Literature DB >> 23931747

A CO-derived iron dicarbyne that releases olefin upon hydrogenation.

Daniel L M Suess1, Jonas C Peters.   

Abstract

An class="Chemical">iron diphosphineborane class="Chemical">platform that was class="Chemical">previously reported to facilitate a high degree of pan class="Chemical">N2 functionalization is herein shown to effect reductive CO coupling. Disilylation of an iron dicarbonyl precursor furnishes a structurally unprecedented iron dicarbyne complex. Several complexes related to this process are also characterized which allows for a comparative analysis of their respective Fe-B and Fe-C bonding. Facile hydrogenation of the iron dicarbyne at ambient temperature and 1 atm H2 results in release of a CO-derived olefin.

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Year:  2013        PMID： 23931747      PMCID： PMC3794666          DOI： 10.1021/ja406874k

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  17 in total

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Authors:  Yunho Lee; Jonas C Peters
Journal:  J Am Chem Soc       Date:  2011-03-04       Impact factor: 15.419

10.  Molybdenum nitrogenase catalyzes the reduction and coupling of CO to form hydrocarbons.

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  8 in total

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3.  Mononuclear Fe(I) and Fe(II) Acetylene Adducts and Their Reductive Protonation to Terminal Fe(IV) and Fe(V) Carbynes.

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Journal:  J Am Chem Soc       Date:  2019-09-09       Impact factor: 15.419

4.  Synthesis and Functionalization Reactivity of Fe-Thiocarbonyl and Thiocarbyne Complexes.

Authors:  Meaghan M Deegan; Jonas C Peters
Journal:  Polyhedron       Date:  2021-09-04       Impact factor: 2.975

5.  Selective reduction and homologation of carbon monoxide by organometallic iron complexes.

Authors:  Helen R Sharpe; Ana M Geer; Laurence J Taylor; Benjamin M Gridley; Toby J Blundell; Alexander J Blake; E Stephen Davies; William Lewis; Jonathan McMaster; David Robinson; Deborah L Kays
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Review 8.  Molecular Catalysts for the Reductive Homocoupling of CO2 towards C2+ Compounds.

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  8 in total

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