Literature DB >> 26977708

A C216-Nanographene Molecule with Defined Cavity as Extended Coronoid.

Uliana Beser1, Marcel Kastler1, Ali Maghsoumi2, Manfred Wagner1, Chiara Castiglioni2, Matteo Tommasini2, Akimitsu Narita1, Xinliang Feng3, Klaus Müllen1.   

Abstract

We describe the first coronoid nanographene C216-molecule. As an extended polycyclic aromatic hydrocarbon containing a defined cavity, our molecule can be seen as a model system to study the influence of holes on the physical and chemical properties of graphene. Along the pathway of an eight-step synthesis including Yamamoto-type cyclization followed by 6-fold Diels-Alder cycloaddition, C216 was obtained by oxidative cyclodehydrogenation in the final step. The defined molecular structure with a cavity was unambiguously validated by MALDI-TOF mass spectrometry and FTIR, Raman, and UV-vis absorption spectroscopy coupled with DFT simulations.

Entities:  

Year:  2016        PMID： 26977708     DOI： 10.1021/jacs.6b01181

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  7 in total

1.  Luminescent Carbon Dot Mimics Assembled on DNA.

Authors:  Ke Min Chan; Wang Xu; Hyukin Kwon; Anna M Kietrys; Eric T Kool
Journal:  J Am Chem Soc       Date:  2017-09-12       Impact factor: 15.419

2.  Versatile synthesis and enlargement of functionalized distorted heptagon-containing nanographenes.

Authors:  Irene R Márquez; Noelia Fuentes; Carlos M Cruz; Virginia Puente-Muñoz; Lia Sotorrios; M Luisa Marcos; Duane Choquesillo-Lazarte; Blanca Biel; Luis Crovetto; Enrique Gómez-Bengoa; M Teresa González; Ruben Martin; Juan M Cuerva; Araceli G Campaña
Journal:  Chem Sci       Date:  2016-08-31       Impact factor: 9.825

3.  Large-Cavity Coronoids with Different Inner and Outer Edge Structures.

Authors:  Marco Di Giovannantonio; Xuelin Yao; Kristjan Eimre; José I Urgel; Pascal Ruffieux; Carlo A Pignedoli; Klaus Müllen; Roman Fasel; Akimitsu Narita
Journal:  J Am Chem Soc       Date:  2020-07-02       Impact factor: 15.419

4.  Synthesis and reactivity of a trigonal porous nanographene on a gold surface.

Authors:  Rafal Zuzak; Iago Pozo; Mads Engelund; Aran Garcia-Lekue; Manuel Vilas-Varela; José M Alonso; Marek Szymonski; Enrique Guitián; Dolores Pérez; Szymon Godlewski; Diego Peña
Journal:  Chem Sci       Date:  2019-09-13       Impact factor: 9.825

Review 5.  Small Size, Big Impact: Recent Progress in Bottom-Up Synthesized Nanographenes for Optoelectronic and Energy Applications.

Authors:  Zhaoyang Liu; Shuai Fu; Xiaomin Liu; Akimitsu Narita; Paolo Samorì; Mischa Bonn; Hai I Wang
Journal:  Adv Sci (Weinh)       Date:  2022-02-26       Impact factor: 17.521

6.  Revisiting Kekulene: Synthesis and Single-Molecule Imaging.

Authors:  Iago Pozo; Zsolt Majzik; Niko Pavliček; Manuel Melle-Franco; Enrique Guitián; Diego Peña; Leo Gross; Dolores Pérez
Journal:  J Am Chem Soc       Date:  2019-09-23       Impact factor: 15.419

7.  Molecular defect-containing bilayer graphene exhibiting brightened luminescence.

Authors:  Xin-Jing Zhao; Hao Hou; Peng-Peng Ding; Ze-Ying Deng; Yang-Yang Ju; Shun-He Liu; Yu-Min Liu; Chun Tang; Liu-Bin Feng; Yuan-Zhi Tan
Journal:  Sci Adv       Date:  2020-02-28       Impact factor: 14.136
  7 in total

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