Literature DB >> 23284481

(3-Oxo-3H-benzo[f]chromen-1-yl)methyl piperidine-1-carbodithio-ate.

O Kotresh1, K Mahesh Kumar, N M Mahabaleshwaraiah, H K Arunkashi, H C Devarajegowda.   

Abstract

In the title compound, C(20)H(19)N O(2)S(2),the 3Hbenzo-chromene ring system is nearly planar, with a maximum deviation of 0.036 (2) Å, and the piperidine ring adopts a chair conformation: the bond-angle sum for its N atom is 358.7°. The dihedral angle between the 3H-benzo[f]chromene ring and the piperidine ring is 89.07 (8)°. In the crystal, C-H⋯O hydrogen bonds lead to [010] C(6) chains and weak aromatic π-π inter-actions between the fused pyran ring and fused benzene ring of benzochromene [centroid-centroid distance = 3.652 (1) Å] are also observed.

Entities:  

Year:  2012        PMID: 23284481      PMCID: PMC3515261          DOI: 10.1107/S1600536812042870

Source DB:  PubMed          Journal:  Acta Crystallogr Sect E Struct Rep Online        ISSN: 1600-5368


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Authors:  George M Sheldrick
Journal:  Acta Crystallogr A       Date:  2007-12-21       Impact factor: 2.290

2.  (7-Chloro-2-oxo-2H-chromen-4-yl)methyl piperidine-1-carbodithio-ate.

Authors:  K Mahesh Kumar; Dalbir Kour; Kamini Kapoor; N M Mahabaleshwaraiah; O Kotresh; Vivek K Gupta; Rajni Kant
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2012-02-29
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1.  Crystal structure of S-(4-methyl-benz-yl) piperidine-dithio-carbamate.

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Journal:  Acta Crystallogr E Crystallogr Commun       Date:  2015-08-06
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