Literature DB >> 24222577

Comparison of the reactivity of nonheme iron(IV)-oxo versus iron(IV)-imido complexes: which is the better oxidant?

Anil Kumar Vardhaman1, Prasenjit Barman, Suresh Kumar, Chivukula V Sastri, Devesh Kumar, Sam P de Visser.   

Abstract

Which is better? The first detailed comparison of the reactivity of nonheme iron(IV)-imido versus nonheme iron(IV)-oxo intermediates with substrates is presented. The iron(IV)-imido variant reacts with sulfides five times faster than iron(IV)-oxo, whereas the reverse trend is observed for hydrogen atom abstraction. These observed trends are analyzed and explained.
Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  CH activation; enzyme models; imido ligands; iron; sulfoxidation

Mesh：

Substances：

Year:  2013        PMID： 24222577     DOI： 10.1002/anie.201305370

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  19 in total

1.  A Mononuclear Nonheme Iron(V)-Imido Complex.

Authors:  Seungwoo Hong; Kyle D Sutherlin; Anil Kumar Vardhaman; James J Yan; Sora Park; Yong-Min Lee; Soojeong Jang; Xiaoyan Lu; Takehiro Ohta; Takashi Ogura; Edward I Solomon; Wonwoo Nam
Journal:  J Am Chem Soc       Date:  2017-06-23       Impact factor: 15.419

2.  Do Spin State and Spin Density Affect Hydrogen Atom Transfer Reactivity?

Authors:  Caroline T Saouma; James M Mayer
Journal:  Chem Sci       Date:  2014-01-01       Impact factor: 9.825

3.  DFT analysis of the electronic structure of Fe(IV) species active in nitrene transfer catalysis: influence of the coordination sphere.

Authors:  Ranjan Patra; Pascale Maldivi
Journal:  J Mol Model       Date:  2016-10-27       Impact factor: 1.810

4.  Arene activation by a nonheme iron(III)-hydroperoxo complex: pathways leading to phenol and ketone products.

Authors:  Abayomi S Faponle; Frédéric Banse; Sam P de Visser
Journal:  J Biol Inorg Chem       Date:  2016-04-20       Impact factor: 3.358

5.  Singlet versus Triplet Reactivity in an Mn(V)-Oxo Species: Testing Theoretical Predictions Against Experimental Evidence.

Authors:  Tzuhsiung Yang; Matthew G Quesne; Heather M Neu; Fabián G Cantú Reinhard; David P Goldberg; Sam P de Visser
Journal:  J Am Chem Soc       Date:  2016-09-14       Impact factor: 15.419

6.  Alkyl Chain Growth on a Transition Metal Center: How Does Iron Compare to Ruthenium and Osmium?

Authors:  Mala A Sainna; Sam P de Visser
Journal:  Int J Mol Sci       Date:  2015-09-28       Impact factor: 5.923

7.  Cysteine protease inhibition by nitrile-based inhibitors: a computational study.

Authors:  Matthew G Quesne; Richard A Ward; Sam P de Visser
Journal:  Front Chem       Date:  2013-12-27       Impact factor: 5.221

8.  Differences and comparisons of the properties and reactivities of iron(III)-hydroperoxo complexes with saturated coordination sphere.

Authors:  Abayomi S Faponle; Matthew G Quesne; Chivukula V Sastri; Frédéric Banse; Sam P de Visser
Journal:  Chemistry       Date:  2014-11-14       Impact factor: 5.236

9.  Identification and Spectroscopic Characterization of Nonheme Iron(III) Hypochlorite Intermediates.

Authors:  Apparao Draksharapu; Davide Angelone; Matthew G Quesne; Sandeep K Padamati; Laura Gómez; Ronald Hage; Miquel Costas; Wesley R Browne; Sam P de Visser
Journal:  Angew Chem Weinheim Bergstr Ger       Date:  2015-02-06

10.  Mechanistic insight into oxygen atom transfer reactions by mononuclear manganese(IV)-oxo adducts.

Authors:  Priya Singh; Eleanor Stewart-Jones; Melissa C Denler; Timothy A Jackson
Journal:  Dalton Trans       Date:  2021-03-16       Impact factor: 4.390
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