Crystal structures of the potassium and rubidium salts of (3,5-di-chloro-phen-oxy)acetic acid: two isotypic coordination polymers.

The two-dimensional coordination polymeric structures of the hydrated potassium and rubidium salts of (3,5-di-chloro-phen-oxy)acetic acid (3,5-D), namely, poly[μ-aqua-bis-[μ3-2-(3,5-di-chloro-phen-oxy)acetato]-dipotassium], [K2(C8H5Cl2O3)2(H2O)] n , and poly[μ-aqua-bis-[μ3-2-(3,5-di-chloro-phen-oxy)acetato]-dirubidium], [Rb2(C8H5Cl2O3)2(H2O)] n , respectively, have been determined and are described. The two compounds are isotypic and the polymeric structure is based on centrosymmetric dinuclear bridged complex units. The irregular six-coordination about the alkali cations comprises a bridging water mol-ecule lying on a twofold rotation axis, the phen-oxy O-atom donor and a triple bridging carboxyl-ate O atom of the oxo-acetate side chain of the 3,5-D ligand, and the second carb-oxy-ate O-atom donor also bridging. The K-O and Rb-O bond-length ranges are 2.7238 (15)-2.9459 (14) and 2.832 (2)-3.050 (2) Å, respectively, and the K⋯K and Rb⋯Rb separations in the dinuclear units are 4.0214 (7) and 4.1289 (6) Å, respectively. Within the layers which lie parallel to (100), the coordinating water mol-ecule forms an O-H⋯O hydrogen bond to the single bridging carboxyl-ate O atom.

Chemical context

The phen­oxy­acetic acids are a particularly useful series of compounds since certain members having specific ring-substituents have herbicidal activity, resulting in their being used commercially. Of these, the most common have been the chlorine-substituted analogues (2,4-di­chloro­phen­oxy)acetic acid (2,4-D), (2,4,5-tri­chloro­phen­oxy)acetic acid (2,4,5-T) and (4-chloro-2-methyl­phen­oxy)acetic acid (MCPA) (Zumdahl, 2010 ▸). As such, the active members have received considerable attention, particularly with respect to health aspects resulting from residual breakdown components after environmental exposure. Compounds formed from their reaction with a wide range of metals have provided a significant number of crystal structures, e.g. for 2,4-D, there are 60 examples of metal complexes, contained in the Cambridge Structural Database (CSD; Groom & Allen, 2014 ▸), e.g. with CaII (Song et al., 2002 ▸) and with ZnII (Kobylecka et al., 2012 ▸).

Metal complex formation with the phen­oxy­acetic acids has been facilitated by their versatility as ligands, showing various inter­active modes with common metals including monodentate and bidentate-bridging coordinations involving the O carbox­yl, O 1 phen­oxy [(O,O)1] chelate inter­action, first reported for the monomeric copper(II) phen­oxy­acetate complex (Prout et al., 1968 ▸) and also found in the potassium–2,4-D salt (Kennard et al., 1983 ▸) as well as in the caesium complexes with 4-fluoro­phen­oxy­acetate and (4-chloro-2-meth­yl)phen­oxy­acetate (Smith, 2015a ▸). In the caesium complex-adduct with 2,4-D (Smith & Lynch, 2014 ▸), a tridentate chelate inter­action variant is found which includes, in addition to the O,O 1-chelate, a Cs—Cl bond to the ortho-Cl ring substituent of the ligand. Only occasional examples of the bidentate carboxyl­ate O,O′-chelate inter­action are found, e.g. with the previously mentioned caesium 4-fluoro­phen­oxy­acetate.

However, examples of structures of alkali metal salts of the phen­oxy­acetic acids are not common in the crystallographic literature, comprising, apart from the previously mentioned examples, the following: sodium phen­oxy­acetate hemihydrate (Prout et al., 1971 ▸; Evans et al., 2001 ▸), anhydrous caesium phen­oxy­acetate (Smith, 2014a ▸), the lithium, rubidium and caesium complexes of 2,4-D (Smith, 2015a ▸), caesium o-phenyl­ene­dioxydi­acetate dihydrate (Smith et al., 1989 ▸) and the lithium salts of (2-chloro­phen­oxy)acetic acid (O’Reilly et al., 1987 ▸), (2-carbamoylphen­oxy)acetic acid (Mak et al., 1986 ▸) and (2-carb­oxy­phen­oxy)acetic acid (Smith et al., 1986 ▸).

To investigate the nature of the coordination complex structures formed in the potassium and rubidium salts of the 2,4-D isomer, reactions of (3,5-di­chloro­phen­oxy)acetic acid (3,5-D) with K2CO3 and Rb2CO3 in aqueous ethanol were carried out, affording the isotypic polymeric title compounds [K2(C8H5Cl2O3)2(H2O)], (I), and [Rb2(C8H5Cl2O3)2(H2O)], (II), and the structures are reported herein.

Structural commentary

The hydrated complexes (I) and (II) are isotypic and are described conjointly. Each comprises a centrosymmetric dinuclear repeating unit (Fig. 1 ▸) in which the irregular six-coordination about the K+ or Rb+ cations consists of a bidentate O carboxyl­ate (O13), O phen­oxy (O11) chelate inter­action (Fig. 2 ▸), three bridging carboxyl­ate (O13i, O13ii, O14iii; for symmetry codes, see Table 1 ▸) inter­actions and a single bridging water mol­ecule (O1W) lying on a twofold rotation axis. The comparative M—O bond length range for the two metals (Tables 1 ▸ and 2 ▸) is 2.7238 (15)–2.9459 (14) Å (K) and 2.832 (2)–3.050 (2) Å (Rb), for the two O-atom donors in the (O:O 1)-chelate inter­action (O13 and O11, respectively).

Figure 1

A view of the partially expanded polymeric extension of the structures of (I) and (II), shown with 30% probability ellipsoids (with data taken from the potassium structure). [See Table 1 ▸ for symmetry codes; additionally: (vi) x − 1, y, z; (vii) x, y − 1, z.]

Figure 2

The mol­ecular configuration and atom-numbering scheme for the isomeric K and Rb complexes with 3,5-D [(I) and (II)], with displacement ellipsoids drawn at the 40% probability level (with data taken from the potassium structure). For symmetry codes, see Table 1 ▸.

Table 1

Selected bond lengths (Å) for (I)

K1—O1W	2.7947 (15)	K1—O13i	2.7855 (15)
K1—O11	2.9459 (14)	K1—O13ii	2.7462 (13)
K1—O13	2.7238 (15)	K1—O14iii	2.7309 (16)

Symmetry codes: (i) ; (ii) ; (iii) .

Table 2

Selected bond lengths (Å) for (II)

Rb1—O1W	2.924 (2)	Rb1—O13i	2.874 (2)
Rb1—O11	3.050 (2)	Rb1—O13ii	2.894 (2)
Rb1—O13	2.832 (2)	Rb1—O14iii	2.842 (2)

Symmetry codes: (i) ; (ii) ; (iii) .

Two-dimensional coordination polymeric structures are generated, lying parallel to (100) (Fig. 3 ▸), in which the core sheet comprises the M—O complex network with the aromatic rings of the ligands peripherally located between the layers. Within the layers there are a number of short metal⋯metal contacts, the shortest being across an inversion centre [K⋯Kii = 4.0214 (7) Å and Rb⋯Rbii = 4.1289 (6) Å], the longest being K⋯Kvi = 4.3327 (5) Å and Rb⋯Rbvi = 4.5483 (5) Å [symmetry codes: (ii) −x + 1, −y + 1, −z + 1; (vi) −x + 1, y, −z + ]. No inter-ring π–π inter­actions are found in either (I) or (II), the minimum ring-centroid separations being 4.3327 (1) Å in (I) and 4.3302 (3) Å in (II), (the b-axis dimensions). The coordinating water mol­ecules on the twofold rotation axes are involved in intra-layer bridging O—H⋯Ocarbox­yl hydrogen-bonding inter­actions (with O14 and O14iv) (Tables 3 ▸ and 4 ▸).

Figure 3

The packing of the layered structure of compounds (I) and (II) in the unit cell, viewed approximately along [010]. Non-associated H atoms have been omitted.

Table 3

Hydrogen-bond geometry (Å, °) for (I)

D—H⋯A	D—H	H⋯A	D⋯A	D—H⋯A
O1W—H1W⋯O14iv	0.85 (2)	1.90 (2)	2.750 (2)	174 (2)

Symmetry code: (iv) .

Table 4

Hydrogen-bond geometry (Å, °) for (II)

D—H⋯A	D—H	H⋯A	D⋯A	D—H⋯A
O1W—H1W⋯O14iv	0.89 (3)	1.87 (3)	2.750 (3)	171 (5)

Symmetry code: (iv) .

The 3,5-D anions in both (I) and (II) adopt the anti­periplanar conformation with the defining oxo­acetate side chain torsion angles C1—O11—C12—O13 of −171.55 (15) and −172.4 (2)° for (I), (II), respectively, that are similar to −172.4 (3)° in the ammonium salt (Smith, 2015b ▸). These values contrast with the value in the 2:1 3,5-D adduct with 4,4′-biphenyl [−71.6 (3)°] (synclinal) (Lynch et al., 2003 ▸).

The present isotypic potassium and rubidium salts of (3,5-di­chloro­phen­oxy)acetic acid provide an example of isotypism which extends to the ammonium salt (Smith, 2015b ▸). Isotypism is also found in the analogous NH4 +, K+ and Rb+ hemihydrate salts of isomeric 2,4-D (Table 5 ▸). It may also be possible that a similar series exists with MCPA for which the structure of only the ammonium hemihydrate salt (NH4 + MCPA−·0.5H2O) is known (Smith, 2014b ▸). It is of note that the sodium salts are not included in the sets, the structures for which are not known.

Table 5

Comparative cell data (Å, °, Å3) for NH4 +, K+ and Rb+ salts of (3,5-di­chloro­phen­oxy)acetic acid (3,5-D), (2,4-di­chloro­phen­oxy)acetic acid (2,4-D) and (4-chloro-2-methyl­phen­oxy)acetic acid (MCPA)

Cell parameters	NH4 +3,5-D−·0.5H2O	K+3,5-D−·0.5H2O	Rb+3,5-D−·0.5H2O	NH4 +2,4-D−·0.5H2O	K+2,4-D−·0.5H2O	Rb+2,4-D−·0.5H2O	NH4 +MCPA−·0.5H2O
a	39.818 (3)	39.274 (2)	39.641 (3)	39.3338 (8)	36.80 (1)	37.254 (2)	38.0396 (9)
b	4.3340 (4)	4.3327 (3)	4.3302 (3)	4.3889 (9)	4.339 (1)	4.3589 (3)	4.456 (5)
c	12.7211 (8)	12.4234 (10)	12.8607 (8)	12.900 (3)	12.975 (7)	13.238 (1)	12.944 (5)
β (°)	98.098 (5)	99.363 (6)	98.404 (5)	103.83 (3)	102.03 (4)	103.231 (7)	104.575 (5)
V	2178.4 (5)	2085.8 (3)	2183.9 (3)	2074.7 (8)	2026 (2)	2092.6 (3)	2123 (3)
Z	8	8	8	8	8	8	8
Space group	C2/c	C2/c	C2/c	C2/c	C2/c	C2/c	C2/c
Reference	Smith (2015b ▸)	This work (I)	This work (II)	Liu et al. (2009 ▸)	Smith (2015a ▸)	Smith (2015a ▸)	Smith (2014b ▸)

Synthesis and crystallization

Compounds (I) and (II) were synthesized by the addition of 0.5 mmol of K2CO3 (65 mg) [for (I)] or Rb2CO3 (115 mg) (for (II)] to a hot solution of (3,5-di­chloro­phen­oxy)acetic acid (3,5-D) (220 mg) in 10 ml of 50% (v/v) ethanol/water. After heating for 5 min, partial room temperature evaporation of the solutions gave in all two cases, colourless needles from which specimens were cleaved for the X-ray analyses.

Refinement details

Crystal data, data collection and structure refinement details for (I) and (II) are summarized in Table 6 ▸. Hydrogen atoms were placed in calculated positions [C—Haromatic = 0.95 Å or C—Hmethyl­ene = 0.99 Å] and were allowed to ride in the refinements, with U iso(H) = 1.2U eq(C). The water H-atom in both structures was located in a difference Fourier map and was allowed to ride in the refinements with an O—H distance restraint of 0.90±0.02 Å and with U iso(H) = 1.5U eq(O).

Table 6

Experimental details

	(I)	(II)
Crystal data
Chemical formula	[K2(C8H5Cl2O3)2(H2O)]	[Rb2(C8H5Cl2O3)2(H2O)]
M r	536.26	629.00
Crystal system, space group	Monoclinic, C2/c	Monoclinic, C2/c
Temperature (K)	200	200
a, b, c (Å)	39.274 (2), 4.3327 (3), 12.4234 (10)	39.641 (3), 4.3302 (3), 12.8607 (8)
β (°)	99.363 (6)	98.404 (5)
V (Å3)	2085.8 (3)	2183.9 (3)
Z	4	4
Radiation type	Mo Kα	Mo Kα
μ (mm−1)	1.00	5.01
Crystal size (mm)	0.45 × 0.12 × 0.04	0.40 × 0.12 × 0.04
Data collection
Diffractometer	Oxford Diffraction Gemini-S CCD detector	Oxford Diffraction Gemini-S CCD detector
Absorption correction	Multi-scan (CrysAlis PRO; Agilent, 2013 ▸)	Multi-scan (CrysAlis PRO; Agilent, 2013 ▸)
T min, T max	0.774, 0.980	0.369, 0.980
No. of measured, independent and observed [I > 2σ(I)] reflections	6745, 2061, 1824	7520, 2152, 1910
R int	0.035	0.055
(sin θ/λ)max (Å−1)	0.617	0.617
Refinement
R[F 2 > 2σ(F 2)], wR(F 2), S	0.031, 0.076, 1.07	0.040, 0.095, 1.06
No. of reflections	2061	2152
No. of parameters	135	136
No. of restraints	1	1
H-atom treatment	H atoms treated by a mixture of independent and constrained refinement	H atoms treated by a mixture of independent and constrained refinement
Δρmax, Δρmin (e Å−3)	0.27, −0.25	0.98, −1.00

Computer programs: CrysAlis PRO (Agilent, 2013 ▸), SIR92 (Altomare et al., 1993 ▸), SHELXS97 and SHELXL97 (Sheldrick, 2008 ▸) within WinGX (Farrugia, 2012 ▸), PLATON (Spek, 2009 ▸).

Crystal structure: contains datablock(s) global, I, II. DOI: 10.1107/S2056989015016722/wm5206sup1.cif

Structure factors: contains datablock(s) I. DOI: 10.1107/S2056989015016722/wm5206Isup2.hkl

Structure factors: contains datablock(s) II. DOI: 10.1107/S2056989015016722/wm5206IIsup3.hkl

Click here for additional data file.

Supporting information file. DOI: 10.1107/S2056989015016722/wm5206Isup4.cml

Click here for additional data file.

Supporting information file. DOI: 10.1107/S2056989015016722/wm5206IIsup5.cml

CCDC references: 1422835, 1422834

Additional supporting information: crystallographic information; 3D view; checkCIF report

[K2(C8H5Cl2O3)2(H2O)]	F(000) = 1080
Mr = 536.26	Dx = 1.708 Mg m−3
Monoclinic, C2/c	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: -C 2yc	Cell parameters from 2400 reflections
a = 39.274 (2) Å	θ = 4.2–28.6°
b = 4.3327 (3) Å	µ = 1.00 mm−1
c = 12.4234 (10) Å	T = 200 K
β = 99.363 (6)°	Flat prism, colourless
V = 2085.8 (3) Å3	0.45 × 0.12 × 0.04 mm
Z = 4

Oxford Diffraction Gemini-S CCD-detector diffractometer	2061 independent reflections
Radiation source: Enhance (Mo) X-ray source	1824 reflections with I > 2σ(I)
Graphite monochromator	Rint = 0.035
Detector resolution: 16.077 pixels mm-1	θmax = 26.0°, θmin = 3.2°
ω scans	h = −48→47
Absorption correction: multi-scan (CrysAlis PRO; Agilent, 2013)	k = −5→5
Tmin = 0.774, Tmax = 0.980	l = −15→15
6745 measured reflections

Refinement on F2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.031	Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.076	H atoms treated by a mixture of independent and constrained refinement
S = 1.07	w = 1/[σ2(Fo2) + (0.0337P)2 + 0.706P] where P = (Fo2 + 2Fc2)/3
2061 reflections	(Δ/σ)max = 0.001
135 parameters	Δρmax = 0.27 e Å−3
1 restraint	Δρmin = −0.25 e Å−3

Geometry. Bond distances, angles etc. have been calculated using the rounded fractional coordinates. All su's are estimated from the variances of the (full) variance-covariance matrix. The cell esds are taken into account in the estimation of distances, angles and torsion angles

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > 2sigma(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

	x	y	z	Uiso*/Ueq
K1	0.53071 (1)	0.71864 (10)	0.40994 (4)	0.0253 (1)
Cl3	0.66484 (1)	1.12106 (12)	0.30636 (5)	0.0351 (2)
Cl5	0.72749 (1)	0.44252 (15)	0.64380 (5)	0.0436 (2)
O1W	0.50000	0.3066 (5)	0.25000	0.0301 (7)
O11	0.59608 (3)	0.5041 (3)	0.53873 (12)	0.0279 (4)
O13	0.53561 (3)	0.2277 (3)	0.54855 (12)	0.0279 (4)
O14	0.55253 (4)	0.0910 (3)	0.72297 (12)	0.0317 (5)
C1	0.62867 (5)	0.5876 (4)	0.52303 (17)	0.0226 (6)
C2	0.63030 (5)	0.7874 (4)	0.43626 (17)	0.0243 (6)
C3	0.66234 (5)	0.8758 (4)	0.41548 (17)	0.0250 (6)
C4	0.69289 (5)	0.7753 (5)	0.47741 (18)	0.0286 (6)
C5	0.69014 (5)	0.5791 (5)	0.56273 (18)	0.0268 (6)
C6	0.65879 (5)	0.4817 (5)	0.58735 (17)	0.0242 (6)
C12	0.59359 (5)	0.3273 (5)	0.63485 (17)	0.0276 (6)
C13	0.55716 (5)	0.2100 (4)	0.63421 (17)	0.0228 (6)
H1W	0.4837 (5)	0.189 (5)	0.263 (2)	0.0340*
H2	0.60980	0.86110	0.39240	0.0290*
H4	0.71470	0.83880	0.46170	0.0340*
H6	0.65780	0.34570	0.64670	0.0290*
H121	0.60060	0.45750	0.70020	0.0330*
H122	0.60960	0.14980	0.63920	0.0330*

	U11	U22	U33	U12	U13	U23
K1	0.0223 (2)	0.0305 (2)	0.0223 (3)	−0.0004 (2)	0.0016 (2)	−0.0001 (2)
Cl3	0.0440 (3)	0.0342 (3)	0.0282 (3)	−0.0098 (2)	0.0095 (3)	0.0029 (2)
Cl5	0.0188 (3)	0.0630 (4)	0.0457 (4)	−0.0017 (3)	−0.0046 (2)	0.0085 (3)
O1W	0.0230 (11)	0.0293 (11)	0.0381 (14)	0.0000	0.0051 (10)	0.0000
O11	0.0163 (7)	0.0415 (8)	0.0251 (8)	−0.0026 (6)	0.0011 (6)	0.0101 (7)
O13	0.0197 (7)	0.0353 (8)	0.0266 (8)	−0.0036 (6)	−0.0028 (6)	−0.0003 (7)
O14	0.0293 (8)	0.0418 (9)	0.0251 (9)	−0.0062 (7)	0.0075 (7)	0.0028 (7)
C1	0.0185 (10)	0.0278 (10)	0.0214 (11)	−0.0023 (8)	0.0029 (8)	−0.0037 (9)
C2	0.0228 (10)	0.0267 (10)	0.0226 (11)	−0.0002 (8)	0.0015 (8)	−0.0016 (9)
C3	0.0302 (11)	0.0243 (10)	0.0211 (11)	−0.0049 (9)	0.0061 (9)	−0.0034 (9)
C4	0.0222 (10)	0.0348 (11)	0.0297 (12)	−0.0077 (9)	0.0070 (9)	−0.0070 (10)
C5	0.0180 (10)	0.0338 (11)	0.0266 (12)	−0.0019 (8)	−0.0023 (8)	−0.0039 (9)
C6	0.0206 (10)	0.0303 (10)	0.0213 (11)	−0.0027 (8)	0.0021 (8)	−0.0005 (9)
C12	0.0232 (11)	0.0384 (11)	0.0200 (11)	−0.0054 (9)	0.0002 (9)	0.0063 (9)
C13	0.0196 (10)	0.0233 (9)	0.0256 (12)	0.0003 (8)	0.0039 (9)	−0.0039 (9)

K1—O1W	2.7947 (15)	O1W—H1Wiv	0.85 (2)
K1—O11	2.9459 (14)	C1—C6	1.393 (3)
K1—O13	2.7238 (15)	C1—C2	1.392 (3)
K1—O13i	2.7855 (15)	C2—C3	1.379 (3)
K1—O13ii	2.7462 (13)	C3—C4	1.386 (3)
K1—O14iii	2.7309 (16)	C4—C5	1.377 (3)
Cl3—C3	1.738 (2)	C5—C6	1.382 (3)
Cl5—C5	1.742 (2)	C12—C13	1.517 (3)
O11—C1	1.374 (2)	C2—H2	0.9500
O11—C12	1.435 (3)	C4—H4	0.9500
O13—C13	1.250 (2)	C6—H6	0.9500
O14—C13	1.257 (2)	C12—H121	0.9900
O1W—H1W	0.85 (2)	C12—H122	0.9900
O1W—K1—O11	114.95 (4)	H1W—O1W—H1Wiv	107 (2)
O1W—K1—O13	85.90 (5)	K1iv—O1W—H1Wiv	119.8 (16)
O1W—K1—O13i	157.48 (4)	O11—C1—C2	115.78 (17)
O1W—K1—O13ii	82.81 (3)	O11—C1—C6	123.74 (18)
O1W—K1—O14iii	75.35 (4)	C2—C1—C6	120.48 (18)
O11—K1—O13	56.26 (4)	C1—C2—C3	118.42 (18)
O11—K1—O13i	87.00 (4)	C2—C3—C4	122.86 (19)
O11—K1—O13ii	133.96 (4)	Cl3—C3—C4	118.13 (15)
O11—K1—O14iii	101.01 (4)	Cl3—C3—C2	119.01 (15)
O13—K1—O13i	103.70 (4)	C3—C4—C5	116.88 (18)
O13—K1—O13ii	85.35 (4)	Cl5—C5—C4	119.39 (16)
O13—K1—O14iii	140.71 (4)	C4—C5—C6	122.91 (19)
O13i—K1—O13ii	77.83 (4)	Cl5—C5—C6	117.71 (17)
O13i—K1—O14iii	106.68 (4)	C1—C6—C5	118.45 (19)
O13ii—K1—O14iii	124.93 (5)	O11—C12—C13	111.48 (16)
K1—O1W—K1iv	100.60 (7)	O13—C13—C12	119.43 (18)
K1—O11—C1	126.11 (11)	O14—C13—C12	113.81 (18)
K1—O11—C12	116.68 (10)	O13—C13—O14	126.70 (18)
C1—O11—C12	116.72 (15)	C1—C2—H2	121.00
K1—O13—C13	123.69 (11)	C3—C2—H2	121.00
K1—O13—K1v	103.70 (5)	C3—C4—H4	122.00
K1—O13—K1ii	94.65 (4)	C5—C4—H4	122.00
K1v—O13—C13	116.55 (11)	C1—C6—H6	121.00
K1ii—O13—C13	112.14 (12)	C5—C6—H6	121.00
K1v—O13—K1ii	102.18 (4)	O11—C12—H121	109.00
K1vi—O14—C13	137.09 (12)	O11—C12—H122	109.00
K1iv—O1W—H1W	105.4 (15)	C13—C12—H121	109.00
K1—O1W—H1W	119.8 (16)	C13—C12—H122	109.00
K1—O1W—H1Wiv	105.4 (15)	H121—C12—H122	108.00
O11—K1—O1W—K1iv	−146.99 (3)	O13—K1—O13ii—K1ii	−0.02 (5)
O13—K1—O1W—K1iv	163.37 (3)	O13—K1—O13ii—C13ii	−129.34 (12)
O1W—K1—O11—C1	99.66 (13)	O11—K1—O14iii—C13iii	87.4 (2)
O1W—K1—O11—C12	−88.68 (13)	O13—K1—O14iii—C13iii	38.4 (2)
O13—K1—O11—C1	165.74 (15)	K1—O11—C1—C2	−1.4 (2)
O13—K1—O11—C12	−22.60 (12)	K1—O11—C1—C6	179.21 (14)
O13i—K1—O11—C1	−85.59 (14)	C12—O11—C1—C2	−173.08 (17)
O13i—K1—O11—C12	86.08 (12)	C12—O11—C1—C6	7.6 (3)
O13ii—K1—O11—C1	−155.47 (13)	K1—O11—C12—C13	15.98 (19)
O13ii—K1—O11—C12	16.20 (14)	C1—O11—C12—C13	−171.55 (15)
O14iii—K1—O11—C1	20.83 (14)	K1—O13—C13—O14	143.75 (15)
O14iii—K1—O11—C12	−167.51 (12)	K1—O13—C13—C12	−39.2 (2)
O1W—K1—O13—C13	156.32 (14)	K1v—O13—C13—O14	−85.6 (2)
O1W—K1—O13—K1v	20.65 (4)	K1v—O13—C13—C12	91.41 (17)
O1W—K1—O13—K1ii	−83.10 (4)	K1ii—O13—C13—O14	31.6 (2)
O11—K1—O13—C13	32.52 (14)	K1ii—O13—C13—C12	−151.35 (14)
O11—K1—O13—K1v	−103.16 (5)	K1vi—O14—C13—O13	−90.6 (2)
O11—K1—O13—K1ii	153.10 (6)	K1vi—O14—C13—C12	92.3 (2)
O13i—K1—O13—C13	−44.32 (15)	O11—C1—C2—C3	−179.06 (16)
O13i—K1—O13—K1v	179.98 (9)	C6—C1—C2—C3	0.3 (3)
O13i—K1—O13—K1ii	76.26 (5)	O11—C1—C6—C5	179.20 (18)
O13ii—K1—O13—C13	−120.58 (14)	C2—C1—C6—C5	−0.1 (3)
O13ii—K1—O13—K1v	103.75 (5)	C1—C2—C3—Cl3	179.16 (14)
O13ii—K1—O13—K1ii	0.02 (8)	C1—C2—C3—C4	−0.3 (3)
O14iii—K1—O13—C13	95.53 (16)	Cl3—C3—C4—C5	−179.45 (16)
O14iii—K1—O13—K1v	−40.15 (8)	C2—C3—C4—C5	0.0 (3)
O14iii—K1—O13—K1ii	−143.89 (6)	C3—C4—C5—Cl5	179.79 (16)
O11—K1—O13i—K1i	125.82 (4)	C3—C4—C5—C6	0.2 (3)
O11—K1—O13i—C13i	−13.64 (13)	Cl5—C5—C6—C1	−179.71 (16)
O13—K1—O13i—K1i	180.00 (4)	C4—C5—C6—C1	−0.2 (3)
O13—K1—O13i—C13i	40.53 (13)	O11—C12—C13—O13	12.0 (2)
O11—K1—O13ii—K1ii	−31.51 (7)	O11—C12—C13—O14	−170.65 (16)
O11—K1—O13ii—C13ii	−160.85 (11)

D—H···A	D—H	H···A	D···A	D—H···A
O1W—H1W···O14vii	0.85 (2)	1.90 (2)	2.750 (2)	174 (2)

[Rb2(C8H5Cl2O3)2(H2O)]	F(000) = 1224
Mr = 629.00	Dx = 1.913 Mg m−3
Monoclinic, C2/c	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: -C 2yc	Cell parameters from 2435 reflections
a = 39.641 (3) Å	θ = 3.6–28.3°
b = 4.3302 (3) Å	µ = 5.01 mm−1
c = 12.8607 (8) Å	T = 200 K
β = 98.404 (5)°	Prism, colourless
V = 2183.9 (3) Å3	0.40 × 0.12 × 0.04 mm
Z = 4

Oxford Diffraction Gemini-S CCD-detector diffractometer	2152 independent reflections
Radiation source: Enhance (Mo) X-ray source	1910 reflections with I > 2σ(I)
Graphite monochromator	Rint = 0.055
Detector resolution: 16.077 pixels mm-1	θmax = 26.0°, θmin = 3.2°
ω–scans	h = −45→48
Absorption correction: multi-scan (CrysAlis PRO; Agilent, 2013)	k = −5→5
Tmin = 0.369, Tmax = 0.980	l = −15→15
7520 measured reflections

Refinement on F2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.040	Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.095	H atoms treated by a mixture of independent and constrained refinement
S = 1.06	w = 1/[σ2(Fo2) + (0.0491P)2] where P = (Fo2 + 2Fc2)/3
2152 reflections	(Δ/σ)max = 0.003
136 parameters	Δρmax = 0.98 e Å−3
1 restraint	Δρmin = −1.00 e Å−3

Geometry. Bond distances, angles etc. have been calculated using the rounded fractional coordinates. All su's are estimated from the variances of the (full) variance-covariance matrix. The cell esds are taken into account in the estimation of distances, angles and torsion angles

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > 2sigma(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

	x	y	z	Uiso*/Ueq
Rb1	0.53252 (1)	0.71425 (8)	0.41106 (2)	0.0271 (1)
Cl3	0.66575 (3)	1.1071 (2)	0.31320 (7)	0.0394 (3)
Cl5	0.72802 (2)	0.4700 (3)	0.64713 (9)	0.0510 (4)
O1W	0.50000	0.2897 (8)	0.25000	0.0336 (12)
O11	0.59805 (6)	0.4938 (6)	0.54449 (18)	0.0312 (8)
O13	0.53789 (6)	0.2205 (5)	0.5570 (2)	0.0295 (8)
O14	0.55505 (6)	0.0734 (6)	0.72371 (19)	0.0341 (8)
C1	0.63017 (8)	0.5832 (8)	0.5286 (3)	0.0255 (11)
C2	0.63168 (10)	0.7780 (8)	0.4420 (3)	0.0278 (11)
C3	0.66324 (10)	0.8701 (8)	0.4215 (3)	0.0284 (11)
C4	0.69371 (11)	0.7828 (8)	0.4829 (3)	0.0327 (12)
C5	0.69102 (9)	0.5914 (9)	0.5678 (3)	0.0302 (11)
C6	0.66010 (8)	0.4923 (8)	0.5924 (3)	0.0267 (11)
C12	0.59553 (9)	0.3198 (8)	0.6376 (3)	0.0285 (11)
C13	0.55928 (9)	0.1991 (8)	0.6381 (3)	0.0243 (11)
H1W	0.4832 (8)	0.172 (8)	0.266 (4)	0.0510*
H2	0.61150	0.84410	0.39880	0.0330*
H4	0.71520	0.85090	0.46730	0.0390*
H6	0.65920	0.36420	0.65190	0.0320*
H121	0.60210	0.45220	0.70000	0.0340*
H122	0.61160	0.14340	0.64200	0.0340*

	U11	U22	U33	U12	U13	U23
Rb1	0.0270 (2)	0.0340 (2)	0.0204 (2)	0.0005 (1)	0.0035 (2)	0.0014 (1)
Cl3	0.0502 (6)	0.0428 (6)	0.0275 (5)	−0.0119 (5)	0.0132 (5)	0.0037 (4)
Cl5	0.0231 (5)	0.0802 (8)	0.0474 (6)	−0.0029 (5)	−0.0022 (5)	0.0124 (6)
O1W	0.028 (2)	0.034 (2)	0.039 (2)	0.0000	0.0057 (19)	0.0000
O11	0.0205 (13)	0.0506 (16)	0.0227 (13)	−0.0044 (11)	0.0038 (11)	0.0129 (12)
O13	0.0245 (14)	0.0378 (14)	0.0255 (14)	−0.0029 (10)	0.0013 (12)	−0.0011 (11)
O14	0.0317 (14)	0.0491 (16)	0.0232 (13)	−0.0085 (13)	0.0100 (12)	0.0059 (12)
C1	0.0249 (19)	0.0317 (19)	0.0205 (18)	−0.0028 (16)	0.0051 (16)	−0.0045 (16)
C2	0.027 (2)	0.035 (2)	0.0215 (19)	−0.0002 (15)	0.0038 (17)	−0.0013 (15)
C3	0.037 (2)	0.0300 (19)	0.0194 (18)	−0.0075 (17)	0.0084 (17)	−0.0052 (15)
C4	0.028 (2)	0.044 (2)	0.028 (2)	−0.0104 (17)	0.0106 (18)	−0.0055 (17)
C5	0.0238 (19)	0.042 (2)	0.0241 (18)	−0.0042 (17)	0.0013 (16)	−0.0036 (17)
C6	0.0244 (19)	0.035 (2)	0.0207 (18)	−0.0020 (15)	0.0036 (15)	−0.0013 (16)
C12	0.025 (2)	0.040 (2)	0.0200 (18)	−0.0040 (16)	0.0018 (16)	0.0041 (16)
C13	0.024 (2)	0.0269 (18)	0.0231 (19)	0.0007 (15)	0.0071 (17)	−0.0048 (15)

Rb1—O1W	2.924 (2)	O1W—H1Wiv	0.89 (3)
Rb1—O11	3.050 (2)	C1—C6	1.397 (5)
Rb1—O13	2.832 (2)	C1—C2	1.405 (5)
Rb1—O13i	2.874 (2)	C2—C3	1.375 (6)
Rb1—O13ii	2.894 (2)	C3—C4	1.395 (6)
Rb1—O14iii	2.842 (2)	C4—C5	1.387 (5)
Cl3—C3	1.745 (4)	C5—C6	1.378 (5)
Cl5—C5	1.741 (4)	C12—C13	1.530 (5)
O11—C1	1.374 (4)	C2—H2	0.9500
O11—C12	1.431 (4)	C4—H4	0.9500
O13—C13	1.248 (5)	C6—H6	0.9500
O14—C13	1.261 (4)	C12—H121	0.9900
O1W—H1W	0.89 (3)	C12—H122	0.9900
O1W—Rb1—O11	116.93 (7)	H1W—O1W—H1Wiv	110 (3)
O1W—Rb1—O13	88.71 (7)	Rb1iv—O1W—H1Wiv	118 (3)
O1W—Rb1—O13i	157.69 (6)	O11—C1—C2	115.8 (3)
O1W—Rb1—O13ii	80.06 (5)	O11—C1—C6	124.0 (3)
O1W—Rb1—O14iii	76.32 (6)	C2—C1—C6	120.3 (3)
O11—Rb1—O13	54.24 (7)	C1—C2—C3	118.1 (3)
O11—Rb1—O13i	84.01 (7)	C2—C3—C4	123.3 (4)
O11—Rb1—O13ii	135.28 (7)	Cl3—C3—C4	117.8 (3)
O11—Rb1—O14iii	103.36 (7)	Cl3—C3—C2	118.9 (3)
O13—Rb1—O13i	98.73 (7)	C3—C4—C5	116.6 (4)
O13—Rb1—O13ii	87.72 (7)	Cl5—C5—C4	119.1 (3)
O13—Rb1—O14iii	143.47 (7)	C4—C5—C6	122.7 (4)
O13i—Rb1—O13ii	79.26 (7)	Cl5—C5—C6	118.2 (3)
O13i—Rb1—O14iii	107.73 (7)	C1—C6—C5	119.0 (3)
O13ii—Rb1—O14iii	121.19 (7)	O11—C12—C13	111.3 (3)
Rb1—O1W—Rb1iv	102.10 (11)	O13—C13—C12	119.7 (3)
Rb1—O11—C1	124.0 (2)	O14—C13—C12	113.3 (3)
Rb1—O11—C12	118.55 (19)	O13—C13—O14	126.9 (3)
C1—O11—C12	116.9 (3)	C1—C2—H2	121.00
Rb1—O13—C13	125.9 (2)	C3—C2—H2	121.00
Rb1—O13—Rb1v	98.73 (8)	C3—C4—H4	122.00
Rb1—O13—Rb1ii	92.28 (7)	C5—C4—H4	122.00
Rb1v—O13—C13	117.8 (2)	C1—C6—H6	121.00
Rb1ii—O13—C13	116.1 (2)	C5—C6—H6	120.00
Rb1v—O13—Rb1ii	100.74 (7)	O11—C12—H121	109.00
Rb1vi—O14—C13	134.3 (2)	O11—C12—H122	109.00
Rb1iv—O1W—H1W	105 (3)	C13—C12—H121	109.00
Rb1—O1W—H1W	118 (3)	C13—C12—H122	109.00
Rb1—O1W—H1Wiv	105 (3)	H121—C12—H122	108.00
O11—Rb1—O1W—Rb1iv	−149.55 (5)	O13—Rb1—O13ii—Rb1ii	0.00 (7)
O13—Rb1—O1W—Rb1iv	162.30 (5)	O13—Rb1—O13ii—C13ii	−132.3 (2)
O1W—Rb1—O11—C1	101.0 (2)	O11—Rb1—O14iii—C13iii	88.7 (3)
O1W—Rb1—O11—C12	−87.7 (2)	O13—Rb1—O14iii—C13iii	42.2 (4)
O13—Rb1—O11—C1	167.6 (3)	Rb1—O11—C1—C2	−2.7 (4)
O13—Rb1—O11—C12	−21.0 (2)	Rb1—O11—C1—C6	177.2 (3)
O13i—Rb1—O11—C1	−87.1 (2)	C12—O11—C1—C2	−174.3 (3)
O13i—Rb1—O11—C12	84.3 (2)	C12—O11—C1—C6	5.7 (5)
O13ii—Rb1—O11—C1	−155.3 (2)	Rb1—O11—C12—C13	15.6 (3)
O13ii—Rb1—O11—C12	16.1 (3)	C1—O11—C12—C13	−172.4 (3)
O14iii—Rb1—O11—C1	19.7 (3)	Rb1—O13—C13—O14	147.4 (3)
O14iii—Rb1—O11—C12	−168.9 (2)	Rb1—O13—C13—C12	−35.8 (4)
O1W—Rb1—O13—C13	155.0 (3)	Rb1v—O13—C13—O14	−86.3 (4)
O1W—Rb1—O13—Rb1v	21.13 (6)	Rb1v—O13—C13—C12	90.5 (3)
O1W—Rb1—O13—Rb1ii	−80.10 (5)	Rb1ii—O13—C13—O14	33.2 (4)
O11—Rb1—O13—C13	29.9 (3)	Rb1ii—O13—C13—C12	−150.0 (2)
O11—Rb1—O13—Rb1v	−103.93 (9)	Rb1vi—O14—C13—O13	−90.5 (4)
O11—Rb1—O13—Rb1ii	154.83 (10)	Rb1vi—O14—C13—C12	92.5 (3)
O13i—Rb1—O13—C13	−46.2 (3)	O11—C1—C2—C3	−178.9 (3)
O13i—Rb1—O13—Rb1v	179.98 (11)	C6—C1—C2—C3	1.1 (5)
O13i—Rb1—O13—Rb1ii	78.77 (7)	O11—C1—C6—C5	178.8 (3)
O13ii—Rb1—O13—C13	−124.9 (3)	C2—C1—C6—C5	−1.3 (5)
O13ii—Rb1—O13—Rb1v	101.23 (7)	C1—C2—C3—Cl3	179.0 (3)
O13ii—Rb1—O13—Rb1ii	0.00 (7)	C1—C2—C3—C4	−0.7 (6)
O14iii—Rb1—O13—C13	90.3 (3)	Cl3—C3—C4—C5	−179.3 (3)
O14iii—Rb1—O13—Rb1v	−43.54 (14)	C2—C3—C4—C5	0.5 (5)
O14iii—Rb1—O13—Rb1ii	−144.77 (9)	C3—C4—C5—Cl5	179.4 (3)
O11—Rb1—O13i—Rb1i	127.64 (8)	C3—C4—C5—C6	−0.7 (6)
O11—Rb1—O13i—C13i	−11.0 (2)	Cl5—C5—C6—C1	−178.9 (3)
O13—Rb1—O13i—Rb1i	179.98 (10)	C4—C5—C6—C1	1.1 (6)
O13—Rb1—O13i—C13i	41.3 (2)	O11—C12—C13—O13	10.0 (4)
O11—Rb1—O13ii—Rb1ii	−29.37 (12)	O11—C12—C13—O14	−172.7 (3)
O11—Rb1—O13ii—C13ii	−161.6 (2)

D—H···A	D—H	H···A	D···A	D—H···A
O1W—H1W···O14vii	0.89 (3)	1.87 (3)	2.750 (3)	171 (5)