Literature DB >> 28119963

meso-N-Methylation of a porphyrinoid complex: activating the H-atom transfer capability of an inert ReV(O) corrolazine.

Evan E Joslin1, Jan Paulo T Zaragoza1, Maxime A Siegler1, David P Goldberg1.   

Abstract

The selective alkylation of a single meso-N atom of a corrolazine macrocycle is reported. Alkylation has a dramatic impact on the physicochemical properties of ReV(O)(TBP8Cz). New electron-transfer and hydrogen-atom-transfer reactivity is also seen for this complex, including one-electron reduction, which gives an air-stable 19π-electron aromatic radical complex.

Entities:  

Year:  2017        PMID： 28119963      PMCID： PMC5351293          DOI： 10.1039/c6cc09341h

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  33 in total

1.  Valence tautomerism in a high-valent manganese-oxo porphyrinoid complex induced by a Lewis acid.

Authors:  Pannee Leeladee; Regina A Baglia; Katharine A Prokop; Reza Latifi; Sam P de Visser; David P Goldberg
Journal:  J Am Chem Soc       Date:  2012-06-15       Impact factor: 15.419

Review 2.  Thermochemistry of proton-coupled electron transfer reagents and its implications.

Authors:  Jeffrey J Warren; Tristan A Tronic; James M Mayer
Journal:  Chem Rev       Date:  2010-10-06       Impact factor: 60.622

3.  Molecular cosensitization for efficient panchromatic dye-sensitized solar cells.

Authors:  Juan-José Cid; Jun-Ho Yum; Song-Rim Jang; Mohammad K Nazeeruddin; Eugenia Martínez-Ferrero; Emilio Palomares; Jaejung Ko; Michael Grätzel; Tomás Torres
Journal:  Angew Chem Int Ed Engl       Date:  2007       Impact factor: 15.336

4.  Catalysis of recombination and its limitation on open circuit voltage for dye sensitized photovoltaic cells using phthalocyanine dyes.

Authors:  Brian C O'Regan; Ismael López-Duarte; M Victoria Martínez-Díaz; Amparo Forneli; Josep Albero; Ana Morandeira; Emilio Palomares; Tomas Torres; James R Durrant
Journal:  J Am Chem Soc       Date:  2008-02-19       Impact factor: 15.419

5.  Mn(V)(O) versus Cr(V)(O) Porphyrinoid Complexes: Structural Characterization and Implications for Basicity Controlling H-Atom Abstraction.

Authors:  Regina A Baglia; Katharine A Prokop-Prigge; Heather M Neu; Maxime A Siegler; David P Goldberg
Journal:  J Am Chem Soc       Date:  2015-08-21       Impact factor: 15.419

6.  Hydrogen atom abstraction by a high-valent manganese(V)-oxo corrolazine.

Authors:  David E Lansky; David P Goldberg
Journal:  Inorg Chem       Date:  2006-06-26       Impact factor: 5.165

7.  The Corrole Radical.

Authors:  Peter Schweyen; Kai Brandhorst; Richard Wicht; Benedikt Wolfram; Martin Bröring
Journal:  Angew Chem Int Ed Engl       Date:  2015-06-12       Impact factor: 15.336

8.  An antiaromatic electrode-active material enabling high capacity and stable performance of rechargeable batteries.

Authors:  Ji-Young Shin; Tetsuya Yamada; Hirofumi Yoshikawa; Kunio Awaga; Hiroshi Shinokubo
Journal:  Angew Chem Int Ed Engl       Date:  2014-02-19       Impact factor: 15.336

9.  The Influence of Peripheral Substituent Modification on P(V), Mn(III), and Mn(V)(O) Corrolazines: X-ray Crystallography, Electrochemical and Spectroscopic Properties, and HAT and OAT Reactivities.

Authors:  Evan E Joslin; Jan Paulo T Zaragoza; Regina A Baglia; Maxime A Siegler; David P Goldberg
Journal:  Inorg Chem       Date:  2016-08-16       Impact factor: 5.165

10.  Mechanism of phenol oxidation by heterodinuclear Ni Cu bis(μ-oxo) complexes involving nucleophilic oxo groups.

Authors:  Subrata Kundu; Enrico Miceli; Erik R Farquhar; Kallol Ray
Journal:  Dalton Trans       Date:  2014-03-21       Impact factor: 4.390
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  1 in total

1.  Factors Affecting Hydrogen Atom Transfer Reactivity of Metal-Oxo Porphyrinoid Complexes.

Authors:  Jireh Joy D Sacramento; David P Goldberg
Journal:  Acc Chem Res       Date:  2018-11-07       Impact factor: 22.384
  1 in total

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