Literature DB >> 25323663

A palladium nanoparticle-nanomicelle combination for the stereoselective semihydrogenation of alkynes in water at room temperature.

Eric D Slack1, Christopher M Gabriel, Bruce H Lipshutz.   

Abstract

The addition of NaBH4 to Pd(OAc)2 in water containing nanomicelles leads to the generation of H2 and Pd nanoparticles. Subsequent reduction of disubstituted alkynes affords Z-alkenes in high yields. These reactions are general, take place in water at ambient temperatures, and offer recycling of the aqueous reaction mixture along with low overall E Factors.
© 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  Lindlar reductions; green chemistry; micelles; nanoparticles; semihydrogenation

Mesh：

Substances：

Year:  2014        PMID： 25323663      PMCID： PMC4448917          DOI： 10.1002/anie.201407723

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  18 in total

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