| Literature DB >> 22920099 |
Abstract
The master equation and, more generally, Markov processes are routinely used as models for stochastic processes. They are often justified on the basis of randomization and coarse-graining assumptions. Here instead, we derive nth-order Markov processes and the master equation as unique solutions to an inverse problem. We find that when constraints are not enough to uniquely determine the stochastic model, an nth-order Markov process emerges as the unique maximum entropy solution to this otherwise underdetermined problem. This gives a rigorous alternative for justifying such models while providing a systematic recipe for generalizing widely accepted stochastic models usually assumed to follow from the first principles.Entities:
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Year: 2012 PMID: 22920099 PMCID: PMC4108628 DOI: 10.1063/1.4743955
Source DB: PubMed Journal: J Chem Phys ISSN: 0021-9606 Impact factor: 3.488