Literature DB >> 17029354

An isolable, nonreducible high-valent manganese(V) imido corrolazine complex.

David E Lansky1, Joseph R Kosack, Amy A Narducci Sarjeant, David P Goldberg.   

Abstract

The manganese(V) imido complex [(TBP8Cz)Mn(V)(NMes)] (2) was synthesized from the Mn(III) complex [(TBP8Cz)Mn(III)] (1) and thermolysis of mesityl azide. An X-ray structure of 2 reveals a short Mn-N distance [1.595(4) A], consistent with the Mn-N triple bond expected for a manganese(V) imido species. This high-valent species is remarkably inert to one- and two-electron reductive processes such as NR group transfer to alkenes or H-atom abstraction from O-H bonds. Electrochemical studies support this lack of reactivity. In contrast, oxidation of 2 is easily accomplished by treatment with [(4-BrC6H4)3N]*+SbCl6, giving a pi-radical-cation complex.

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Year:  2006        PMID： 17029354     DOI： 10.1021/ic0609251

Source DB:  PubMed          Journal:  Inorg Chem        ISSN： 0020-1669            Impact factor:   5.165


  6 in total

1.  Mn(V)(O) versus Cr(V)(O) Porphyrinoid Complexes: Structural Characterization and Implications for Basicity Controlling H-Atom Abstraction.

Authors:  Regina A Baglia; Katharine A Prokop-Prigge; Heather M Neu; Maxime A Siegler; David P Goldberg
Journal:  J Am Chem Soc       Date:  2015-08-21       Impact factor: 15.419

2.  meso-N-Methylation of a porphyrinoid complex: activating the H-atom transfer capability of an inert ReV(O) corrolazine.

Authors:  Evan E Joslin; Jan Paulo T Zaragoza; Maxime A Siegler; David P Goldberg
Journal:  Chem Commun (Camb)       Date:  2017-02-07       Impact factor: 6.222

3.  Photocatalytic Oxygenation of Substrates by Dioxygen with Protonated Manganese(III) Corrolazine.

Authors:  Jieun Jung; Heather M Neu; Pannee Leeladee; Maxime A Siegler; Kei Ohkubo; David P Goldberg; Shunichi Fukuzumi
Journal:  Inorg Chem       Date:  2016-03-14       Impact factor: 5.165

4.  Rhenium(V)-oxo corrolazines: isolating redox-active ligand reactivity.

Authors:  Jan Paulo T Zaragoza; Maxime A Siegler; David P Goldberg
Journal:  Chem Commun (Camb)       Date:  2016-01-04       Impact factor: 6.222

5.  Nitrogen Atom Transfer Catalysis by Metallonitrene C-H Insertion: Photocatalytic Amidation of Aldehydes.

Authors:  Till Schmidt-Räntsch; Hendrik Verplancke; Jonas N Lienert; Serhiy Demeshko; Matthias Otte; Gerard P Van Trieste; Kaleb A Reid; Joseph H Reibenspies; David C Powers; Max C Holthausen; Sven Schneider
Journal:  Angew Chem Int Ed Engl       Date:  2022-01-14       Impact factor: 16.823

6.  Crystal structure of nitrido[5,10,15,20-tetra-kis(4-methylphenyl)-porphyrinato]-manganese(V).

Authors:  Mason R Shields; Ilia A Guzei; James G Goll
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2014-09-24
  6 in total

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