| Literature DB >> 24350563 |
Avijit Pramanik1, Maryam Emami Khansari, Douglas R Powell, Frank R Fronczek, Md Alamgir Hossain.
Abstract
A new hexaurea receptor has been synthesized, which absorbs atmospheric CO2 to produce an air-stable solid carbonate complex under normal conditions. Structural analysis of the carbonate complex with this receptor suggests that the carbonate is fully encapsulated within its highly organized intramolecular cavity via 12 strong NH···O bonds in the range of 2.703(3)-2.989(3) Å from six urea units, with each anionic oxygen coordinated via four NH···O bonds with two urea groups.Entities:
Mesh:
Substances:
Year: 2013 PMID: 24350563 PMCID: PMC3976990 DOI: 10.1021/ol403186k
Source DB: PubMed Journal: Org Lett ISSN: 1523-7052 Impact factor: 6.005