Literature DB >> 26594587

Crystal structure of 3'-(1H-indole-3-carbon-yl)-1'-methyl-2-oxo-4'-(4-oxo-4H-chromen-3-yl)spiro-[indoline-3,2'-pyrrolidine]-3'-carbo-nitrile.

M P Savithri1, R Raja2, D Kathirvelan3, B S R Reddy3, A SubbiahPandi4.   

Abstract

In the title compound, C31H22N4O4, the pyrrolidine ring adopts a twist conformation on the N-CH2 bond. The indolin-2-one and the 1H-indole rings are nearly planar (r.m.s. deviations = 0.06 and 0.011 Å, respectively) and are inclined to one another by 34.19 (9)°. The chromene ring system is also nearly planar (r.m.s. deviation = 0.029 Å). It is almost normal to the 1H-indole ring system, with a dihedral angle of 88.71 (8)°, and is inclined to the indolin-2-one ring system by 72.76 (8)°. In the crystal, mol-ecules are linked via N-H⋯O hydrogen bonds, forming slabs parallel to (10-1). The slabs are linked by C-H⋯O hydrogen bonds, forming a three-dimensional structure.

Entities:  

Keywords:  carbo­nitrile; chromen; crystal structure; hydrogen bonding; indole; pyrrolidine; spiro

Year:  2015        PMID: 26594587      PMCID: PMC4645027          DOI: 10.1107/S2056989015020174

Source DB:  PubMed          Journal:  Acta Crystallogr E Crystallogr Commun


  8 in total

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  8 in total

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