Literature DB >> 24435479

Stereoselective iron-catalyzed alkyne hydrogenation in ionic liquids.

Tim N Gieshoff1, Alice Welther, Michael T Kessler, Martin H G Prechtl, Axel Jacobi von Wangelin.   

Abstract

Iron(0) nanoparticles in ionic liquids (ILs) have been shown to catalyse the semi-hydrogenation of alkynes. In the presence of a nitrile-functionalised IL or acetonitrile, stereoselective formation of (Z)-alkenes was observed. The biphasic solvent system allowed facile separation and re-use of the catalyst.

Entities:  

Mesh：

Substances：

Year:  2014        PMID： 24435479     DOI： 10.1039/c3cc49679a

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  4 in total

1.  Mechanism of the Bis(imino)pyridine-Iron-Catalyzed Hydromagnesiation of Styrene Derivatives.

Authors:  Peter G N Neate; Mark D Greenhalgh; William W Brennessel; Stephen P Thomas; Michael L Neidig
Journal:  J Am Chem Soc       Date:  2019-06-17       Impact factor: 15.419

2.  A palladium nanoparticle-nanomicelle combination for the stereoselective semihydrogenation of alkynes in water at room temperature.

Authors:  Eric D Slack; Christopher M Gabriel; Bruce H Lipshutz
Journal:  Angew Chem Int Ed Engl       Date:  2014-10-16       Impact factor: 15.336

3.  Synthesis of Bimetallic Pt/Sn-based Nanoparticles in Ionic Liquids.

Authors:  Christine Dietrich; Georgios Uzunidis; Yannick Träutlein; Silke Behrens
Journal:  J Vis Exp       Date:  2018-08-23       Impact factor: 1.355

4.  Nickel-Catalyzed Stereodivergent Synthesis of E- and Z-Alkenes by Hydrogenation of Alkynes.

Authors:  Kathiravan Murugesan; Charles Beromeo Bheeter; Pim R Linnebank; Anke Spannenberg; Joost N H Reek; Rajenahally V Jagadeesh; Matthias Beller
Journal:  ChemSusChem       Date:  2019-06-18       Impact factor: 8.928
  4 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.