Literature DB >> 24362244

Mechanism of phenol oxidation by heterodinuclear Ni Cu bis(μ-oxo) complexes involving nucleophilic oxo groups.

Subrata Kundu1, Enrico Miceli, Erik R Farquhar, Kallol Ray.   

Abstract

Oxidation of phenols by heterodinuclear Cu(III)(μ-O)2Ni(III) complexes containing nucleophilic oxo groups occurs by both proton coupled electron transfer (PCET) and hydrogen atom transfer (HAT) mechanisms; the exact mechanism depends on the nature of the phenol as well as the substitution pattern of the ligand bound to Cu.

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Year:  2014        PMID: 24362244      PMCID: PMC4201338          DOI: 10.1039/c3dt52644e

Source DB:  PubMed          Journal:  Dalton Trans        ISSN: 1477-9226            Impact factor:   4.390


  23 in total

Review 1.  Proton and hydrogen currents in photosynthetic water oxidation.

Authors:  C Tommos; G T Babcock
Journal:  Biochim Biophys Acta       Date:  2000-05-12

Review 2.  Coupling of electron and proton transfer in oxidative water cleavage in photosynthesis.

Authors:  G Renger
Journal:  Biochim Biophys Acta       Date:  2004-04-12

3.  Polyphenols deriving from chalcones: investigations of redox activities.

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4.  A "side-on" superoxonickel complex [LNi(O2)] with a square-planar tetracoordinate nickel(II) center and its conversion into [LNi(mu-OH)2NiL].

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Journal:  Angew Chem Int Ed Engl       Date:  2008       Impact factor: 15.336

Review 5.  The biology and chemistry of high-valent iron-oxo and iron-nitrido complexes.

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Journal:  Nat Commun       Date:  2012-03-06       Impact factor: 14.919

6.  Hydrogen atom abstraction by a high-valent manganese(V)-oxo corrolazine.

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Journal:  Inorg Chem       Date:  2006-06-26       Impact factor: 5.165

7.  New insights into the oxidative electrochemistry of vitamin E.

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8.  Contrasting copper-dioxygen chemistry arising from alike tridentate alkyltriamine copper(I) complexes.

Authors:  Hong-Chang Liang; Christiana Xin Zhang; Mark J Henson; Roger D Sommer; Karen R Hatwell; Susan Kaderli; Andreas D Zuberbühler; Arnold L Rheingold; Edward I Solomon; Kenneth D Karlin
Journal:  J Am Chem Soc       Date:  2002-04-24       Impact factor: 15.419

9.  A high-valent heterobimetallic [Cu(III)(μ-O)2Ni(III)]2+ core with nucleophilic oxo groups.

Authors:  Subrata Kundu; Florian Felix Pfaff; Enrico Miceli; Ivelina Zaharieva; Christian Herwig; Shenglai Yao; Erik R Farquhar; Uwe Kuhlmann; Eckhard Bill; Peter Hildebrandt; Holger Dau; Matthias Driess; Christian Limberg; Kallol Ray
Journal:  Angew Chem Int Ed Engl       Date:  2013-04-15       Impact factor: 15.336

Review 10.  Lignin engineering.

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  9 in total

1.  Chromium-Salen Catalyzed Cross-Coupling of Phenols: Mechanism and Origin of the Selectivity.

Authors:  Yexenia Nieves-Quinones; Thomas J Paniak; Young Eun Lee; Sun Min Kim; Sergei Tcyrulnikov; Marisa C Kozlowski
Journal:  J Am Chem Soc       Date:  2019-06-13       Impact factor: 15.419

Review 2.  Copper-Oxygen Complexes Revisited: Structures, Spectroscopy, and Reactivity.

Authors:  Courtney E Elwell; Nicole L Gagnon; Benjamin D Neisen; Debanjan Dhar; Andrew D Spaeth; Gereon M Yee; William B Tolman
Journal:  Chem Rev       Date:  2017-01-19       Impact factor: 60.622

3.  Hydrogen Atom Abstraction by High-Valent Fe(OH) versus Mn(OH) Porphyrinoid Complexes: Mechanistic Insights from Experimental and Computational Studies.

Authors:  Jan Paulo T Zaragoza; Daniel C Cummins; M Qadri E Mubarak; Maxime A Siegler; Sam P de Visser; David P Goldberg
Journal:  Inorg Chem       Date:  2019-12-05       Impact factor: 5.165

4.  meso-N-Methylation of a porphyrinoid complex: activating the H-atom transfer capability of an inert ReV(O) corrolazine.

Authors:  Evan E Joslin; Jan Paulo T Zaragoza; Maxime A Siegler; David P Goldberg
Journal:  Chem Commun (Camb)       Date:  2017-02-07       Impact factor: 6.222

5.  A Reactive Manganese(IV)-Hydroxide Complex: A Missing Intermediate in Hydrogen Atom Transfer by High-Valent Metal-Oxo Porphyrinoid Compounds.

Authors:  Jan Paulo T Zaragoza; Maxime A Siegler; David P Goldberg
Journal:  J Am Chem Soc       Date:  2018-03-15       Impact factor: 15.419

Review 6.  Synthetic Fe/Cu Complexes: Toward Understanding Heme-Copper Oxidase Structure and Function.

Authors:  Suzanne M Adam; Gayan B Wijeratne; Patrick J Rogler; Daniel E Diaz; David A Quist; Jeffrey J Liu; Kenneth D Karlin
Journal:  Chem Rev       Date:  2018-10-29       Impact factor: 60.622

7.  Lewis-Acid-assisted Hydrogen Atom Transfer to Manganese(V)-Oxo Corrole through Valence Tautomerization.

Authors:  Curt J Bougher; Mahdi M Abu-Omar
Journal:  ChemistryOpen       Date:  2016-10-28       Impact factor: 2.911

8.  Reactivity of the copper(iii)-hydroxide unit with phenols.

Authors:  Debanjan Dhar; Gereon M Yee; Todd F Markle; James M Mayer; William B Tolman
Journal:  Chem Sci       Date:  2016-09-27       Impact factor: 9.825

9.  Concerted proton-electron transfer oxidation of phenols and hydrocarbons by a high-valent nickel complex.

Authors:  Katherine J Fisher; Margalit L Feuer; Hannah M C Lant; Brandon Q Mercado; Robert H Crabtree; Gary W Brudvig
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  9 in total

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