| Literature DB >> 24478114 |
Danqing Zheng1, Yuanyuan An, Zhenhua Li, Jie Wu.
Abstract
The coupling of aryldiazonium tetrafluoroborates, DABCO⋅(SO2)2, and hydrazines under metal-free conditions leads to the formation of aryl N-aminosulfonamides. The reaction proceeds smoothly at room temperature and shows broad functional-group tolerance. A radical process is proposed for this transformation.Entities:
Keywords: aminosulfonylation; aryldiazonium salt; hydrazine; metal-free conditions; sulfur dioxide
Mesh:
Substances:
Year: 2014 PMID: 24478114 DOI: 10.1002/anie.201309851
Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN: 1433-7851 Impact factor: 15.336