Literature DB >> 26914533

Scalable, Metal- and Additive-Free, Photoinduced Borylation of Haloarenes and Quaternary Arylammonium Salts.

Adelphe M Mfuh1, John D Doyle1, Bhuwan Chhetri1, Hadi D Arman1, Oleg V Larionov1.   

Abstract

We report herein a simple, metal- and additive-free, photoinduced borylation of haloarenes, including electron-rich fluoroarenes, as well as arylammonium salts directly to boronic acids. This borylation method has a broad scope and functional group tolerance. We show that it can be further extended to boronic esters and carried out on gram scale as well as under flow conditions.

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Year:  2016        PMID： 26914533      PMCID： PMC4974080          DOI： 10.1021/jacs.6b01376

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  67 in total

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