Literature DB >> 23166056

The bis(allyl)bismuth cation: a reagent for direct allyl transfer by Lewis acid activation and controlled radical polymerization.

Crispin Lichtenberg1, Fangfang Pan, Thomas P Spaniol, Ulli Englert, Jun Okuda.   

Abstract

A positive effect: the bis(allyl)bismuth cation in [Bi(C(3)H(5))(2)(thf)(2)][B(C(6)H(3)Cl(2))(4)] is superior to neutral tris(allyl)bismuth in the additive-free allylation of unsaturated C-heteroatom functionalities and the controlled living radical polymerization of activated olefins.
Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Year:  2012        PMID： 23166056     DOI： 10.1002/anie.201206782

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  8 in total

1.  Well-Defined, Molecular Bismuth Compounds: Catalysts in Photochemically Induced Radical Dehydrocoupling Reactions.

Authors:  Jacqueline Ramler; Ivo Krummenacher; Crispin Lichtenberg
Journal:  Chemistry       Date:  2020-10-14       Impact factor: 5.236

2.  Molecular Bismuth Cations: Assessment of Soft Lewis Acidity.

Authors:  Jacqueline Ramler; Crispin Lichtenberg
Journal:  Chemistry       Date:  2020-07-28       Impact factor: 5.236

3.  Cationic Bismuth Aminotroponiminates: Charge Controls Redox Properties.

Authors:  Anna Hanft; Krzysztof Radacki; Crispin Lichtenberg
Journal:  Chemistry       Date:  2021-01-26       Impact factor: 5.236

Review 4.  Bismuth Redox Catalysis: An Emerging Main-Group Platform for Organic Synthesis.

Authors:  Hye Won Moon; Josep Cornella
Journal:  ACS Catal       Date:  2022-01-07       Impact factor: 13.084

5.  Two Faces of the Bi-O Bond: Photochemically and Thermally Induced Dehydrocoupling for Si-O Bond Formation.

Authors:  Jacqueline Ramler; Johannes Schwarzmann; Andreas Stoy; Crispin Lichtenberg
Journal:  Eur J Inorg Chem       Date:  2021-12-18       Impact factor: 2.551

6.  Bi-mediated allylation of aldehydes in [bmim][Br]: a mechanistic investigation.

Authors:  Mrunesh Koli; Sucheta Chatterjee; Subrata Chattopadhyay; Dibakar Goswami
Journal:  Beilstein J Org Chem       Date:  2018-08-22       Impact factor: 2.883

7.  Carbon monoxide insertion at a heavy p-block element: unprecedented formation of a cationic bismuth carbamoyl.

Authors:  Jacqueline Ramler; Jordi Poater; Florian Hirsch; Benedikt Ritschel; Ingo Fischer; F Matthias Bickelhaupt; Crispin Lichtenberg
Journal:  Chem Sci       Date:  2019-02-28       Impact factor: 9.825

Review 8.  Main-Group Metal Complexes in Selective Bond Formations Through Radical Pathways.

Authors:  Crispin Lichtenberg
Journal:  Chemistry       Date:  2020-03-24       Impact factor: 5.236
  8 in total

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