| Literature DB >> 22510100 |
Brett VanVeller1, Derek J Schipper, Timothy M Swager.
Abstract
The cyclization and planarization of polycyclic aromatic hydrocarbons with concomitant oxygen substitution was achieved through acid catalyzed transetherification and oxygen-radical reactions. The triptycene scaffold enforces proximity of the alcohol and arene reacting partners and confers significant rigidity to the resulting π-system, expanding the tool set of iptycenes for materials applications.Entities:
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Year: 2012 PMID: 22510100 PMCID: PMC3353728 DOI: 10.1021/ja3018253
Source DB: PubMed Journal: J Am Chem Soc ISSN: 0002-7863 Impact factor: 15.419