Literature DB >> 23379760

Rh2(II)-catalyzed selective aminomethylene migration from styryl azides.

Chen Kong1, Navendu Jana, Tom G Driver.   

Abstract

Rh(2)(II)-carboxylate complexes were discovered to promote the selective migration of aminomethylenes in β,β-disubstituted styryl azides to form 2,3-disubstituted indoles. Mechanistic data are also presented that suggest that the migration occurs stepwise before diffusion of the iminium ion.

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Year:  2013        PMID： 23379760      PMCID： PMC8941974          DOI： 10.1021/ol400137q

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  32 in total

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5.  Hydrazulene ring systems via heteroatom-assisted [1,2]-shift of oxonium and sulfonium ylides.

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6.  Rh2(II)-catalyzed nitro-group migration reactions: selective synthesis of 3-nitroindoles from β-nitro styryl azides.

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7.  Interrupting the Nazarov reaction: domino and cascade processes utilizing cyclopentenyl cations.

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Review 9.  Recent progress in the total synthesis of indole alkaloids.

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