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Literature DB >> 23406445

Palladium(0)-catalyzed alkynylation of C(sp3)-H bonds.

Jian He¹, Masayuki Wasa, Kelvin S L Chan, Jin-Quan Yu.

Abstract

The alkynylation of β-C(sp(3))-H bonds in aliphatic amides with alkynyl halides has been enabled using Pd(0)/N-heterocyclic carbene (NHC) and Pd(0)/phosphine (PR3) catalysts. This is the first example of utilizing [AlkynylPd(II)L(n)] complexes to activate C(sp(3))-H bonds.

Entities: Chemical Disease Species

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Year: 2013 PMID： 23406445 DOI： 10.1021/ja400648w

Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419

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Cited

25 in total

1. Palladium(II)-Catalyzed Site-Selective C(sp³ )-H Alkynylation of Oligopeptides: A Linchpin Approach for Oligopeptide-Drug Conjugation.

Authors: Tao Liu; Jennifer X Qiao; Michael A Poss; Jin-Quan Yu
Journal: Angew Chem Int Ed Engl Date: 2017-08-07 Impact factor: 15.336

2. Palladium-Catalyzed Transformations of Alkyl C-H Bonds.

Authors: Jian He; Masayuki Wasa; Kelvin S L Chan; Qian Shao; Jin-Quan Yu
Journal: Chem Rev Date: 2016-12-02 Impact factor: 60.622

3. Ligand-Enabled Alkynylation of C(sp³ )-H Bonds with Palladium(II) Catalysts.

Authors: Haiyan Fu; Peng-Xiang Shen; Jian He; Fanglin Zhang; Suhua Li; Peng Wang; Tao Liu; Jin-Quan Yu
Journal: Angew Chem Int Ed Engl Date: 2017-01-12 Impact factor: 15.336

4. Ligand-enabled cross-coupling of C(sp(3))-H bonds with arylsilanes.

Authors: Jian He; Ryosuke Takise; Haiyan Fu; Jin-Quan Yu
Journal: J Am Chem Soc Date: 2015-04-02 Impact factor: 15.419

Review 5. Complementary Strategies for Directed C(sp³ )-H Functionalization: A Comparison of Transition-Metal-Catalyzed Activation, Hydrogen Atom Transfer, and Carbene/Nitrene Transfer.

Authors: John C K Chu; Tomislav Rovis
Journal: Angew Chem Int Ed Engl Date: 2017-12-05 Impact factor: 15.336

10. Ligand-enabled triple C-H activation reactions: one-pot synthesis of diverse 4-aryl-2-quinolinones from propionamides.

Authors: Youqian Deng; Wei Gong; Jian He; Jin-Quan Yu
Journal: Angew Chem Int Ed Engl Date: 2014-05-14 Impact factor: 15.336

Palladium(0)-catalyzed alkynylation of C(sp3)-H bonds.

1. Palladium(II)-Catalyzed Site-Selective C(sp³ )-H Alkynylation of Oligopeptides: A Linchpin Approach for Oligopeptide-Drug Conjugation.

2. Palladium-Catalyzed Transformations of Alkyl C-H Bonds.

3. Ligand-Enabled Alkynylation of C(sp³ )-H Bonds with Palladium(II) Catalysts.

4. Ligand-enabled cross-coupling of C(sp(3))-H bonds with arylsilanes.

Review 5. Complementary Strategies for Directed C(sp³ )-H Functionalization: A Comparison of Transition-Metal-Catalyzed Activation, Hydrogen Atom Transfer, and Carbene/Nitrene Transfer.

6. γ,δ,ε-C(sp(3))-H Functionalization through Directed Radical H-Abstraction.

7. Pd(II)-catalyzed C-H functionalizations directed by distal weakly coordinating functional groups.

8. Ligand-Promoted Borylation of C(sp(3))-H Bonds with Palladium(II) Catalysts.

Review 9. N-Heterocyclic Carbene Complexes in C-H Activation Reactions.

10. Ligand-enabled triple C-H activation reactions: one-pot synthesis of diverse 4-aryl-2-quinolinones from propionamides.

Review 5. Complementary Strategies for Directed C(sp3 )-H Functionalization: A Comparison of Transition-Metal-Catalyzed Activation, Hydrogen Atom Transfer, and Carbene/Nitrene Transfer.

Review 9. N-Heterocyclic Carbene Complexes in C-H Activation Reactions.

Review 5. Complementary Strategies for Directed C(sp³ )-H Functionalization: A Comparison of Transition-Metal-Catalyzed Activation, Hydrogen Atom Transfer, and Carbene/Nitrene Transfer.