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Literature DB >> 23597402

Enantioselective thiourea-catalyzed intramolecular cope-type hydroamination.

Adam R Brown¹, Christopher Uyeda, Carolyn A Brotherton, Eric N Jacobsen.

Abstract

Catalysis of Cope-type rearrangements of class="Chemical">bis-homoallylic hydroxylamines is democlass="Chemical">nstrated usiclass="Chemical">ng chiral class="Chemical">n class="Chemical">thiourea derivatives. This formal intramolecular hydroamination reaction provides access to highly enantioenriched α-substituted pyrrolidine products and represents a complementary approach to metal-catalyzed methods.

Entities: Chemical Gene Species

Mesh：

Substances：
Hydroxylamine
Thiourea

Year: 2013 PMID： 23597402 PMCID： PMC3689223 DOI： 10.1021/ja402893z

Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419

51 in total

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5. Catalytic Asymmetric Synthesis of α-Arylpyrrolidines and Benzo-fused Nitrogen Heterocycles.

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10. Nucleophile-Assisted Alkene Activation: Olefins Alone Are Often Incompetent.

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