Literature DB >> 26507380

Rhenium(V)-oxo corrolazines: isolating redox-active ligand reactivity.

Jan Paulo T Zaragoza1, Maxime A Siegler1, David P Goldberg1.   

Abstract

The synthesis of the first example of a third-row metallocorrolazine characterized by single crystal X-ray diffraction is reported. This Re(V)(O) porphyrinoid complex shows an exclusively ligand-based reactivity with strong acids and oxidizing agents. The one-electron oxidized π-radical-cation complex is capable of H-atom abstraction.

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Year:  2016        PMID： 26507380      PMCID： PMC4679572          DOI： 10.1039/c5cc07956j

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  28 in total

1.  Chemical Redox Agents for Organometallic Chemistry.

Authors:  Neil G. Connelly; William E. Geiger
Journal:  Chem Rev       Date:  1996-03-28       Impact factor: 60.622

2.  Heme-Containing Oxygenases.

Authors:  Masanori Sono; Mark P. Roach; Eric D. Coulter; John H. Dawson
Journal:  Chem Rev       Date:  1996-11-07       Impact factor: 60.622

3.  Synthesis, characterization, and physicochemical properties of manganese(III) and manganese(V)-oxo corrolazines.

Authors:  David E Lansky; Beaven Mandimutsira; Bobby Ramdhanie; Maria Clausén; James Penner-Hahn; S A Zvyagin; Joshua Telser; J Krzystek; Riqiang Zhan; Zhongping Ou; Karl M Kadish; Lev Zakharov; Arnold L Rheingold; David P Goldberg
Journal:  Inorg Chem       Date:  2005-06-27       Impact factor: 5.165

Review 4.  High-valent corrole metal complexes.

Authors:  Z Gross
Journal:  J Biol Inorg Chem       Date:  2001-09       Impact factor: 3.358

5.  An isolable, nonreducible high-valent manganese(V) imido corrolazine complex.

Authors:  David E Lansky; Joseph R Kosack; Amy A Narducci Sarjeant; David P Goldberg
Journal:  Inorg Chem       Date:  2006-10-16       Impact factor: 5.165

6.  Hydrogen atom abstraction by a high-valent manganese(V)-oxo corrolazine.

Authors:  David E Lansky; David P Goldberg
Journal:  Inorg Chem       Date:  2006-06-26       Impact factor: 5.165

7.  Mechanism for reduction catalysis by metal oxo: hydrosilation of organic carbonyl groups catalyzed by a rhenium(V) oxo complex.

Authors:  Elon A Ison; Evan R Trivedi; Rex A Corbin; Mahdi M Abu-Omar
Journal:  J Am Chem Soc       Date:  2005-11-09       Impact factor: 15.419

8.  Swift oxo transfer reactions of perchlorate and other substrates catalyzed by rhenium oxazoline and thiazoline complexes.

Authors:  Mahdi M Abu-Omar
Journal:  Chem Commun (Camb)       Date:  2003-09-07       Impact factor: 6.222

9.  Rhenium-188 labelled meso-tetrakis[3,4-bis(carboxymethyleneoxy)phenyl] porphyrin for targeted radiotherapy: preliminary biological evaluation in mice.

Authors:  Zhi-yun Jia; Hou-fu Deng; Man-fei Pu; Shun-zhong Luo
Journal:  Eur J Nucl Med Mol Imaging       Date:  2008-01-12       Impact factor: 9.236

10.  Kinetics and mechanism of rhenium-catalyzed O atom transfer from epoxides.

Authors:  Kevin P Gable; Eric C Brown
Journal:  J Am Chem Soc       Date:  2003-09-10       Impact factor: 15.419
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  6 in total

1.  Factors Affecting Hydrogen Atom Transfer Reactivity of Metal-Oxo Porphyrinoid Complexes.

Authors:  Jireh Joy D Sacramento; David P Goldberg
Journal:  Acc Chem Res       Date:  2018-11-07       Impact factor: 22.384

2.  meso-N-Methylation of a porphyrinoid complex: activating the H-atom transfer capability of an inert ReV(O) corrolazine.

Authors:  Evan E Joslin; Jan Paulo T Zaragoza; Maxime A Siegler; David P Goldberg
Journal:  Chem Commun (Camb)       Date:  2017-02-07       Impact factor: 6.222

Review 3.  Activation of Dioxygen by Iron and Manganese Complexes: A Heme and Nonheme Perspective.

Authors:  Sumit Sahu; David P Goldberg
Journal:  J Am Chem Soc       Date:  2016-08-30       Impact factor: 15.419

4.  The Influence of Peripheral Substituent Modification on P(V), Mn(III), and Mn(V)(O) Corrolazines: X-ray Crystallography, Electrochemical and Spectroscopic Properties, and HAT and OAT Reactivities.

Authors:  Evan E Joslin; Jan Paulo T Zaragoza; Regina A Baglia; Maxime A Siegler; David P Goldberg
Journal:  Inorg Chem       Date:  2016-08-16       Impact factor: 5.165

5.  Oriented External Electric Fields Regurating the Reaction Mechanism of CH4 Oxidation Catalyzed by Fe(IV)-Oxo-Corrolazine: Insight from Density Functional Calculations.

Authors:  Jie Wu; Tairen Long; Haiyan Wang; Jin-Xia Liang; Chun Zhu
Journal:  Front Chem       Date:  2022-06-29       Impact factor: 5.545

6.  Statistical analysis of C-H activation by oxo complexes supports diverse thermodynamic control over reactivity.

Authors:  Joseph E Schneider; McKenna K Goetz; John S Anderson
Journal:  Chem Sci       Date:  2021-01-29       Impact factor: 9.825
  6 in total

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