Literature DB >> 21995751

Palladium(II)-catalyzed dehydrogenative alkenylation of cyclic enaminones via the Fujiwara-Moritani reaction.

Yi-Yun Yu1, Micah J Niphakis, Gunda I Georg.   

Abstract

A new Pd(II)-catalyzed dehydrogenative alkenylation reaction involving two alkenes was developed. A variety of nonaromatic, cyclic enaminones were successfully coupled to primary and secondary alkenes yielding a series of unique 1,3-dienes. The generality of this transformation presents a useful strategy for directly cross-coupling alkenes and offers an attractive new approach to functionalize enaminones.
© 2011 American Chemical Society

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Year:  2011        PMID： 21995751      PMCID： PMC3235746          DOI： 10.1021/ol202677g

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  28 in total

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  11 in total

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