Literature DB >> 27347688

Additive- and Metal-Free, Predictably 1,2- and 1,3-Regioselective, Photoinduced Dual C-H/C-X Borylation of Haloarenes.

Adelphe M Mfuh1, Vu T Nguyen1, Bhuwan Chhetri1, Jessica E Burch1, John D Doyle1, Vladimir N Nesterov2, Hadi D Arman1, Oleg V Larionov1.   

Abstract

We report herein a simple, additive- and metal-free, photoinduced, dual C-H/C-X borylation of chloro-, bromo-, and iodoarenes. The reaction produces 1,2- and 1,3-diborylarenes on gram scales under batch and continuous flow conditions. The regioselectivity of the dual C-H/C-X borylation is determined by the solvent and the substituents in the parent haloarenes.

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Year:  2016        PMID： 27347688      PMCID： PMC4958914          DOI： 10.1021/jacs.6b05436

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


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