Literature DB >> 22083090

Understanding the regioselectivity in Scholl reactions for the synthesis of oligoarenes.

Michael Danz1, Ralf Tonner, Gerhard Hilt.   

Abstract

A short reaction sequence leads to oligoarene derivatives utilising a regioselective Scholl reaction for the unprecedented cyclisation to the mono-functionalised oligoarene under methanol elimination. Quantum-chemical investigations reveal the reason for the remarkably high regioselectivity. This journal is © The Royal Society of Chemistry 2012

Entities:  

Year:  2011        PMID： 22083090     DOI： 10.1039/c1cc15980a

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  4 in total

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Journal:  Nat Commun       Date:  2018-04-27       Impact factor: 14.919

3.  Alternating oligo(o,p-phenylenes) via ruthenium catalyzed diol-diene benzannulation: orthogonality to cross-coupling enables de novo nanographene and PAH construction.

Authors:  Zachary A Kasun; Hiroki Sato; Jing Nie; Yasuyuki Mori; Jon A Bender; Sean T Roberts; Michael J Krische
Journal:  Chem Sci       Date:  2018-08-30       Impact factor: 9.825

4.  On-surface cyclodehydrogenation reaction pathway determined by selective molecular deuterations.

Authors:  Chuanxu Ma; Zhongcan Xiao; Peter V Bonnesen; Liangbo Liang; Alexander A Puretzky; Jingsong Huang; Marek Kolmer; Bobby G Sumpter; Wenchang Lu; Kunlun Hong; Jerzy Bernholc; An-Ping Li
Journal:  Chem Sci       Date:  2021-11-16       Impact factor: 9.825
  4 in total

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