Literature DB >> 24228754

Silver-catalyzed vinylogous fluorination of vinyl diazoacetates.

Changming Qin1, Huw M L Davies.   

Abstract

A silver-catalyzed vinylogous fluorination of vinyl diazoacetates to generate γ-fluoro-α,β-unsaturated carbonyls is presented. Application of this method to the fluorination of farnesol and steroid derivatives was achieved.

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Year:  2013        PMID: 24228754      PMCID: PMC3880583          DOI: 10.1021/ol403017e

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  49 in total

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2.  Synthesis of [18F]-γ-fluoro-α,β,-unsaturated esters and ketones via vinylogous 18F-fluorination of α-diazoacetates with [18F]AgF.

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  6 in total

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