Literature DB >> 17523651

Unexpected phenyl group rearrangement during an intramolecular Scholl reaction leading to an alkoxy-substituted hexa-peri-hexabenzocoronene.

Xi Dou1, Xiaoyin Yang, Graham J Bodwell, Manfred Wagner, Volker Enkelmann, Klaus Müllen.   

Abstract

A simple dimethoxy-substituted hexa-peri-hexabenzocoronene (m-dimethoxy HBC) was unexpectedly obtained along with a bis-spirocyclic dienone during an intramolecular Scholl reaction of its para isomer.

Entities:  

Year:  2007        PMID： 17523651     DOI： 10.1021/ol0708018

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  6 in total

1.  Polycyclic aromatic triptycenes: oxygen substitution cyclization strategies.

Authors:  Brett VanVeller; Derek J Schipper; Timothy M Swager
Journal:  J Am Chem Soc       Date:  2012-04-18       Impact factor: 15.419

2.  Alternating oligo(o,p-phenylenes) via ruthenium catalyzed diol-diene benzannulation: orthogonality to cross-coupling enables de novo nanographene and PAH construction.

Authors:  Zachary A Kasun; Hiroki Sato; Jing Nie; Yasuyuki Mori; Jon A Bender; Sean T Roberts; Michael J Krische
Journal:  Chem Sci       Date:  2018-08-30       Impact factor: 9.825

3.  Six-fold C-H borylation of hexa-peri-hexabenzocoronene.

Authors:  Mai Nagase; Kenta Kato; Akiko Yagi; Yasutomo Segawa; Kenichiro Itami
Journal:  Beilstein J Org Chem       Date:  2020-03-13       Impact factor: 2.883

4.  Carbon Origami via an Alumina-Assisted Cyclodehydrofluorination Strategy.

Authors:  Ann-Kristin Steiner; Dmitry I Sharapa; Sergey I Troyanov; Jürgen Nuss; Konstantin Amsharov
Journal:  Chemistry       Date:  2021-03-23       Impact factor: 5.236

Review 5.  Scholl reaction as a powerful tool for the synthesis of nanographenes: a systematic review.

Authors:  Rabab S Jassas; Ehsan Ullah Mughal; Amina Sadiq; Reem I Alsantali; Munirah M Al-Rooqi; Nafeesa Naeem; Ziad Moussa; Saleh A Ahmed
Journal:  RSC Adv       Date:  2021-09-29       Impact factor: 4.036

Review 6.  The Mechanochemical Synthesis and Activation of Carbon-Rich π-Conjugated Materials.

Authors:  Mingjun Xuan; Christian Schumacher; Carsten Bolm; Robert Göstl; Andreas Herrmann
Journal:  Adv Sci (Weinh)       Date:  2022-01-20       Impact factor: 17.521
  6 in total

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