The synthesis of the first example of a third-row metallocorrolazine characterized by single crystal X-ray diffraction is reported. This Re(V)(O) porphyrinoid complex shows an exclusively ligand-based reactivity with strong acids and oxidizing agents. The one-electron oxidized π-radical-cation complex is capable of H-atom abstraction.
The synthesis of the first example of a third-row n class="Chemical">metallocorrolazine characterized by single crystal X-ray diffraction is reported. This Re(V)(O) porphyrinoid complex shows an exclusively ligand-based reactivity with strong acids and oxidizing agents. The one-electron oxidized π-radical-cation complex is capable of H-atom abstraction.
Authors: David E Lansky; Beaven Mandimutsira; Bobby Ramdhanie; Maria Clausén; James Penner-Hahn; S A Zvyagin; Joshua Telser; J Krzystek; Riqiang Zhan; Zhongping Ou; Karl M Kadish; Lev Zakharov; Arnold L Rheingold; David P Goldberg Journal: Inorg Chem Date: 2005-06-27 Impact factor: 5.165
Authors: Evan E Joslin; Jan Paulo T Zaragoza; Regina A Baglia; Maxime A Siegler; David P Goldberg Journal: Inorg Chem Date: 2016-08-16 Impact factor: 5.165