Literature DB >> 24894885

New conserved structural fields for supercooled liquids.

Jean Farago1, Alexander Semenov, Stefan Frey, Jörg Baschnagel.   

Abstract

By considering Voronoi tessellations of the configurations of a fluid, we propose two new conserved fields, which provide structural information not fully accounted for by the usual 2-point density correlation functions. One of these fields is scalar and associated with the volume of the Voronoi cell, whereas the other one, termed the "geometric polarisation", is vectorial and related to the local anisotropy of the configurations. We study the static and dynamical properties of these fields in the supercooled regime of a model glass-forming liquid. We show that the geometric polarisation is statically correlated to the force field, but contrary to it develops a plateau regime when the temperature is lowered. This different relaxation is related to the cage effect in glass-forming liquids, which prevents a complete relaxation of the shape of the cage around particle on intermediate time scales.

Year:  2014        PMID: 24894885     DOI: 10.1140/epje/i2014-14046-9

Source DB:  PubMed          Journal:  Eur Phys J E Soft Matter        ISSN: 1292-8941            Impact factor:   1.890


  12 in total

1.  How reproducible are dynamic heterogeneities in a supercooled liquid?

Authors:  Asaph Widmer-Cooper; Peter Harrowell; H Fynewever
Journal:  Phys Rev Lett       Date:  2004-09-24       Impact factor: 9.161

2.  Inhomogeneous mode-coupling theory and growing dynamic length in supercooled liquids.

Authors:  Giulio Biroli; Jean-Philippe Bouchaud; Kunimasa Miyazaki; David R Reichman
Journal:  Phys Rev Lett       Date:  2006-11-06       Impact factor: 9.161

3.  Derivation of a microscopic theory of barriers and activated hopping transport in glassy liquids and suspensions.

Authors:  Kenneth S Schweizer
Journal:  J Chem Phys       Date:  2005-12-22       Impact factor: 3.488

4.  Voronoi cell volume distribution and configurational entropy of hard-spheres.

Authors:  V Senthil Kumar; V Kumaran
Journal:  J Chem Phys       Date:  2005-09-15       Impact factor: 3.488

5.  Predicting the long-time dynamic heterogeneity in a supercooled liquid on the basis of short-time heterogeneities.

Authors:  Asaph Widmer-Cooper; Peter Harrowell
Journal:  Phys Rev Lett       Date:  2006-05-10       Impact factor: 9.161

6.  A topographic view of supercooled liquids and glass formation.

Authors:  F H Stillinger
Journal:  Science       Date:  1995-03-31       Impact factor: 47.728

7.  Packing structures and transitions in liquids and solids.

Authors:  F H Stillinger; T A Weber
Journal:  Science       Date:  1984-09-07       Impact factor: 47.728

8.  Fluctuating nonlinear hydrodynamics and the liquid-glass transition.

Authors: 
Journal:  Phys Rev A Gen Phys       Date:  1986-09

9.  Spatiotemporal hierarchy of relaxation events, dynamical heterogeneities, and structural reorganization in a supercooled liquid.

Authors:  R Candelier; A Widmer-Cooper; J K Kummerfeld; O Dauchot; G Biroli; P Harrowell; D R Reichman
Journal:  Phys Rev Lett       Date:  2010-09-24       Impact factor: 9.161

10.  Continuous-time random-walk approach to supercooled liquids. I. Different definitions of particle jumps and their consequences.

Authors:  J Helfferich; F Ziebert; S Frey; H Meyer; J Farago; A Blumen; J Baschnagel
Journal:  Phys Rev E Stat Nonlin Soft Matter Phys       Date:  2014-04-25
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