00031.713112337325d12127126p4755.3836
2106.9917.00051.867812270835f12060124d4744.8093
2115.7642.00240.782912337325d12125716p4725.1361
2120.5669.00071.242512377436d12165344f4714.4345
2120.8171.00033.141511694335p11482233d4713.8783
2122.4890.00071.383212233035d12020744f4710.1652
2131.8359.00033.341712060124d11846925p4689.5137
2140.9990.00033.561912101214d11887105p4669.4434
2141.2904.00033.841712060124d11846015p4668.8080
2141.7196.00033.681912116536p11902444d4667.8724
2149.9613.00032.001612061924d11846925p4649.9785
2153.0756.01330.97249  12487147g12271845f4643.2525
2154.2720.00330.844512380926d12165434f4640.6738
2155.2844.00051.161512380926d12165334f4638.4940
2159.4158.00033.601712061924d11846015p4629.6196
2160.9803.00290.934912381615d12165524f4626.2679
2162.1254.00032.662012106916p11890724d4623.8177
2171.5873.01880.93320  12486757g12269655f4603.6711
2176.3085.00032.141511715115p11497515s4593.6841
2177.3877.00032.821511699925p11482233d4591.4073
2193.4579.00033.571712060124d11840715p4557.7687
2194.1919.00032.631511699925p11480523d4556.2440
2196.0919.00031.841611756305p11536713d4552.3021
2196.7152.00080.991612435728p12216035d4551.0104
2197.2121.00033.701711976016s11756305p4549.9812
2204.5860.00151.377112413725f12193315d4534.7624
2208.4057.00032.651812165334f11944524d4526.9190
2208.5727.00033.141511718425p11497515s4526.5767
2209.3987.00051.251812165434f11944524d4524.8844
2209.7454.00031.571912165524f11944524d4524.1744
2211.5834.00034.031712061924d11840715p4520.4145
2213.5460.00034.461611921334d11699925p4516.4065
2246.6156.00033.991611890724d11666015p4449.9264
2248.3218.00110.951912350525d12125716p4446.5494
2251.7588.00440.563212350906d12125716p4439.7624
2258.7548.00051.271812116536p11890724d4426.0112
2261.2421.00032.981711944524d11718425p4421.1427
2270.1168.00033.751611921334d11694335p4403.8589
2284.4171.00034.271712075334d11846925p4376.2910
2284.8056.00033.971911984814d11756305p4375.5469
2285.1957.00032.022012119226p11890724d4374.7999
2289.6911.00032.361511715115p11486205s4366.2108
2290.3931.00032.401712116116s11887105p4364.8726
2293.5068.00034.181711944524d11715115p4358.9467
2301.7641.00031.981611694335p11464123d4343.3095
2312.9381.00351.129312434938p12203645d4322.3266
2313.6761.00140.902212350525d12119226p4320.9479
2325.5328.00091.323812251415d12018924f4298.9176
2346.1926.00032.481611715115p11480523d4261.0628
2350.5497.00032.291912125716p11890724d4253.1642
2358.3348.00033.051511699925p11464123d4239.1241
2361.6531.00032.941611718425p11482233d4233.1678
2364.0065.00033.301912127126p11890724d4228.9536
2365.6102.00081.172412355735d12119226p4226.0867
2378.4572.00033.681611718425p11480523d4203.2599
2382.4561.00034.391711956634d11718425p4196.2049
2392.0485.00180.852512355735d12116536p4179.3776
2399.2345.00081.333312346816d12106916p4166.8598
2417.3418.00032.912012106916p11865114d4135.6476
2440.1867.00151.023112350906d12106916p4096.9299
2440.4078.00032.961812165344f11921334d4096.5587
2441.3600.00031.601712165434f11921334d4094.9609
2441.7057.00180.711812165524f11921334d4094.3811
2445.5073.00033.971711944524d11699925p4088.0163
2459.5585.00380.9669122709[2.5]5g12025044f4064.6619 B
2459.5811.01030.76119  122709[2.5]5g12025034f4064.6246 B
2465.6143.00630.483812393618s12147006p4054.6787
2469.5656.00032.3766122719[3.5]5g12025044f4048.1912 B
2469.5987.00032.43100  122719[3.5]5g12025034f4048.1370 B
2473.0739.00033.0744122723[4.5]5g12025044f4042.4484 B
2473.1102.00033.478712272345g12025034f4042.3891
2479.4116.00032.1829122709[2.5]5g12023024f4032.1154
2479.7056.00032.4857122709[2.5]5g12023034f4031.6374 B
2487.7965.00121.143412365346d12116536p4018.5255
2489.4120.00033.186512271935g12023024f4015.9177
2489.7220.00033.3267122719[3.5]5g12023034f4015.4177 B
2493.9253.00032.865712414935g12165524f4008.6500
2494.2737.00033.0057124148[3.5]5g12165434f4008.0901 B
2495.0047.00033.2588124148[3.5]5g12165334f4006.9158 B
2495.2332.00131.61102  124148[3.5]5g12165344f4006.5489 B
2499.4868.00033.751711968326s11718425p3999.7305
2502.0780.00032.741711944524d11694335p3995.5883
2505.6623.00033.4839122713[5.5]5g12020744f3989.8727 B
2505.7057.00033.6958122713[5.5]5g12020754f3989.8036 B
2510.3355.00033.361611715115p11464123d3982.4453
2512.2643.00031.761811666015p11414813d3979.3877
2512.3413.00480.9892122719[3.5]5g120207[4.5]4f3979.2658 B
2515.8301.00032.1978122723[4.5]5g12020744f3973.7475 B
2515.8629.00032.26109  122723[4.5]5g12020754f3973.6957 B
2520.8112.00033.3156122709[2.5]5g12018924f3965.8955 B
2521.2210.00033.086012270925g12018814f3965.2508
2531.7513.00032.901711968326s11715115p3948.7582
2542.8637.00033.201912101214d11846925p3931.5020
2552.3181.00032.941912101214d11846015p3916.9387
2556.5390.00032.562112106916p11851204d3910.4718
2566.7213.00033.551711956634d11699925p3894.9588
2571.0392.01360.447512317217p12060124d3888.4174
2576.5772.00033.431711976016s11718425p3880.0598
2587.9374.00031.731611756305p11497515s3863.0276
2604.4858.00032.761912101214d11840715p3838.4827
2605.7661.00032.192012125716p11865114d3836.5967
2608.8419.00033.801711976016s11715115p3832.0734
2619.2228.00032.422012127126p11865114d3816.8855
2623.2920.00033.861811956634d11694335p3810.9648
2625.0351.00141.002812388217s12125716p3808.4342
2632.5850.00171.164812390328s12127126p3797.5122
2637.0050.00033.181912109706s11846015p3791.1470
2664.1706.00032.521911984814d11718425p3752.4900
2665.2399.00300.904812393618s12127126p3750.9845
2678.6952.00211.125512393618s12125716p3732.1430
2683.7523.00033.441811968326s11699925p3725.1104
2689.1726.00033.271812109706s11840715p3717.6021
2690.3873.00121.022612388217s12119226p3715.9236
2692.2580.00033.861812116116s11846925p3713.3416
2696.4354.00034.111911984814d11715115p3707.5888
2701.7123.00033.651812116116s11846015p3700.3473
2711.4036.00031.981512390328s12119226p3687.1212 B
2725.0243.00670.656012533508s12261016p3668.6916
2737.8368.00061.594412390328s12116536p3651.5229
2740.3226.00034.281811968326s11694335p3648.2105
2744.0525.00091.374012393618s12119226p3643.2516
2744.9632.00031.722112125716p11851204d3642.0429
2747.6223.00033.571812165434f11890724d3638.5182
2747.9691.00032.441812165524f11890724d3638.0590
2753.4613.00260.702612260116p11984814d3630.8023
2753.8798.00033.821812116116s11840715p3630.2505
2760.8424.00034.081811976016s11699925p3621.0954
2784.8409.00120.851711944524d11666015p3589.8904
2813.4539.00390.603112388217s12106916p3553.3810
2818.8415.00032.032012147006p11865114d3546.5895
2834.4679.00171.195412390328s12106916p3527.0371
2838.2967.00231.258312268615f11984814d3522.2792
2838.6384.00032.525812268625f11984814d3521.8552
2848.4359.00032.152011984814d11699925p3509.7414
2851.5955.00032.281711699925p11414813d3505.8526
2860.3627.00032.438112270825f11984814d3495.1069
2874.8957.00390.643412263526p11976016s3477.4387
2918.1446.00071.172112260116p11968326s3425.9006
2926.5652.00360.693512261016p11968326s3416.0433
2942.7840.00720.595612279106p11984814d3397.2162
2947.9582.00231.309012270825f11976016s3391.2534
2976.1176.00231.237812413725f12116116s3359.1661
3003.1852.00032.941912165524f11865114d3328.8900
3003.5961.00034.161711715115p11414813d3328.4346
3016.7344.00034.101611666015p11364315s3313.9388
3023.0838.00033.941811968326s11666015p3306.9785
3024.8017.00221.329012270835f11968326s3305.1004
3035.8606.00032.431711718425p11414813d3293.0607
3040.5660.00033.571811840715p11536713d3287.9646
3061.9268.00032.512112193315d11887105p3265.0269
3069.0179.00111.042512263526p11956634d3257.4829
3092.7336.00033.571811846015p11536713d3232.5038
3095.4093.00033.011511181813d10872304p3229.7096
3100.1742.00033.251811976016s11666015p3224.7456
3102.1880.00032.811811846925p11536713d3222.6523
3120.3530.00331.006512268625f11956634d3203.8917
3125.5136.00041.967412413725f12101214d3198.6017
3129.6340.00032.056112269645f11956634d3194.3905
3141.8337.00042.037512270835f11956634d3181.9867
3143.1718.00131.083212337325d12023034f3180.6321
3151.7997.00032.609212271845f11956634d3171.9253
3164.8110.00061.252212261016p11944524d3158.8847
3187.7678.00032.012011984814d11666015p3136.1359
3191.5209.00034.701711666015p11346825s3132.4479
3226.2014.00033.641711694335p11371733d3098.7752
3234.0312.00032.092411666015p11342623d3091.2729 B
3255.6064.01110.436012350525d12025034f3070.7867
3263.2924.00061.817812270825f11944524d3063.5541
3272.9837.00032.409112271835f11944524d3054.4830
3279.3267.00390.906212346816d12018924f3048.5749
3279.7342.00420.704212346816d12018814f3048.1961
3282.7720.00033.491711699925p11371733d3045.3753
3320.6895.00440.714512350906d12018814f3010.6015
3334.4971.00031.912112179405d11846015p2998.1351
3350.2442.00190.943312355735d12020744f2984.0430
3356.0661.00034.961711699925p11364315s2978.8665
3382.2227.00032.346812413645f12075334d2955.8292
3383.7324.00440.957812413735f12075334d2954.5105
3386.6647.00091.092312179405d11840715p2951.9523
3403.2640.00770.535212365346d12025044f2937.5543
3407.1346.00131.133512325517p11984814d2934.2171
3415.2255.00033.771811756305p11414813d2927.2658
3417.2967.00033.431912060124d11718425p2925.4916
3422.1922.00061.312212263526p11921334d2921.3066
3432.4115.00034.121711840715p11497515s2912.6090
3435.4222.00033.181912061924d11718425p2910.0565
3444.4688.01070.608512461047d12116536p2902.4135
3446.0344.00041.673612365346d12020754f2901.0949
3448.9604.00091.072212101214d11756305p2898.6337
3449.5614.00032.951912060124d11715115p2898.1286
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3830.7906.00181.75200  124061[3.5]6g12023034f2609.7152 B
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6804.1004.00033.493512023024f11342623d1469.3004
6807.9810.00181.347812346816d11666015p1468.4629
6823.9129.00034.153412025034f11342623d1465.0345
6831.3425.00034.143412165344f11482233d1463.4411
6832.2944.00032.813312165434f11482233d1463.2372
6832.6383.00041.913712165524f11482233d1463.1645
6848.1066.00032.103412165334f11480523d1459.8586
6849.0986.00033.903412165434f11480523d1459.6472
6849.4457.00032.673512165524f11480523d1459.5732
6858.0314.00032.683111414813d10729024p1457.7459
6960.4610.00161.053612390328s11694335p1436.2938
7012.2491.00033.923512165334f11464123d1425.6862
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7093.4598.00034.803311414813d10705404p1409.3640
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7186.8195.00034.163612020744f11302033d1391.0558
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7209.3980.00032.403512023034f11302033d1386.6992
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7229.5208.00033.323612025034f11302033d1382.8394
7229.5596.00032.973612025044f11302033d1382.8320
7230.9218.00034.203311346825s10623824p1382.5715
7287.3941.00035.473611275043d10546334p1371.8575
7308.7184.00034.923311480523d10749614p1367.8549
7319.5339.00081.697512268625f11536713d1365.8337 B
7322.4961.00071.584712147006p11414813d1365.2812
7338.7045.00035.073311342623d10608714p1362.2658
7351.2921.00034.233311464123d10729024p1359.9332
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7381.2145.00033.743311346825s10608714p1354.4202
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7479.0030.00035.233511371733d10623824p1336.7110
7479.5986.00032.143812023034f11275043d1336.6046
7499.7604.00033.413712025044f11275043d1333.0114
7506.8488.00032.113812165524f11414813d1331.7527
7509.2835.00035.023411464123d10713214p1331.3209
7515.4349.00033.453311480523d10729024p1330.2312
7532.2390.00035.183511482233d10729024p1327.2635
7548.5433.00041.814112119226p11364315s1324.3967
7554.0597.00041.964512127126p11371733d1323.4295
7556.0010.00034.423411364315s10608714p1323.0895
7557.5951.00034.633411302033d10546334p1322.8104
7565.6667.00034.593311166803d10410214p1321.3992
7600.2631.00081.554912106916p11346825s1315.3842
7613.8980.00051.703912125716p11364315s1313.0286
7626.2064.00710.464112260116p11497515s1310.9094
7627.3559.00101.364412127126p11364315s1310.7118
7660.0431.00061.634412263526p11497515s1305.1187
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7685.3185.00034.603511497515s10729024p1300.8264
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7715.9287.00034.943411181813d10410214p1295.6659
7729.9269.00034.093511486205s10713214p1293.3195
7748.0090.01310.163812261016p11486205s1290.3012
7765.8417.00101.455112119226p11342623d1287.3383
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7813.1258.00051.774812263526p11482233d1279.5474
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7826.9723.00051.784612147006p11364315s1277.2838
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7873.7454.00470.74511269.6962
7881.2694.00370.885612268625f11480523d1268.4841
7895.9030.00650.91105  12271845f11482233d1266.1332 B
7902.7445.00470.745112270835f11480523d1265.0371
7910.1795.00032.893611414813d10623824p1263.8480
7920.7469.00033.153611497515s10705404p1262.1619
7936.7267.00032.653912165344f11371733d1259.6206
7937.6794.00081.313112165434f11371733d1259.4695
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8076.8285.00271.106812271835f11464123d1237.7710
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8091.1398.00032.664012023024f11213923d1235.5817
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8538.3141.00340.956012268615f11414813d1170.8709
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8633.8790.00111.324412165434f11302033d1157.9109
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8887.7599.00042.034011497515s10608714p1124.8349
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9282.1503.00371.33158  12270825f11342623d1077.0415
9313.7480.00072.03130  12413645f11482233d1073.3875
9315.2458.00760.85107  12413735f11482233d1073.2149 ?
9323.8646.00051.744111342623d10410214p1072.2229
9332.0600.00111.80124  12413735f11480523d1071.2813
9342.3745.00042.874111480523d10546334p1070.0985
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10217.4425.00044.554910561724p  9540014s978.4502
10341.7253.00720.90114  12405836f11371733d966.6915 B
10351.5020.00044.805810410214p  9375114s965.7785
10419.1483.00620.756912413645f11371733d959.5081
10455.6379.00340.875012320637p11275043d956.1595
10547.4896.00121.588412268625f11213923d947.8328
10569.2113.00450.957912270825f11213923d945.8849
10632.2932.00820.90130  12405836f11342623d940.2729 B
10660.7525.02580.68247  12548346f11482233d937.7628
10678.0032.01100.629212548336f11480523d936.2478
10687.4309.00044.144810608714p  9540014s935.4219
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10837.7237.00044.626310623824p  9540014s922.4498
10841.6683.01750.68167  12548336f11464123d922.1142 B
10868.0457.00101.617112268615f11181813d919.8770
10868.3873.00071.867112268625f11181813d919.8479
10872.9204.00043.274711497515s10410214p919.4637
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11380.4908.00171.235411851204d10713214p878.4554
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11840.2156.01570.55111  12486147f11302033d844.3472 ?
11866.6727.00054.27112  10561724p  9375114s842.4647 R
11889.8716.00054.25105  10729024p  9540014s840.8209 R
11912.4488.00550.939412405136f11213923d839.2273 ?
11912.7258.01300.224312405226f11213923d839.2078 B
11923.1757.00071.665111921334d10729024p838.4723
11998.2807.00710.778312413735f11213923d833.2237
12096.5884.00054.167610749614p  9540014s826.4521
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12313.1259.00101.505411944524d10713214p811.9182
12318.9991.00054.22141  10546334p  9314424s811.5311 R
12336.6612.00054.22100  10608714p  9375114s810.3692 R
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12393.3829.00201.125111968326s10729024p806.6603
12413.8443.00052.085311865114d10623824p805.3307
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12438.6957.00171.286212116116s10872304p803.7217
12473.5104.00054.328710561724p  9314424s801.4785 R
12486.9545.00054.246610623824p  9375114s800.6155
12578.0436.00054.258310713214p  9455404s794.8175 R
12628.4665.00231.085511976016s10713214p791.6440
12669.0604.00052.195311890724d10623824p789.1074
12705.9011.00121.425611976016s10705404p786.8194
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13034.1248.00091.545511865114d10561724p767.0057
13093.7911.00054.19123  10623824p  9314424s763.5105 R
13104.4750.00101.525912060124d10749614p762.8880
13122.6038.00081.776412061924d10749614p761.8335 B
13210.2160.00580.827612193315d10872304p756.7815
13303.6742.00054.238010705404p  9375114s751.4651
13311.1897.00091.615412060124d10729024p751.0408
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16215.7974.00770.707712350525d10729024p616.5120
16241.8345.00460.937712247917s10623824p615.5237
16267.7212.00171.326612355735d10729024p614.5442
16373.7785.00161.366812350525d10713214p610.5636
16376.5857.00570.837612387307s10749614p610.4589
16392.1213.00251.207712247917s10608714p609.8804
16498.7909.00091.746712060124d10410214p605.9373
16516.9178.00151.416912061924d10410214p605.2723
16542.8781.00081.937012216035d10561724p604.3224
16573.3095.00072.336912203645d10546334p603.2128
16592.5002.00350.976512388217s10729024p602.5151
16624.1544.00440.876512208725d10546334p601.3678
16697.3880.00261.106212216035d10546334p598.7303
16822.7950.00390.936612244027s10561724p594.2669
16862.1077.00151.437512247917s10561724p592.8814
16909.8197.00081.977012101214d10410214p591.2086
16977.3094.00121.70105  12244027s10546334p588.8580
16994.5069.00151.396612109706s10410214p588.2624
17059.2146.00141.446812116116s10410214p586.0311
17135.3729.00360.996912337325d10623824p583.4264
17319.8714.00760.89117  12355735d10623824p577.2118
17418.2292.00191.266612350525d10608714p573.9520
17692.0003.00111.657412179405d10410214p565.0704
17830.7477.00081.957212193315d10410214p560.6734
17940.1488.00181.367812355735d10561724p557.2543
17984.8161.00091.867312208725d10410214p555.8703
18156.5910.00431.028812377436d10561724p550.6113 B
18190.4151.00121.668212365346d10546334p549.5875
18337.9668.00201.337912244027s10410214p545.1655
19147.0962.00601.03128  12461047d10546334p522.1271
19270.8283.00161.518712337325d10410214p518.7746
19365.8730.00181.418112346816d10410214p516.2284
19406.8306.00520.959112350906d10410214p515.1390
19757.0357.01980.74217  12522048d10546334p506.0078
21260.1678.00121.678511666015p  9540014s470.2316
21599.5004.00211.358511699925p  9540014s462.8441
21751.5042.00161.549011715115p  9540014s459.6096
22106.3349.00151.548711666015p  9455404s452.2322
22163.1303.00092.178911756305p  9540014s451.0733
22909.3977.00700.829211666015p  9375114s436.3793
23007.6035.00121.779311840715p  9540014s434.5168
23059.7718.00121.819211846015p  9540014s433.5338
23069.2269.00102.259411846925p  9540014s433.3561
23248.7308.00102.299411699925p  9375114s430.0101
23400.7318.00102.389311715115p  9375114s427.2169
23432.9967.00102.139311718425p  9375114s426.6286
23471.0911.00102.459511887105p  9540014s425.9362
23516.2369.00151.599411666015p  9314424s425.1185
23798.9979.00102.769611694335p  9314424s420.0674
23812.3612.00102.509511756305p  9375114s419.8317
23853.7677.00111.989611840715p  9455404s419.1029
23855.5677.00102.139511699925p  9314424s419.0713
23905.9348.00111.979411846015p  9455404s418.1883
24007.5691.00111.899511715115p  9314424s416.4179
24039.8337.00102.769711718425p  9314424s415.8590
24656.8287.01030.77121  11840715p  9375114s405.4527
24709.0026.00650.89100  11846015p  9375114s404.5965
24718.4566.00111.979911846925p  9375114s404.4418
25120.3269.00850.767111887105p  9375114s397.9715
25315.8403.00131.799911846015p  9314424s394.8979
25325.2989.00341.179611846925p  9314424s394.7504
25668.9124.00631.298612106916p  9540014s389.4560
26070.4161.00601.998412147006p  9540014s383.4678
26515.0764.00631.418612106916p  9455404s377.0368
27085.9965.00661.358612023034f  9314424s369.0894
27318.1447.00681.258912106916p  9375114s365.9529
27390.7207.00641.708612279106p  9540014s364.9832
27506.5746.01650.52109  12125716p  9375114s363.4459
27520.0268.00641.568312127126p  9375114s363.2682
27719.6402.00910.729512147006p  9375114s360.6522
27985.2236.00681.339512338507p  9540014s357.2295
28021.6135.00641.968612116536p  9314424s356.7655
28126.8637.00620.95109  12127126p  9314424s355.4305
29634.4517.00751.158712338507p  9375114s337.3482
30117.7873.00771.129512326227p  9314424s331.9342

The notation nl (e.g., 6p) denotes levels of the 3p5nl configuration with 3p5(2P3/2) core. The notation nl′ (e.g., 6p′) denotes levels of the 3p5nl configuration with 3p5(2P1/2) core.

The uncertainty Δσ in the line-center wavenumber appears in the second column. This experimental uncertainty (one standard deviation level) comes from two sources: (1) the uncertainty ΔσL in locating the center of the line in the presence of noise, and (2) ΔσS from the uncertainty in the scale of the FTS. We combine these to find the overall uncertainty in the wave number: Δσ = [(ΔσL)2 + (ΔσS)2)]1/2. We evaluate the uncertainty in locating the line center from ΔσL = 0.5(W)/(S/N), where W (the FWHM) and S/N (the signal-to-noise ratio) appear in Table 1, and the factor 0.5 is an approximation to the more precise factor given by Davis, Abrams, and Brault [5]. For very strong lines (S/N > 104) this expression may underestimate ΔσL because it neglects self-absorption that may, if asymmetric, shift the line center, and it neglects the local increase in the noise level under a strong line in the FTS spectrum [6]. We therefore set a lower limit on ΔσL of 0.0003 cm−1. The argument supporting this limiting value is presented in Ref. [1]. Wavenumbers measured with the FTS must be multiplied by a scale factor s to correct for any angular deviation between the path followed by light from the source as it passes through the instrument and the path followed by the laser beam that measures the displacement of the FTS mirror. The scale factor s is a constant (~1) for a given spectrum and is determined empirically by measuring with the FTS standard lines of accurately known wavenumber; s = (standard wavenumber)/(measured wavenumber). Any uncertainty Δs in the determination of s contributes a proportional uncertainty in the corrected wavenumber σ given by ΔσS = σ(Δs/s). The factor in parentheses was typically (3 to 7) × 10−8 for the different spectra that we measured. We adopt as the uncertainty Δs for a particular spectrum the standard deviation in the mean value of s derived from measurements of 28 Ar II standard lines in that spectrum. As standards we used as many as possible of the 28 Ar II lines recommended by Learner and Thorne [7]. These well isolated lines of good strength from transitions between low excitation levels should be minimally sensitive to pressure in the source. Our wavenumbers for these Ar II standard lines were taken from Ref. [1] and derive ultimately from the CO molecular lines used to calibrate the Ar II spectra [8]. Our Ar II wavenumbers are slightly higher than the values reported by Norlén [9]. For the 28 Ar II standard lines, the mean value of the ratio σ (based on CO)/(Norlén) is [1 + 67(8) × 10−9]. The list of argon wavenumbers collected by comparing different spectra was then compared with line lists in the literature for Ar I, Ar II, and Ar III—notably those of Minnhagen [10], Striganov and Sventitskii [11], and Kurucz and Peytremann [12]—to identify the ion and classify the transition. Additional Ar I lines with wavelengths longer than those in existing compilations were identified by calculating all electric dipole transition energies allowed by parity and J-value selection rules, using Ar I level energies from Moore [13] as expanded and refined by level energies from Minnhagen [10] and Norlén [9]. In Table 1, we identify the transition upper level in columns 5–7 by its energy, J-value, and orbital, and the lower level in columns 8–10. When individual J levels could not be resolved, the [K] value (the result of coupling the total angular momentum J1 of the 3p5 core with the orbital angular momentum l of the valence electron) is given. The last column gives the wavelength in air as determined from the vacuum wavenumber by a formula from Edlén [14]. Ar II and Ar III lines were identified and classified in the same way. When all Ar I, II, and III lines had been removed from the list of common lines, we searched for possible contaminants that might be common to all our spectra by searching for the strongest lines in the spectra of H, He, C, N, O, Ne, Na, and Fe. A few H, C, and O lines were found, readily identified as coming from a low-mass contaminant by their broad Doppler widths. On the Cu cathode spectrum between 2000 cm−1 and 3000 cm−1, molecular lines from ArH+ were abundant and strong (S/N up to 102). With all known Ar and contaminant lines removed, the 114 common lines left over are presumably from Ar. By comparing the relative intensity of these unidentified lines in spectra recorded at different power levels, we conclude that most come from an Ar ion. Four unidentified lines that appear to come from Ar I are included in Table 1 with no designation.

4. Comparison With Other Line Lists

Our Ar I wavelengths agree with those of Minnhagen [10] within the modest precision he assigns: “better than 10 mÅ for lines that are not too weak.” Our agreement with Norlén’s [9] wavenumbers is generally within (1 or 2) × 10−3 cm−1, as might be expected from the close agreement of his calculated wavenumbers for Ar II with the values we used to calibrate the FTS scale. Norlén’s calculated wavenumbers are essentially averages over many alternate (Ritz-equivalent) paths that reduce the uncertainty of his values well below that which we are able to achieve in a single measurement, especially for weak lines. Hence Norlén’s values, multiplied by [1 + 67(8) × 10−9], are to be preferred to those in Table 1 when available. Palmeri and Biemont [15] have measured 100 transitions from 4f, 5g, and 6g levels in Ar I, using spectra recorded with the same FTS used in the present experiment. In their hollow cathode source they used various Ar pressures but all were lower than ours; their average pressure of about 130 Pa (1 Torr) was lower than ours by a factor of 1/3. For the 4f → 3d transitions (66 lines), our wavenumbers agree beautifully with theirs; the mean deviation between the two sets of wavenumbers is 0.4(1.1) × 10−3 cm−1. For the 5g → 4f and 6g → 4f transitions (33 lines), our wavenumbers are, on average, greater than theirs by 6 × 10−3 cm−1. We attribute this difference to a pressure effect that appears to be strongly dependent on the angular momentum of the levels involved. This difference did not show up in our comparison with Norlén’s wavenumbers, even though his source pressure was lower than ours by a factor of 1/10, because the shift depends on the angular momentum of the levels involved and Norlén measured only transitions between s, p, and d orbitals in Ar I. Any interaction between an excited Ar atom and neighboring atoms that shifts the energy of an excited level will also broaden it, and this effect is clearly seen in Table 1. For example, transitions near 3800 cm−1 from the 6g levels in Ar I have an average width ≈300 × 10−3 cm−1, while nearby lines from 4d′ and 5p′ upper levels have widths between (18 and 22) × 10−3 cm−1. The dependence on l appears to be greater than the dependence on n; nine lines from 7p configurations in the same (3600 to 4000) cm−1 range have an average width of 38 × 10−3 cm−1. In these examples, the lines are only broadened and shifted at the pressure (270 Pa to 530 Pa) of our source, but the lines may not be seen at all from a source at higher pressure. Palmeri and Biemont [15] report lines near 2100 cm−1 from 7g and 7h levels of Ar I that are broadened beyond recognition as lines on our spectra. We conclude that the gas pressure in our hollow cathode source has increased the wavenumber of some lines from levels of high l or n. The shifted lines display a width noticeably greater than that of nearby transitions between s, p, and d levels. The wavenumbers, line widths, and relative signal amplitudes in the table are those one can expect to see from a hollow cathode discharge in Ar at a pressure of a few hundred Pa.
  2 in total

1.  New Wavenumber Calibration Tables From Heterodyne Frequency Measurements.

Authors:  Arthur G Maki; Joseph S Wells
Journal:  J Res Natl Inst Stand Technol       Date:  1992 Jul-Aug

2.  Improved Wavelengths and Energy Levels of Doubly-Ionized Argon (Ar III).

Authors:  Victor Kaufman; Ward Whaling
Journal:  J Res Natl Inst Stand Technol       Date:  1996 Sep-Oct
  2 in total
  2 in total

1.  Re-Optimized Energy Levels and Ritz Wavelengths of (198)Hg I.

Authors:  Alexander Kramida
Journal:  J Res Natl Inst Stand Technol       Date:  2011-04-01

2.  Comment on "Argon I Lines Produced in a Hollow Cathode Source, 332 nm to 5865 nm".

Authors:  Craig J Sansonetti
Journal:  J Res Natl Inst Stand Technol       Date:  2007-12-01
  2 in total

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