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Literature DB >> 14677959

N=N bond cleavage by a low-coordinate ironII hydride complex.

Jeremy M Smith¹, Rene J Lachicotte, Patrick L Holland.

Abstract

Reaction of the three-coordinate complex LFeCl (L = bulky beta-diketiminate) with KBEt3H gives a dark red iron(II) hydride complex. The complex is a dimer in the solid state, but spectroscopy and kinetics suggest that an orange three-coordinate monomer is in equilibrium with the dimer in solution. The double bond of azobenzene is completely cleaved by heating with the hydride complex, and a hydrazido intermediate can be isolated.

Entities: Chemical

Year: 2003 PMID： 14677959 DOI： 10.1021/ja038152s

Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419

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Cited

27 in total

1. Iron-catalyzed carbometalation of propargylic and homopropargylic alcohols.

Authors: Donghui Zhang; Joseph M Ready
Journal: J Am Chem Soc Date: 2006-11-29 Impact factor: 15.419

2. A dinucleating ligand related to the beta-diketiminates.

Authors: Travis J Hebden; William W Brennessel; Christine J Flaschenriem; Patrick L Holland
Journal: Dalton Trans Date: 2006-06-28 Impact factor: 4.390

3. An iron(ii) hydride complex of a ligand with two adjacent β-diketiminate binding sites and its reactivity.

Authors: Henrike Gehring; Ramona Metzinger; Beatrice Braun; Christian Herwig; Sjoerd Harder; Kallol Ray; Christian Limberg
Journal: Dalton Trans Date: 2016-01-13 Impact factor: 4.390

4. Quantitative geometric descriptions of the belt iron atoms of the iron-molybdenum cofactor of nitrogenase and synthetic iron(II) model complexes.

Authors: Javier Vela; Jordi Cirera; Jeremy M Smith; Rene J Lachicotte; Christine J Flaschenriem; Santiago Alvarez; Patrick L Holland
Journal: Inorg Chem Date: 2007-01-08 Impact factor: 5.165

N=N bond cleavage by a low-coordinate ironII hydride complex.

1. Iron-catalyzed carbometalation of propargylic and homopropargylic alcohols.

2. A dinucleating ligand related to the beta-diketiminates.

3. An iron(ii) hydride complex of a ligand with two adjacent β-diketiminate binding sites and its reactivity.

4. Quantitative geometric descriptions of the belt iron atoms of the iron-molybdenum cofactor of nitrogenase and synthetic iron(II) model complexes.

5. Roles of Iron Complexes in Catalytic Radical Alkene Cross-Coupling: A Computational and Mechanistic Study.

6. The Mechanism of N-N Double Bond Cleavage by an Iron(II) Hydride Complex.

7. Three-coordinate and four-coordinate cobalt hydride complexes that react with dinitrogen.

8. H-H and Si-H bond addition to Fe≡NNR2 intermediates derived from N2.

9. Testing the polynuclear hypothesis: multielectron reduction of small molecules by triiron reaction sites.

10. The reactivity patterns of low-coordinate iron-hydride complexes.