| Literature DB >> 23476521 |
B Balakrishnan1, Meganathan Nandakumar, P R Seshadri, Arasambattu K Mohanakrishnan.
Abstract
The title compound, C28H26O5, is the Diels-Alder adduct from 1,3-diphenyl-benzo[c]furan and diethyl maleate. The mol-ecule comprises of a fused tricyclic system containing two five-membered rings, which are in envelope conformations with the O atom at the flap, and a six-membered ring adopting a boat conformation. The dihedral angle between phenyl substituents in the 1,8-positions is 55.1 (1)°. The ethyl groups are disordered over two sets of sites, with occupancy ratios of 0.648 (9):0.352 (9) and 0.816 (1):0.184 (1). In the crystal, pairs of C-H⋯π inter-actions link the mol-ecules into inversion dimers.Entities:
Year: 2013 PMID: 23476521 PMCID: PMC3588525 DOI: 10.1107/S1600536813002791
Source DB: PubMed Journal: Acta Crystallogr Sect E Struct Rep Online ISSN: 1600-5368