| Literature DB >> 26594587 |
M P Savithri1, R Raja2, D Kathirvelan3, B S R Reddy3, A SubbiahPandi4.
Abstract
In the title compound, C31H22N4O4, the pyrrolidine ring adopts a twist conformation on the N-CH2 bond. The indolin-2-one and the 1H-indole rings are nearly planar (r.m.s. deviations = 0.06 and 0.011 Å, respectively) and are inclined to one another by 34.19 (9)°. The chromene ring system is also nearly planar (r.m.s. deviation = 0.029 Å). It is almost normal to the 1H-indole ring system, with a dihedral angle of 88.71 (8)°, and is inclined to the indolin-2-one ring system by 72.76 (8)°. In the crystal, mol-ecules are linked via N-H⋯O hydrogen bonds, forming slabs parallel to (10-1). The slabs are linked by C-H⋯O hydrogen bonds, forming a three-dimensional structure.Entities:
Keywords: carbonitrile; chromen; crystal structure; hydrogen bonding; indole; pyrrolidine; spiro
Year: 2015 PMID: 26594587 PMCID: PMC4645027 DOI: 10.1107/S2056989015020174
Source DB: PubMed Journal: Acta Crystallogr E Crystallogr Commun