Literature DB >> 24634189

Reductive amination without an external hydrogen Source.

Denis Chusov1, Benjamin List.   

Abstract

A method of reductive amination without an external hydrogen source is reported. Carbon monoxide is used as the reductant. The reaction proceeds efficiently for a variety of carbonyl compounds and amines at low catalyst loadings and is mechanistically interesting as it does not seem to involve molecular hydrogen.
© 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  amination; amines; atom economy; carbon monoxide; reduction

Year:  2014        PMID： 24634189     DOI： 10.1002/anie.201400059

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  8 in total

1.  Photoredox-catalyzed Direct Reductive Amination of Aldehydes without an External Hydrogen/Hydride Source.

Authors:  Rauful Alam; Gary A Molander
Journal:  Org Lett       Date:  2018-04-13       Impact factor: 6.005

Review 2.  Harnessing the Power of the Water-Gas Shift Reaction for Organic Synthesis.

Authors:  Andrea Ambrosi; Scott E Denmark
Journal:  Angew Chem Int Ed Engl       Date:  2016-09-06       Impact factor: 15.336

3.  N-formyl-stabilizing quasi-catalytic species afford rapid and selective solvent-free amination of biomass-derived feedstocks.

Authors:  Hu Li; Haixin Guo; Yaqiong Su; Yuya Hiraga; Zhen Fang; Emiel J M Hensen; Masaru Watanabe; Richard Lee Smith
Journal:  Nat Commun       Date:  2019-02-11       Impact factor: 14.919

4.  Synthesis, crystal structure and catalytic activity in reductive amination of di-chlorido-(η6-p-cymene)(2'-di-cyclo-hexyl-phosphanyl-2,6-di-meth-oxy-biphen-yl-κP)ruthenium(II).

Authors:  Maria Makarova; Alexey A Tsygankov; Olga Chusova; Ivan V Linko; Pavel V Dorovatovskii; Yan V Zubavichus
Journal:  Acta Crystallogr E Crystallogr Commun       Date:  2018-03-09

Review 5.  NAD(P)H-Dependent Dehydrogenases for the Asymmetric Reductive Amination of Ketones: Structure, Mechanism, Evolution and Application.

Authors:  Mahima Sharma; Juan Mangas-Sanchez; Nicholas J Turner; Gideon Grogan
Journal:  Adv Synth Catal       Date:  2017-05-11       Impact factor: 5.837

6.  Deoxygenation of Epoxides with Carbon Monoxide.

Authors:  Theo Maulbetsch; Eva Jürgens; Doris Kunz
Journal:  Chemistry       Date:  2020-07-23       Impact factor: 5.236

7.  Simple ruthenium-catalyzed reductive amination enables the synthesis of a broad range of primary amines.

Authors:  Thirusangumurugan Senthamarai; Kathiravan Murugesan; Jacob Schneidewind; Narayana V Kalevaru; Wolfgang Baumann; Helfried Neumann; Paul C J Kamer; Matthias Beller; Rajenahally V Jagadeesh
Journal:  Nat Commun       Date:  2018-10-08       Impact factor: 14.919

Review 8.  New Trends and Future Opportunities in the Enzymatic Formation of C-C, C-N, and C-O bonds.

Authors:  Jack J Sangster; James R Marshall; Nicholas J Turner; Juan Mangas-Sanchez
Journal:  Chembiochem       Date:  2021-11-24       Impact factor: 3.461
  8 in total

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